Formation of an exceptionally stable ketene during phototransformations of bicyclo[2.2.2]oct-5-en-2-ones having mixed chromophores

Formation of an exceptionally stable ketene during phototransformations of bicyclo[2.2.2]oct-5-en-2-ones having mixed chromophores

Photochemical reactions of bicyclo[2.2.2]oct-5-en-2-ones having mixed chromophores like a 5,6 dibenzoyl moiety and bulky electron-deficient substituents like phenyl or isopropenyl at the bridgehead position were analyzed for the first time in different solvents and upon irradiation with different wa...

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Bibliographic Details
Main Author: Asitanga Ghosh
Format: Article
Language:English
Published: Beilstein-Institut 2020-09-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
α,β- and β,γ-enones
bridgehead position
ketene
mixed chromophores
Online Access:https://doi.org/10.3762/bjoc.16.190

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