| Summary: | Chloride penetration resistance is one of the most important performance measures for the evaluation of the durability of concrete under a chloride environment. Due to differences in theory and experimental conditions, the durability index (chloride diffusion coefficient) obtained from laboratory accelerated migration tests cannot reflect the real process of chloride ingress into concrete in the natural environment. The difference in test methods must be considered and the transfer parameter <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><msub><mi>k</mi><mi>t</mi></msub></mrow></semantics></math></inline-formula> should be introduced into the service life prediction model when the test results of accelerated methods are used. According to the test data of coastal exposure in South China, the attenuation rule of the chloride diffusion coefficient of different cement-based materials changed with time and was analyzed in this paper. Based on the diffusion coefficient–time curve, the theoretical natural diffusion coefficients of 28 d and 56 d were deduced, which were compared with the chloride diffusion coefficients obtained from the non-steady-state rapid migration method (RCM) at the same age. Therefore, the transfer parameter <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><msub><mi>k</mi><mi>t</mi></msub></mrow></semantics></math></inline-formula> that expounds the relationship between concrete resistance to chloride permeability under a non-stationary electrical accelerated state and natural diffusion in the marine environment can be calculated; thus, the RCM testing index can be used to evaluate the long-term performance of the concrete structure in the marine environment. The results show that the value of <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><msub><mi>k</mi><mi>t</mi></msub></mrow></semantics></math></inline-formula> was related to environmental conditions, test methods, and binder systems.
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