CdTe X/γ-ray Detectors with Different Contact Materials

Different contact materials and optimization of techniques of their depositions expand the possibilities to obtain high performance room temperature CdTe-based X/γ-ray detectors. The heterostructures with ohmic (MoO<i><sub>x</sub></i>) and Schottky (MoO<i><sub>x&l...

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Main Authors: Volodymyr Gnatyuk, Olena Maslyanchuk, Mykhailo Solovan, Viktor Brus, Toru Aoki
Format: Article
Language:English
Published: MDPI AG 2021-05-01
Series:Sensors
Subjects:
Online Access:https://www.mdpi.com/1424-8220/21/10/3518
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author Volodymyr Gnatyuk
Olena Maslyanchuk
Mykhailo Solovan
Viktor Brus
Toru Aoki
author_facet Volodymyr Gnatyuk
Olena Maslyanchuk
Mykhailo Solovan
Viktor Brus
Toru Aoki
author_sort Volodymyr Gnatyuk
collection DOAJ
description Different contact materials and optimization of techniques of their depositions expand the possibilities to obtain high performance room temperature CdTe-based X/γ-ray detectors. The heterostructures with ohmic (MoO<i><sub>x</sub></i>) and Schottky (MoO<i><sub>x</sub></i>, TiO<i><sub>x</sub></i>, TiN, and In) contacts, created by DC reactive magnetron sputtering and vacuum thermal evaporation, as well as In/CdTe/Au diodes with a <i>p-n</i> junction, formed by laser-induced doping, have been developed and investigated. Depending on the surface pre-treatment of semi-insulating <i>p</i>-CdTe crystals, the deposition of a MoO<i><sub>x</sub></i> film formed either ohmic or Schottky contacts. Based on the calculations and <i>I-V</i> characteristics of the Mo-MoO<i><sub>x</sub></i>/<i>p</i>-CdTe/MoO<i><sub>x</sub></i>-Mo, In/<i>p</i>-CdTe/MoO<i><sub>x</sub></i>-Mo, Ti-TiO<i><sub>x</sub></i>/<i>p</i>-CdTe/MoO<i><sub>x</sub></i>-Mo, and Ti-TiN/<i>p</i>-CdTe/MoO<i><sub>x</sub></i>-Mo Schottky-diode detectors, the current transport processes were described in the models of the carrier generation–recombination within the space-charge region (SCR) at low bias, and space-charge limited current incorporating the Poole–Frenkel effect at higher voltages, respectively. The energies of generation–recombination centers, density of trapping centers, and effective carrier lifetimes were determined. Nanosecond laser irradiation of the In electrode, pre-deposited on the <i>p</i>-CdTe crystals, resulted in extending the voltage range, corresponding to the carrier generation–recombination in the SCR in the <i>I-V</i> characteristics of the In/CdTe/Au diodes. Such In/CdTe/Au <i>p-n</i> junction diode detectors demonstrated high energy resolutions (7%@59.5 keV, 4%@122 keV, and 1.6%@662 keV).
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spelling doaj.art-7bfeb3dd962a45699f966072b647aecb2023-11-21T20:19:08ZengMDPI AGSensors1424-82202021-05-012110351810.3390/s21103518CdTe X/γ-ray Detectors with Different Contact MaterialsVolodymyr Gnatyuk0Olena Maslyanchuk1Mykhailo Solovan2Viktor Brus3Toru Aoki4V.E. Lashkaryov Institute of Semiconductor Physics of the National Academy of Sciences of Ukraine, Prospekt Nauky 41, 03028 Kyiv, UkraineInstitute of Applied Physics and Computer Sciences, Yuriy Fedkovych Chernivtsi National University, Kotsyubynskyi Str. 2, 58012 Chernivtsi, UkraineInstitute of Applied Physics and Computer Sciences, Yuriy Fedkovych Chernivtsi National University, Kotsyubynskyi Str. 2, 58012 Chernivtsi, UkraineDepartment of Physics, School of Sciences and Humanities, Nazarbayev University, Kabanbay Batyr Ave 53, Nur-Sultan 010000, KazakhstanResearch Institute of Electronics, Shizuoka University, 3-5-1 Johoku, Naka-ku, Hamamatsu 432 8011, JapanDifferent contact materials and optimization of techniques of their depositions expand the possibilities to obtain high performance room temperature CdTe-based X/γ-ray detectors. The heterostructures with ohmic (MoO<i><sub>x</sub></i>) and Schottky (MoO<i><sub>x</sub></i>, TiO<i><sub>x</sub></i>, TiN, and In) contacts, created by DC reactive magnetron sputtering and vacuum thermal evaporation, as well as In/CdTe/Au diodes with a <i>p-n</i> junction, formed by laser-induced doping, have been developed and investigated. Depending on the surface pre-treatment of semi-insulating <i>p</i>-CdTe crystals, the deposition of a MoO<i><sub>x</sub></i> film formed either ohmic or Schottky contacts. Based on the calculations and <i>I-V</i> characteristics of the Mo-MoO<i><sub>x</sub></i>/<i>p</i>-CdTe/MoO<i><sub>x</sub></i>-Mo, In/<i>p</i>-CdTe/MoO<i><sub>x</sub></i>-Mo, Ti-TiO<i><sub>x</sub></i>/<i>p</i>-CdTe/MoO<i><sub>x</sub></i>-Mo, and Ti-TiN/<i>p</i>-CdTe/MoO<i><sub>x</sub></i>-Mo Schottky-diode detectors, the current transport processes were described in the models of the carrier generation–recombination within the space-charge region (SCR) at low bias, and space-charge limited current incorporating the Poole–Frenkel effect at higher voltages, respectively. The energies of generation–recombination centers, density of trapping centers, and effective carrier lifetimes were determined. Nanosecond laser irradiation of the In electrode, pre-deposited on the <i>p</i>-CdTe crystals, resulted in extending the voltage range, corresponding to the carrier generation–recombination in the SCR in the <i>I-V</i> characteristics of the In/CdTe/Au diodes. Such In/CdTe/Au <i>p-n</i> junction diode detectors demonstrated high energy resolutions (7%@59.5 keV, 4%@122 keV, and 1.6%@662 keV).https://www.mdpi.com/1424-8220/21/10/3518CdTe detectorsX-ray and γ-ray spectroscopySchottky contact<i>p-n</i> junctioncharge transport mechanism
spellingShingle Volodymyr Gnatyuk
Olena Maslyanchuk
Mykhailo Solovan
Viktor Brus
Toru Aoki
CdTe X/γ-ray Detectors with Different Contact Materials
Sensors
CdTe detectors
X-ray and γ-ray spectroscopy
Schottky contact
<i>p-n</i> junction
charge transport mechanism
title CdTe X/γ-ray Detectors with Different Contact Materials
title_full CdTe X/γ-ray Detectors with Different Contact Materials
title_fullStr CdTe X/γ-ray Detectors with Different Contact Materials
title_full_unstemmed CdTe X/γ-ray Detectors with Different Contact Materials
title_short CdTe X/γ-ray Detectors with Different Contact Materials
title_sort cdte x γ ray detectors with different contact materials
topic CdTe detectors
X-ray and γ-ray spectroscopy
Schottky contact
<i>p-n</i> junction
charge transport mechanism
url https://www.mdpi.com/1424-8220/21/10/3518
work_keys_str_mv AT volodymyrgnatyuk cdtexgraydetectorswithdifferentcontactmaterials
AT olenamaslyanchuk cdtexgraydetectorswithdifferentcontactmaterials
AT mykhailosolovan cdtexgraydetectorswithdifferentcontactmaterials
AT viktorbrus cdtexgraydetectorswithdifferentcontactmaterials
AT toruaoki cdtexgraydetectorswithdifferentcontactmaterials