Morphological and Chemical Effects of Plasma Treatment with Oxygen (O2) and Sulfur Hexafluoride (SF6) on Cellulose Surface

Cellulose is a polymer widely available in nature, however its applications may be restrict due to its hydrophilic character. The creation of hierarchical structures on the surface is one of the required factors to obtain the hydrophobicity of this material. In order to compare the morphological and...

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Main Authors: Janine Sanches Gonzaga de Camargo, Aparecido Junior de Menezes, Nilson Cristino da Cruz, Elidiane Cipriano Rangel, Adriana de Oliveira Delgado-Silva
Format: Article
Language:English
Published: Associação Brasileira de Metalurgia e Materiais (ABM); Associação Brasileira de Cerâmica (ABC); Associação Brasileira de Polímeros (ABPol) 2018-02-01
Series:Materials Research
Subjects:
Online Access:http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392017000800842&tlng=en
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author Janine Sanches Gonzaga de Camargo
Aparecido Junior de Menezes
Nilson Cristino da Cruz
Elidiane Cipriano Rangel
Adriana de Oliveira Delgado-Silva
author_facet Janine Sanches Gonzaga de Camargo
Aparecido Junior de Menezes
Nilson Cristino da Cruz
Elidiane Cipriano Rangel
Adriana de Oliveira Delgado-Silva
author_sort Janine Sanches Gonzaga de Camargo
collection DOAJ
description Cellulose is a polymer widely available in nature, however its applications may be restrict due to its hydrophilic character. The creation of hierarchical structures on the surface is one of the required factors to obtain the hydrophobicity of this material. In order to compare the morphological and chemical effects caused by the action of different gases in the creation of nanostructures on the cellulose surface, samples were exposed to oxygen (O2) and sulfur hexafluoride (SF6) plasma treatments. The changes in morphology after treatment prove that both the gases were able to create similar nanostructures in the material. The analysis of elemental composition and identification of functional groups on the sample surface showed that chemical modifications occurred differently for each treatment. Contact angle measurements revealed that samples treated by O2 plasma remained hydrophilic, whereas low receptivity to polar (θ > 120º) and non-polar (θ > 100º) liquids was observed for samples exposed to SF6 plasma.
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publishDate 2018-02-01
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spelling doaj.art-7bac9351ba89493eadad489c535d8ff72022-12-21T19:33:38ZengAssociação Brasileira de Metalurgia e Materiais (ABM); Associação Brasileira de Cerâmica (ABC); Associação Brasileira de Polímeros (ABPol)Materials Research1516-14392018-02-0120suppl 284285010.1590/1980-5373-mr-2016-1111Morphological and Chemical Effects of Plasma Treatment with Oxygen (O2) and Sulfur Hexafluoride (SF6) on Cellulose SurfaceJanine Sanches Gonzaga de CamargoAparecido Junior de MenezesNilson Cristino da CruzElidiane Cipriano RangelAdriana de Oliveira Delgado-SilvaCellulose is a polymer widely available in nature, however its applications may be restrict due to its hydrophilic character. The creation of hierarchical structures on the surface is one of the required factors to obtain the hydrophobicity of this material. In order to compare the morphological and chemical effects caused by the action of different gases in the creation of nanostructures on the cellulose surface, samples were exposed to oxygen (O2) and sulfur hexafluoride (SF6) plasma treatments. The changes in morphology after treatment prove that both the gases were able to create similar nanostructures in the material. The analysis of elemental composition and identification of functional groups on the sample surface showed that chemical modifications occurred differently for each treatment. Contact angle measurements revealed that samples treated by O2 plasma remained hydrophilic, whereas low receptivity to polar (θ > 120º) and non-polar (θ > 100º) liquids was observed for samples exposed to SF6 plasma.http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392017000800842&tlng=encelluloseplasma treatmenthydrophobicityhierarchical structures
spellingShingle Janine Sanches Gonzaga de Camargo
Aparecido Junior de Menezes
Nilson Cristino da Cruz
Elidiane Cipriano Rangel
Adriana de Oliveira Delgado-Silva
Morphological and Chemical Effects of Plasma Treatment with Oxygen (O2) and Sulfur Hexafluoride (SF6) on Cellulose Surface
Materials Research
cellulose
plasma treatment
hydrophobicity
hierarchical structures
title Morphological and Chemical Effects of Plasma Treatment with Oxygen (O2) and Sulfur Hexafluoride (SF6) on Cellulose Surface
title_full Morphological and Chemical Effects of Plasma Treatment with Oxygen (O2) and Sulfur Hexafluoride (SF6) on Cellulose Surface
title_fullStr Morphological and Chemical Effects of Plasma Treatment with Oxygen (O2) and Sulfur Hexafluoride (SF6) on Cellulose Surface
title_full_unstemmed Morphological and Chemical Effects of Plasma Treatment with Oxygen (O2) and Sulfur Hexafluoride (SF6) on Cellulose Surface
title_short Morphological and Chemical Effects of Plasma Treatment with Oxygen (O2) and Sulfur Hexafluoride (SF6) on Cellulose Surface
title_sort morphological and chemical effects of plasma treatment with oxygen o2 and sulfur hexafluoride sf6 on cellulose surface
topic cellulose
plasma treatment
hydrophobicity
hierarchical structures
url http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392017000800842&tlng=en
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