Bis(4-amino-3,5-di-2-pyridyl-1,2,4-triazole-κ2N1,N5)diaquazinc(II) dinitrate
The asymmetric unit of the title compound, [Zn(C12H10N6)2(H2O)2](NO3)2, contains one-half of the complex molecule and one NO3− anion. The ZnII ion displays a distorted tetragonal-pyramidal geometry with four N atoms from two chelating 4-amino-3,5-di-2-pyridyl-1,2,4-triazole (2-bpt) lig...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2009-09-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809032103 |
| _version_ | 1819105030411649024 |
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| author | Jia Hua Lu Gao Baiyan Li |
| author_facet | Jia Hua Lu Gao Baiyan Li |
| author_sort | Jia Hua |
| collection | DOAJ |
| description | The asymmetric unit of the title compound, [Zn(C12H10N6)2(H2O)2](NO3)2, contains one-half of the complex molecule and one NO3− anion. The ZnII ion displays a distorted tetragonal-pyramidal geometry with four N atoms from two chelating 4-amino-3,5-di-2-pyridyl-1,2,4-triazole (2-bpt) ligands in the basal plane and one water molecule occupying the apical site. Another water molecule at the opposite of the apical site has a weak interaction with the ZnII ion [Zn—O = 2.852 (5) Å]. The ZnII ion and the two water molecules lie on a twofold rotation axis. An extensive system of hydrogen bonds involving the NH2 groups of the 2-bpt ligands, water molecules and nitrate anions links all residues into a three-dimensional network. |
| first_indexed | 2024-12-22T02:15:46Z |
| format | Article |
| id | doaj.art-7b58e10f80554e4baf8b29156ddb272a |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-22T02:15:46Z |
| publishDate | 2009-09-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-7b58e10f80554e4baf8b29156ddb272a2022-12-21T18:42:17ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-09-01659m1106m110710.1107/S1600536809032103Bis(4-amino-3,5-di-2-pyridyl-1,2,4-triazole-κ2N1,N5)diaquazinc(II) dinitrateJia HuaLu GaoBaiyan LiThe asymmetric unit of the title compound, [Zn(C12H10N6)2(H2O)2](NO3)2, contains one-half of the complex molecule and one NO3− anion. The ZnII ion displays a distorted tetragonal-pyramidal geometry with four N atoms from two chelating 4-amino-3,5-di-2-pyridyl-1,2,4-triazole (2-bpt) ligands in the basal plane and one water molecule occupying the apical site. Another water molecule at the opposite of the apical site has a weak interaction with the ZnII ion [Zn—O = 2.852 (5) Å]. The ZnII ion and the two water molecules lie on a twofold rotation axis. An extensive system of hydrogen bonds involving the NH2 groups of the 2-bpt ligands, water molecules and nitrate anions links all residues into a three-dimensional network.http://scripts.iucr.org/cgi-bin/paper?S1600536809032103 |
| spellingShingle | Jia Hua Lu Gao Baiyan Li Bis(4-amino-3,5-di-2-pyridyl-1,2,4-triazole-κ2N1,N5)diaquazinc(II) dinitrate Acta Crystallographica Section E |
| title | Bis(4-amino-3,5-di-2-pyridyl-1,2,4-triazole-κ2N1,N5)diaquazinc(II) dinitrate |
| title_full | Bis(4-amino-3,5-di-2-pyridyl-1,2,4-triazole-κ2N1,N5)diaquazinc(II) dinitrate |
| title_fullStr | Bis(4-amino-3,5-di-2-pyridyl-1,2,4-triazole-κ2N1,N5)diaquazinc(II) dinitrate |
| title_full_unstemmed | Bis(4-amino-3,5-di-2-pyridyl-1,2,4-triazole-κ2N1,N5)diaquazinc(II) dinitrate |
| title_short | Bis(4-amino-3,5-di-2-pyridyl-1,2,4-triazole-κ2N1,N5)diaquazinc(II) dinitrate |
| title_sort | bis 4 amino 3 5 di 2 pyridyl 1 2 4 triazole amp 954 2n1 n5 diaquazinc ii dinitrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536809032103 |
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