Crystal structure of poly[dichlorido(μ-2,5-dicarboxybenzene-1,4-dicarboxylato-κ2O1:O4)bis[μ-4′-(pyridin-3-yl)-4,2′:6′,4′′-terpyridine-κ2N1:N4′]dizinc]
In the title polymeric ZnII complex, [Zn2(C10H4O8)Cl2(C20H14N4)2]n, the ZnII cations are bridged by both 2,5-dicarboxybenzene-1,4-dicarboxylate dianions and 4′-(pyridin-3-yl)-4,2′:6′,4′′-terpyridine ligands, forming ladder-like polymeric chains propagating along [1-10]. The Cl− anion further coordin...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2016-11-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989016016285 |
| _version_ | 1819005107199541248 |
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| author | Yue Tian Sha-Sha Xu Jian Su Yang Zhang Shao-Shuai Zhao Yu-Peng Tian |
| author_facet | Yue Tian Sha-Sha Xu Jian Su Yang Zhang Shao-Shuai Zhao Yu-Peng Tian |
| author_sort | Yue Tian |
| collection | DOAJ |
| description | In the title polymeric ZnII complex, [Zn2(C10H4O8)Cl2(C20H14N4)2]n, the ZnII cations are bridged by both 2,5-dicarboxybenzene-1,4-dicarboxylate dianions and 4′-(pyridin-3-yl)-4,2′:6′,4′′-terpyridine ligands, forming ladder-like polymeric chains propagating along [1-10]. The Cl− anion further coordinates the ZnII cation to complete a distorted tetrahedral environment. In the 4′-(pyridin-3-yl)-4,2′:6′,4′′-terpyridine ligand, the three sideward pyridine rings are twisted with respect to the central pyridine ring by 39.27 (12), 14.89 (13) and 3.36 (13)°, respectively. In the crystal, classical O—H...N hydrogen bonds and weak C—H...O and C—H...Cl hydrogen bonds link the chains into a three-dimensional supramolecular architecture. π–π stacking is observed between the pyridine and benzene rings of neighbouring polymeric chains, with a centroid-to-centroid distance of 3.7280 (14) Å. |
| first_indexed | 2024-12-20T23:47:32Z |
| format | Article |
| id | doaj.art-7c0a5196f57a405887d577b1756a60f5 |
| institution | Directory Open Access Journal |
| issn | 2056-9890 |
| language | English |
| last_indexed | 2024-12-20T23:47:32Z |
| publishDate | 2016-11-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E: Crystallographic Communications |
| spelling | doaj.art-7c0a5196f57a405887d577b1756a60f52022-12-21T19:22:55ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902016-11-0172111663166510.1107/S2056989016016285xu5893Crystal structure of poly[dichlorido(μ-2,5-dicarboxybenzene-1,4-dicarboxylato-κ2O1:O4)bis[μ-4′-(pyridin-3-yl)-4,2′:6′,4′′-terpyridine-κ2N1:N4′]dizinc]Yue Tian0Sha-Sha Xu1Jian Su2Yang Zhang3Shao-Shuai Zhao4Yu-Peng Tian5Department of Chemistry, Key Laboratory of Functional Inorganic Materials Chemistry of Anhui Province, Anhui University, Hefei 230601, People's Republic of ChinaDepartment of Chemistry, Key Laboratory of Functional Inorganic Materials Chemistry of Anhui Province, Anhui University, Hefei 230601, People's Republic of ChinaDepartment of Chemistry, Key Laboratory of Functional Inorganic Materials Chemistry of Anhui Province, Anhui University, Hefei 230601, People's Republic of ChinaDepartment of Chemistry, Key Laboratory of Functional Inorganic Materials Chemistry of Anhui Province, Anhui University, Hefei 230601, People's Republic of ChinaDepartment of Chemistry, Key Laboratory of Functional Inorganic Materials Chemistry of Anhui Province, Anhui University, Hefei 230601, People's Republic of ChinaDepartment of Chemistry, Key Laboratory of Functional Inorganic Materials Chemistry of Anhui Province, Anhui University, Hefei 230601, People's Republic of ChinaIn the title polymeric ZnII complex, [Zn2(C10H4O8)Cl2(C20H14N4)2]n, the ZnII cations are bridged by both 2,5-dicarboxybenzene-1,4-dicarboxylate dianions and 4′-(pyridin-3-yl)-4,2′:6′,4′′-terpyridine ligands, forming ladder-like polymeric chains propagating along [1-10]. The Cl− anion further coordinates the ZnII cation to complete a distorted tetrahedral environment. In the 4′-(pyridin-3-yl)-4,2′:6′,4′′-terpyridine ligand, the three sideward pyridine rings are twisted with respect to the central pyridine ring by 39.27 (12), 14.89 (13) and 3.36 (13)°, respectively. In the crystal, classical O—H...N hydrogen bonds and weak C—H...O and C—H...Cl hydrogen bonds link the chains into a three-dimensional supramolecular architecture. π–π stacking is observed between the pyridine and benzene rings of neighbouring polymeric chains, with a centroid-to-centroid distance of 3.7280 (14) Å.http://scripts.iucr.org/cgi-bin/paper?S2056989016016285crystal structure4′-(pyridin-3-yl)-4,2′:6′,4′′-terpyridinezinc(II) complexcoordination polymer |
| spellingShingle | Yue Tian Sha-Sha Xu Jian Su Yang Zhang Shao-Shuai Zhao Yu-Peng Tian Crystal structure of poly[dichlorido(μ-2,5-dicarboxybenzene-1,4-dicarboxylato-κ2O1:O4)bis[μ-4′-(pyridin-3-yl)-4,2′:6′,4′′-terpyridine-κ2N1:N4′]dizinc] Acta Crystallographica Section E: Crystallographic Communications crystal structure 4′-(pyridin-3-yl)-4,2′:6′,4′′-terpyridine zinc(II) complex coordination polymer |
| title | Crystal structure of poly[dichlorido(μ-2,5-dicarboxybenzene-1,4-dicarboxylato-κ2O1:O4)bis[μ-4′-(pyridin-3-yl)-4,2′:6′,4′′-terpyridine-κ2N1:N4′]dizinc] |
| title_full | Crystal structure of poly[dichlorido(μ-2,5-dicarboxybenzene-1,4-dicarboxylato-κ2O1:O4)bis[μ-4′-(pyridin-3-yl)-4,2′:6′,4′′-terpyridine-κ2N1:N4′]dizinc] |
| title_fullStr | Crystal structure of poly[dichlorido(μ-2,5-dicarboxybenzene-1,4-dicarboxylato-κ2O1:O4)bis[μ-4′-(pyridin-3-yl)-4,2′:6′,4′′-terpyridine-κ2N1:N4′]dizinc] |
| title_full_unstemmed | Crystal structure of poly[dichlorido(μ-2,5-dicarboxybenzene-1,4-dicarboxylato-κ2O1:O4)bis[μ-4′-(pyridin-3-yl)-4,2′:6′,4′′-terpyridine-κ2N1:N4′]dizinc] |
| title_short | Crystal structure of poly[dichlorido(μ-2,5-dicarboxybenzene-1,4-dicarboxylato-κ2O1:O4)bis[μ-4′-(pyridin-3-yl)-4,2′:6′,4′′-terpyridine-κ2N1:N4′]dizinc] |
| title_sort | crystal structure of poly dichlorido μ 2 5 dicarboxybenzene 1 4 dicarboxylato κ2o1 o4 bis μ 4 pyridin 3 yl 4 2 6 4 terpyridine κ2n1 n4 dizinc |
| topic | crystal structure 4′-(pyridin-3-yl)-4,2′:6′,4′′-terpyridine zinc(II) complex coordination polymer |
| url | http://scripts.iucr.org/cgi-bin/paper?S2056989016016285 |
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