Flexible fibrous structure of bacterial cellulose by synergic role carboxymethyl cellulose and glycerol for LiB polymer electrolyte
In this work, we report a flexible nanofibrous cellulose nanocomposite with great potential for lithium-ion battery (LiB) polymer electrolyte. Flexible and fibrous material is synthesized using a simple and easy technique by synergistically combining carboxymethyl cellulose (CMC) and glycerol (Gly)....
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| Format: | Article |
| Language: | English |
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IOP Publishing
2023-01-01
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| Series: | Materials Research Express |
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| Online Access: | https://doi.org/10.1088/2053-1591/acd67c |
| _version_ | 1797746408668790784 |
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| author | Qolby Sabrina Christin Rina Ratri Andri Hardiansyah Titik Lestariningsih Achmad Subhan Maria Margaretha Suliyanti Nurfina Yudasari Rike Yudianti Hiroshi Uyama |
| author_facet | Qolby Sabrina Christin Rina Ratri Andri Hardiansyah Titik Lestariningsih Achmad Subhan Maria Margaretha Suliyanti Nurfina Yudasari Rike Yudianti Hiroshi Uyama |
| author_sort | Qolby Sabrina |
| collection | DOAJ |
| description | In this work, we report a flexible nanofibrous cellulose nanocomposite with great potential for lithium-ion battery (LiB) polymer electrolyte. Flexible and fibrous material is synthesized using a simple and easy technique by synergistically combining carboxymethyl cellulose (CMC) and glycerol (Gly). Flexible porous cellulose forms a three-dimensional network for the mobility of Li ions in the polymer electrolyte of LIB systems. We investigated the effect ionic liquid of flexible fibrous cellulose (BC-CMC-Gly) on the electrochemical properties. The surface interaction between Li ions and the porous network is a key parameter demonstrated by the Li-ion emission line at 610.37 nm using laser inductance breakdown spectroscopy (LiBS). The ionic conductivity of BC-CMC-Gly characterized by EIS measurement is about 1.1 × 10 ^−3 S cm ^−1 . According to linear sweep voltammetry (LSV), BC-CMC-Gly, with a potential window of 4.3 V, shows a more expansive window voltage than pure BC (2.75 V) and BC-CMC (3.3 V). This indicates that the electrochemical stability is good, as wide as the range of voltages that the electrode reactions define. The specific capacity of BC-CMC-Gly containing IL is very high, about 27.6 mAh g ^−1 compared to BC (7.4 mAh g ^−1 ) and BC-CMC (11,5 mAh g ^−1 ). All these findings clearly show that forming plasticized structures synergistically with CMC trapped in the BC structure results in the largest Li-ion adsorption capacity and electrochemical performance improvement. Thermal stability up to 200 °C and electrolyte uptake of approx. 189% are the beneficial properties of BC-CMC-Gly fibrous cellulose for LiB electrolyte polymer. |
| first_indexed | 2024-03-12T15:37:24Z |
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| id | doaj.art-7bff9df2b3a545ba98f7ab6683e88eb3 |
| institution | Directory Open Access Journal |
| issn | 2053-1591 |
| language | English |
| last_indexed | 2024-03-12T15:37:24Z |
| publishDate | 2023-01-01 |
| publisher | IOP Publishing |
| record_format | Article |
| series | Materials Research Express |
| spelling | doaj.art-7bff9df2b3a545ba98f7ab6683e88eb32023-08-09T16:10:02ZengIOP PublishingMaterials Research Express2053-15912023-01-0110505530510.1088/2053-1591/acd67cFlexible fibrous structure of bacterial cellulose by synergic role carboxymethyl cellulose and glycerol for LiB polymer electrolyteQolby Sabrina0https://orcid.org/0000-0002-7732-5087Christin Rina Ratri1https://orcid.org/0000-0001-7345-7456Andri Hardiansyah2https://orcid.org/0000-0002-9505-3716Titik Lestariningsih3https://orcid.org/0000-0003-3069-2856Achmad Subhan4https://orcid.org/0000-0002-0774-9220Maria Margaretha Suliyanti5https://orcid.org/0000-0003-4497-1899Nurfina Yudasari6https://orcid.org/0000-0002-2920-9380Rike Yudianti7https://orcid.org/0000-0001-6946-707XHiroshi Uyama8https://orcid.org/0000-0002-8587-2507Research Center for Advanced Material, National Research and Innovation Agency, Kompleks PUSPIPTEK, Gedung 440-442, Serpong, Tangerang Selatan 15314, Banten, Indonesia; Department of Applied Chemistry, Graduate School of Engineering, Osaka University , Suita, Osaka 565-0871, JapanResearch Center for Advanced Material, National Research and Innovation Agency, Kompleks PUSPIPTEK, Gedung 440-442, Serpong, Tangerang Selatan 15314, Banten, IndonesiaResearch Center for Advanced Material, National Research and Innovation Agency, Kompleks PUSPIPTEK, Gedung 440-442, Serpong, Tangerang Selatan 15314, Banten, IndonesiaResearch Center for Advanced Material, National Research and Innovation Agency, Kompleks PUSPIPTEK, Gedung 440-442, Serpong, Tangerang Selatan 15314, Banten, IndonesiaResearch Center for Advanced Material, National Research and Innovation Agency, Kompleks PUSPIPTEK, Gedung 440-442, Serpong, Tangerang Selatan 15314, Banten, IndonesiaResearch Center for Advanced Material, National Research and Innovation Agency, Kompleks PUSPIPTEK, Gedung 440-442, Serpong, Tangerang Selatan 15314, Banten, IndonesiaResearch Center for Advanced Material, National Research and Innovation Agency, Kompleks PUSPIPTEK, Gedung 440-442, Serpong, Tangerang Selatan 15314, Banten, IndonesiaResearch Center for Advanced Material, National Research and Innovation Agency, Kompleks PUSPIPTEK, Gedung 440-442, Serpong, Tangerang Selatan 15314, Banten, IndonesiaDepartment of Applied Chemistry, Graduate School of Engineering, Osaka University , Suita, Osaka 565-0871, JapanIn this work, we report a flexible nanofibrous cellulose nanocomposite with great potential for lithium-ion battery (LiB) polymer electrolyte. Flexible and fibrous material is synthesized using a simple and easy technique by synergistically combining carboxymethyl cellulose (CMC) and glycerol (Gly). Flexible porous cellulose forms a three-dimensional network for the mobility of Li ions in the polymer electrolyte of LIB systems. We investigated the effect ionic liquid of flexible fibrous cellulose (BC-CMC-Gly) on the electrochemical properties. The surface interaction between Li ions and the porous network is a key parameter demonstrated by the Li-ion emission line at 610.37 nm using laser inductance breakdown spectroscopy (LiBS). The ionic conductivity of BC-CMC-Gly characterized by EIS measurement is about 1.1 × 10 ^−3 S cm ^−1 . According to linear sweep voltammetry (LSV), BC-CMC-Gly, with a potential window of 4.3 V, shows a more expansive window voltage than pure BC (2.75 V) and BC-CMC (3.3 V). This indicates that the electrochemical stability is good, as wide as the range of voltages that the electrode reactions define. The specific capacity of BC-CMC-Gly containing IL is very high, about 27.6 mAh g ^−1 compared to BC (7.4 mAh g ^−1 ) and BC-CMC (11,5 mAh g ^−1 ). All these findings clearly show that forming plasticized structures synergistically with CMC trapped in the BC structure results in the largest Li-ion adsorption capacity and electrochemical performance improvement. Thermal stability up to 200 °C and electrolyte uptake of approx. 189% are the beneficial properties of BC-CMC-Gly fibrous cellulose for LiB electrolyte polymer.https://doi.org/10.1088/2053-1591/acd67cpolymer electrolytesbacterial celluloseionic liquidcarboxymethyl celluloseglycerolLi-ion batteries |
| spellingShingle | Qolby Sabrina Christin Rina Ratri Andri Hardiansyah Titik Lestariningsih Achmad Subhan Maria Margaretha Suliyanti Nurfina Yudasari Rike Yudianti Hiroshi Uyama Flexible fibrous structure of bacterial cellulose by synergic role carboxymethyl cellulose and glycerol for LiB polymer electrolyte Materials Research Express polymer electrolytes bacterial cellulose ionic liquid carboxymethyl cellulose glycerol Li-ion batteries |
| title | Flexible fibrous structure of bacterial cellulose by synergic role carboxymethyl cellulose and glycerol for LiB polymer electrolyte |
| title_full | Flexible fibrous structure of bacterial cellulose by synergic role carboxymethyl cellulose and glycerol for LiB polymer electrolyte |
| title_fullStr | Flexible fibrous structure of bacterial cellulose by synergic role carboxymethyl cellulose and glycerol for LiB polymer electrolyte |
| title_full_unstemmed | Flexible fibrous structure of bacterial cellulose by synergic role carboxymethyl cellulose and glycerol for LiB polymer electrolyte |
| title_short | Flexible fibrous structure of bacterial cellulose by synergic role carboxymethyl cellulose and glycerol for LiB polymer electrolyte |
| title_sort | flexible fibrous structure of bacterial cellulose by synergic role carboxymethyl cellulose and glycerol for lib polymer electrolyte |
| topic | polymer electrolytes bacterial cellulose ionic liquid carboxymethyl cellulose glycerol Li-ion batteries |
| url | https://doi.org/10.1088/2053-1591/acd67c |
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