Transition Bimetal Based MOF Nanosheets for Robust Aqueous Zn Battery

High-performance, good stability, low-cost, and environmentally friendly batteries are important for multifunctional electronics and electric vehicles. Compared with the high-energy density lithium-ion batteries, aqueous rechargeable battery has been extensively researched due to high safety, low co...

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Main Authors: Jun Wan, Junfeng Li, Zhiheng Xiao, Dandan Tang, Bo Wang, Yongjun Xiao, Weilin Xu
Format: Article
Language:English
Published: Frontiers Media S.A. 2020-06-01
Series:Frontiers in Materials
Subjects:
Online Access:https://www.frontiersin.org/article/10.3389/fmats.2020.00194/full
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author Jun Wan
Jun Wan
Junfeng Li
Junfeng Li
Zhiheng Xiao
Dandan Tang
Bo Wang
Yongjun Xiao
Weilin Xu
author_facet Jun Wan
Jun Wan
Junfeng Li
Junfeng Li
Zhiheng Xiao
Dandan Tang
Bo Wang
Yongjun Xiao
Weilin Xu
author_sort Jun Wan
collection DOAJ
description High-performance, good stability, low-cost, and environmentally friendly batteries are important for multifunctional electronics and electric vehicles. Compared with the high-energy density lithium-ion batteries, aqueous rechargeable battery has been extensively researched due to high safety, low cost and much better rate performance. Here, we report a one-step approach to fabricate porous Ni-Cu metal–organic framework (MOF) nanosheet arrays structures for stable energy storage with a high-energy (71.2 mWh cm−3) and high-stability (capacity retention of ≈91% after 2,500 cycles) performance. Furthermore, we synthesized various porous homogeneous Ni-Co, Ni-Zn, Ni-Fe and Ni-Mn bimetal MOF structures with high surface area and conductivity utilizing this rational design. This work provides a simple efficient strategy for constructing porous homogeneous bimetal MOF nanosheet arrays with high energy and stability performance, holding a great potential for future portable electronics.
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spelling doaj.art-7c0b16405b5043b0a012859e1827ddb22022-12-22T01:22:37ZengFrontiers Media S.A.Frontiers in Materials2296-80162020-06-01710.3389/fmats.2020.00194556145Transition Bimetal Based MOF Nanosheets for Robust Aqueous Zn BatteryJun Wan0Jun Wan1Junfeng Li2Junfeng Li3Zhiheng Xiao4Dandan Tang5Bo Wang6Yongjun Xiao7Weilin Xu8State Key Laboratory for Hubei New Textile Materials and Advanced Processing Technology, Wuhan Textile University, Wuhan, ChinaHubei Key Laboratory of Biomass Fiber and Ecological Dyeing and Finishing, School of Chemistry and Chemical Engineering, Wuhan Textile University, Wuhan, ChinaState Key Laboratory for Hubei New Textile Materials and Advanced Processing Technology, Wuhan Textile University, Wuhan, ChinaHubei Key Laboratory of Biomass Fiber and Ecological Dyeing and Finishing, School of Chemistry and Chemical Engineering, Wuhan Textile University, Wuhan, ChinaState Key Laboratory for Hubei New Textile Materials and Advanced Processing Technology, Wuhan Textile University, Wuhan, ChinaInstitute of China Rural Studies, Central China Normal University, Wuhan, ChinaSchool of Electrical Engineering and Automation, Luoyang Institute of Science and Technology, Luoyang, ChinaSchool of Physics and Electronic Information Engineering, Hubei Engineering University, Xiaogan, ChinaState Key Laboratory for Hubei New Textile Materials and Advanced Processing Technology, Wuhan Textile University, Wuhan, ChinaHigh-performance, good stability, low-cost, and environmentally friendly batteries are important for multifunctional electronics and electric vehicles. Compared with the high-energy density lithium-ion batteries, aqueous rechargeable battery has been extensively researched due to high safety, low cost and much better rate performance. Here, we report a one-step approach to fabricate porous Ni-Cu metal–organic framework (MOF) nanosheet arrays structures for stable energy storage with a high-energy (71.2 mWh cm−3) and high-stability (capacity retention of ≈91% after 2,500 cycles) performance. Furthermore, we synthesized various porous homogeneous Ni-Co, Ni-Zn, Ni-Fe and Ni-Mn bimetal MOF structures with high surface area and conductivity utilizing this rational design. This work provides a simple efficient strategy for constructing porous homogeneous bimetal MOF nanosheet arrays with high energy and stability performance, holding a great potential for future portable electronics.https://www.frontiersin.org/article/10.3389/fmats.2020.00194/fullbimetalmetal organic frameworknanosheethigh-stabilityZn battery
spellingShingle Jun Wan
Jun Wan
Junfeng Li
Junfeng Li
Zhiheng Xiao
Dandan Tang
Bo Wang
Yongjun Xiao
Weilin Xu
Transition Bimetal Based MOF Nanosheets for Robust Aqueous Zn Battery
Frontiers in Materials
bimetal
metal organic framework
nanosheet
high-stability
Zn battery
title Transition Bimetal Based MOF Nanosheets for Robust Aqueous Zn Battery
title_full Transition Bimetal Based MOF Nanosheets for Robust Aqueous Zn Battery
title_fullStr Transition Bimetal Based MOF Nanosheets for Robust Aqueous Zn Battery
title_full_unstemmed Transition Bimetal Based MOF Nanosheets for Robust Aqueous Zn Battery
title_short Transition Bimetal Based MOF Nanosheets for Robust Aqueous Zn Battery
title_sort transition bimetal based mof nanosheets for robust aqueous zn battery
topic bimetal
metal organic framework
nanosheet
high-stability
Zn battery
url https://www.frontiersin.org/article/10.3389/fmats.2020.00194/full
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AT zhihengxiao transitionbimetalbasedmofnanosheetsforrobustaqueousznbattery
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