High thermal stability of the amorphous oxide in Ti44.5Cu44.5Zr7Be4 metallic glass

The oxidation behavior of Ti44.5Cu44.5Zr7Be4 metallic glass has been investigated. The oxide layer with a fully amorphous structure forms when heated up to the SCL temperature region, indicating that the presence of Be in the oxide layer improves the thermal stability of the amorphous oxide. The amo...

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Main Authors: Sung Hyun Park, Ka Ram Lim, Min Young Na, Kang Cheol Kim, Won Tae Kim, Do Hyang Kim
Format: Article
Language:English
Published: AIP Publishing LLC 2015-11-01
Series:AIP Advances
Online Access:http://dx.doi.org/10.1063/1.4935263
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author Sung Hyun Park
Ka Ram Lim
Min Young Na
Kang Cheol Kim
Won Tae Kim
Do Hyang Kim
author_facet Sung Hyun Park
Ka Ram Lim
Min Young Na
Kang Cheol Kim
Won Tae Kim
Do Hyang Kim
author_sort Sung Hyun Park
collection DOAJ
description The oxidation behavior of Ti44.5Cu44.5Zr7Be4 metallic glass has been investigated. The oxide layer with a fully amorphous structure forms when heated up to the SCL temperature region, indicating that the presence of Be in the oxide layer improves the thermal stability of the amorphous oxide. The amorphous oxide is stable even when heated above the crystallization onset temperature. The thickness of the amorphous oxide layer reaches to ∼160 nm when heated up to 773 K. The oxide layer grows in both inward and outward directions, leaving Cu-enriched crystalline particles at the middle section of the oxide layer.
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spelling doaj.art-7bc00d64d3b748289b007786d3db2a412022-12-22T03:50:11ZengAIP Publishing LLCAIP Advances2158-32262015-11-01511117202117202-810.1063/1.4935263004511ADVHigh thermal stability of the amorphous oxide in Ti44.5Cu44.5Zr7Be4 metallic glassSung Hyun Park0Ka Ram Lim1Min Young Na2Kang Cheol Kim3Won Tae Kim4Do Hyang Kim5Department of Materials Science and Engineering, Center for Non-crystalline Materials, Yonsei University,134 Shinchon-dong, Seodaemun-gu, Seoul 120-749, South KoreaLight Metal Division, Korea Institute of Materials Science, 797 Changwondaero, Seongsan-gu, Changwon,Gyeongnam 642-831, South KoreaDepartment of Materials Science and Engineering, Center for Non-crystalline Materials, Yonsei University,134 Shinchon-dong, Seodaemun-gu, Seoul 120-749, South KoreaDepartment of Materials Science and Engineering, Center for Non-crystalline Materials, Yonsei University,134 Shinchon-dong, Seodaemun-gu, Seoul 120-749, South KoreaDepartment of Optical Engineering, Cheongju University, 36 Naedock-dong, Cheongju 360-764, South KoreaDepartment of Materials Science and Engineering, Center for Non-crystalline Materials, Yonsei University,134 Shinchon-dong, Seodaemun-gu, Seoul 120-749, South KoreaThe oxidation behavior of Ti44.5Cu44.5Zr7Be4 metallic glass has been investigated. The oxide layer with a fully amorphous structure forms when heated up to the SCL temperature region, indicating that the presence of Be in the oxide layer improves the thermal stability of the amorphous oxide. The amorphous oxide is stable even when heated above the crystallization onset temperature. The thickness of the amorphous oxide layer reaches to ∼160 nm when heated up to 773 K. The oxide layer grows in both inward and outward directions, leaving Cu-enriched crystalline particles at the middle section of the oxide layer.http://dx.doi.org/10.1063/1.4935263
spellingShingle Sung Hyun Park
Ka Ram Lim
Min Young Na
Kang Cheol Kim
Won Tae Kim
Do Hyang Kim
High thermal stability of the amorphous oxide in Ti44.5Cu44.5Zr7Be4 metallic glass
AIP Advances
title High thermal stability of the amorphous oxide in Ti44.5Cu44.5Zr7Be4 metallic glass
title_full High thermal stability of the amorphous oxide in Ti44.5Cu44.5Zr7Be4 metallic glass
title_fullStr High thermal stability of the amorphous oxide in Ti44.5Cu44.5Zr7Be4 metallic glass
title_full_unstemmed High thermal stability of the amorphous oxide in Ti44.5Cu44.5Zr7Be4 metallic glass
title_short High thermal stability of the amorphous oxide in Ti44.5Cu44.5Zr7Be4 metallic glass
title_sort high thermal stability of the amorphous oxide in ti44 5cu44 5zr7be4 metallic glass
url http://dx.doi.org/10.1063/1.4935263
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