Penggunaan Ultrasonik untuk Transesterifikasi Minyak Goreng Bekas

In this work, the ultrasound-assisted transesterification of used frying oil (UFO) was studied. A two-step pretreatment of degumming and esterification was conducted to prepare UFO as raw material for transesterification. The esterification and transesterification was performed by using ethanol as s...

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Main Author: Muhammad Dani Supardan
Format: Article
Language:English
Published: Universitas Syiah Kuala, Chemical Engineering Department 2011-06-01
Series:Jurnal Rekayasa Kimia & Lingkungan
Online Access:https://jurnal.unsyiah.ac.id/RKL/article/view/239
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author Muhammad Dani Supardan
author_facet Muhammad Dani Supardan
author_sort Muhammad Dani Supardan
collection DOAJ
description In this work, the ultrasound-assisted transesterification of used frying oil (UFO) was studied. A two-step pretreatment of degumming and esterification was conducted to prepare UFO as raw material for transesterification. The esterification and transesterification was performed by using ethanol as solvent in the presence of ultrasonic irradiations operating at frequency of 40 kHz. The esterification was carried out with oil to ethanol ratio of 1:10, temperature of 60oC and reaction time of 4 hours in the presence of 1 wt .% H2SO4 as an acid catalyst. Meanwhile, the transesterification reaction was carried out with oil to ethanol molar ratio of 1:8, 1:10, 1:12, 1:15; KOH catalyst concentration of 0.5, 0.75, 1, 1.25 and 1.5 wt.%; and reaction temperature of 40, 50 and 60oC. The highest biodiesel yield of 65% obtained at ultrasound-assisted transesterification condition of oil to ethanol molar ratio of 1:12, reaction temperature of 50oC and KOH concentration of 1 wt.%. The results of analysis of some parameters of the product showed biodiesel has fulfilled the specifications according to the Indonesian National Standard (SNI) 04-7182-2006 number. Keywords: Biodiesel, Esterification, Used frying oil, Transesterification, Ultrasonic
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spelling doaj.art-7bec2ef9c0414f129c1c5043001a3a812024-04-02T15:29:29ZengUniversitas Syiah Kuala, Chemical Engineering DepartmentJurnal Rekayasa Kimia & Lingkungan1412-50642356-16612011-06-0181234Penggunaan Ultrasonik untuk Transesterifikasi Minyak Goreng BekasMuhammad Dani Supardan0Jurusan Teknik Kimia, Fakultas Teknik, Universitas Syiah KualaIn this work, the ultrasound-assisted transesterification of used frying oil (UFO) was studied. A two-step pretreatment of degumming and esterification was conducted to prepare UFO as raw material for transesterification. The esterification and transesterification was performed by using ethanol as solvent in the presence of ultrasonic irradiations operating at frequency of 40 kHz. The esterification was carried out with oil to ethanol ratio of 1:10, temperature of 60oC and reaction time of 4 hours in the presence of 1 wt .% H2SO4 as an acid catalyst. Meanwhile, the transesterification reaction was carried out with oil to ethanol molar ratio of 1:8, 1:10, 1:12, 1:15; KOH catalyst concentration of 0.5, 0.75, 1, 1.25 and 1.5 wt.%; and reaction temperature of 40, 50 and 60oC. The highest biodiesel yield of 65% obtained at ultrasound-assisted transesterification condition of oil to ethanol molar ratio of 1:12, reaction temperature of 50oC and KOH concentration of 1 wt.%. The results of analysis of some parameters of the product showed biodiesel has fulfilled the specifications according to the Indonesian National Standard (SNI) 04-7182-2006 number. Keywords: Biodiesel, Esterification, Used frying oil, Transesterification, Ultrasonichttps://jurnal.unsyiah.ac.id/RKL/article/view/239
spellingShingle Muhammad Dani Supardan
Penggunaan Ultrasonik untuk Transesterifikasi Minyak Goreng Bekas
Jurnal Rekayasa Kimia & Lingkungan
title Penggunaan Ultrasonik untuk Transesterifikasi Minyak Goreng Bekas
title_full Penggunaan Ultrasonik untuk Transesterifikasi Minyak Goreng Bekas
title_fullStr Penggunaan Ultrasonik untuk Transesterifikasi Minyak Goreng Bekas
title_full_unstemmed Penggunaan Ultrasonik untuk Transesterifikasi Minyak Goreng Bekas
title_short Penggunaan Ultrasonik untuk Transesterifikasi Minyak Goreng Bekas
title_sort penggunaan ultrasonik untuk transesterifikasi minyak goreng bekas
url https://jurnal.unsyiah.ac.id/RKL/article/view/239
work_keys_str_mv AT muhammaddanisupardan penggunaanultrasonikuntuktransesterifikasiminyakgorengbekas