Microstructure Evolution and Shear Strength of Tin-Indium-xCu/Cu Joints

The low melting temperature In-48Sn alloy is a promising candidate for flexible devices. However, the joint strength of the In-48Sn alloy on the Cu substrate was low due to the rapid diffusion of Cu into the In-rich alloy. In this study, the effect of the addition of xCu (x = 2.0 and 8.0 wt.%) on we...

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Main Authors: Duy Le Han, Yu-An Shen, Fupeng Huo, Hiroshi Nishikawa
Format: Article
Language:English
Published: MDPI AG 2021-12-01
Series:Metals
Subjects:
Online Access:https://www.mdpi.com/2075-4701/12/1/33
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author Duy Le Han
Yu-An Shen
Fupeng Huo
Hiroshi Nishikawa
author_facet Duy Le Han
Yu-An Shen
Fupeng Huo
Hiroshi Nishikawa
author_sort Duy Le Han
collection DOAJ
description The low melting temperature In-48Sn alloy is a promising candidate for flexible devices. However, the joint strength of the In-48Sn alloy on the Cu substrate was low due to the rapid diffusion of Cu into the In-rich alloy. In this study, the effect of the addition of xCu (x = 2.0 and 8.0 wt.%) on wettability, interfacial reaction, and mechanical strength of the In-Sn-xCu/Cu joint is analyzed. The results demonstrate that both the In-48Sn and In-Sn-xCu alloys exhibit good wettability on the Cu substrate and that the contact angle increases with an increase in the Cu content. Furthermore, fine grains are observed in the alloy matrix of the In-Sn-xCu/Cu joint and the interfacial intermetallic compound (IMC) comprising the Cu-rich Cu<sub>6</sub>(In,Sn)<sub>5</sub> near the Cu substrate and the Cu-deficient Cu(In,Sn)<sub>2</sub> near the solder side. The In-Sn-2.0Cu/Cu joint with fine microstructure and a small amount of IMC in the alloy matrix shows the highest average shear strength of 16.5 MPa. Although the In-Sn-8.0Cu/Cu joint also exhibits fine grains, the presence of large number of voids and rough interfacial IMC layer causes the formation of additional stress concentration points, thereby reducing the average shear strength of the joint.
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spelling doaj.art-7c42daad971440abb8b2e1d178e4ba122023-11-23T14:41:17ZengMDPI AGMetals2075-47012021-12-011213310.3390/met12010033Microstructure Evolution and Shear Strength of Tin-Indium-xCu/Cu JointsDuy Le Han0Yu-An Shen1Fupeng Huo2Hiroshi Nishikawa3Joining and Welding Research Institute, Osaka University, Osaka 567-0047, JapanDepartment of Materials Science and Engineering, Feng Chia University, Taichung 407, TaiwanJoining and Welding Research Institute, Osaka University, Osaka 567-0047, JapanJoining and Welding Research Institute, Osaka University, Osaka 567-0047, JapanThe low melting temperature In-48Sn alloy is a promising candidate for flexible devices. However, the joint strength of the In-48Sn alloy on the Cu substrate was low due to the rapid diffusion of Cu into the In-rich alloy. In this study, the effect of the addition of xCu (x = 2.0 and 8.0 wt.%) on wettability, interfacial reaction, and mechanical strength of the In-Sn-xCu/Cu joint is analyzed. The results demonstrate that both the In-48Sn and In-Sn-xCu alloys exhibit good wettability on the Cu substrate and that the contact angle increases with an increase in the Cu content. Furthermore, fine grains are observed in the alloy matrix of the In-Sn-xCu/Cu joint and the interfacial intermetallic compound (IMC) comprising the Cu-rich Cu<sub>6</sub>(In,Sn)<sub>5</sub> near the Cu substrate and the Cu-deficient Cu(In,Sn)<sub>2</sub> near the solder side. The In-Sn-2.0Cu/Cu joint with fine microstructure and a small amount of IMC in the alloy matrix shows the highest average shear strength of 16.5 MPa. Although the In-Sn-8.0Cu/Cu joint also exhibits fine grains, the presence of large number of voids and rough interfacial IMC layer causes the formation of additional stress concentration points, thereby reducing the average shear strength of the joint.https://www.mdpi.com/2075-4701/12/1/33low-temperature alloyIn-48Sn alloyinterfacial reactionsolder joint strengthshear fracture surfacewettability
spellingShingle Duy Le Han
Yu-An Shen
Fupeng Huo
Hiroshi Nishikawa
Microstructure Evolution and Shear Strength of Tin-Indium-xCu/Cu Joints
Metals
low-temperature alloy
In-48Sn alloy
interfacial reaction
solder joint strength
shear fracture surface
wettability
title Microstructure Evolution and Shear Strength of Tin-Indium-xCu/Cu Joints
title_full Microstructure Evolution and Shear Strength of Tin-Indium-xCu/Cu Joints
title_fullStr Microstructure Evolution and Shear Strength of Tin-Indium-xCu/Cu Joints
title_full_unstemmed Microstructure Evolution and Shear Strength of Tin-Indium-xCu/Cu Joints
title_short Microstructure Evolution and Shear Strength of Tin-Indium-xCu/Cu Joints
title_sort microstructure evolution and shear strength of tin indium xcu cu joints
topic low-temperature alloy
In-48Sn alloy
interfacial reaction
solder joint strength
shear fracture surface
wettability
url https://www.mdpi.com/2075-4701/12/1/33
work_keys_str_mv AT duylehan microstructureevolutionandshearstrengthoftinindiumxcucujoints
AT yuanshen microstructureevolutionandshearstrengthoftinindiumxcucujoints
AT fupenghuo microstructureevolutionandshearstrengthoftinindiumxcucujoints
AT hiroshinishikawa microstructureevolutionandshearstrengthoftinindiumxcucujoints