Recovery and Characterization Studies of Post-Production Alloy Waste from the Automotive Industry

Superalloys provide high corrosion resistance and are widely used as high-performance materials in aerospace, automotive, chemical, and other industries. Herein, the investigation into the characteristics and properties of alloy waste; Inconel 625, Inconel 718, and Titanium Grade 5, from the automot...

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Main Authors: Sylwester Żelazny, Witold Żukowski, Dariusz Bogdał, Szczepan Bednarz, Wiktor Kasprzyk, Tomasz Świergosz
Format: Article
Language:English
Published: MDPI AG 2020-12-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/13/24/5600
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author Sylwester Żelazny
Witold Żukowski
Dariusz Bogdał
Szczepan Bednarz
Wiktor Kasprzyk
Tomasz Świergosz
author_facet Sylwester Żelazny
Witold Żukowski
Dariusz Bogdał
Szczepan Bednarz
Wiktor Kasprzyk
Tomasz Świergosz
author_sort Sylwester Żelazny
collection DOAJ
description Superalloys provide high corrosion resistance and are widely used as high-performance materials in aerospace, automotive, chemical, and other industries. Herein, the investigation into the characteristics and properties of alloy waste; Inconel 625, Inconel 718, and Titanium Grade 5, from the automotive industry, was introduced as a result of a recovery in various processes. For this reason, the following procedures were carried as follows; the washing process to remove oil from the swarf was evaluated using several commercial agents and for the process of thermal disposal of processing fluids, a temperature of 900 °C was used in a muffle furnace without air access. The presented studies show that the commercially available series of washing agents did not modify the composition of the surface. However, the high temperatures during the calcination of oil residues are affecting the elemental composition of the alloys. According to the results of the analyses, it is not possible to remove 100% of the oil residues from alloy waste using washing agents based on light organic fractions; however, the effectiveness of this method reaches 99%. In this report, accurate SEM-EDS analyses show changes that occur on the surface after machining and removal of processing fluids. The NMR and GC/MS investigations indicate contaminants as a mixture of aliphatic and cycloaliphatic hydrocarbons with carbon numbers from C8–C30.
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spelling doaj.art-7c97c29bc3a44dc28e770caf79b6dd8b2023-11-20T23:54:56ZengMDPI AGMaterials1996-19442020-12-011324560010.3390/ma13245600Recovery and Characterization Studies of Post-Production Alloy Waste from the Automotive IndustrySylwester Żelazny0Witold Żukowski1Dariusz Bogdał2Szczepan Bednarz3Wiktor Kasprzyk4Tomasz Świergosz5Department of Inorganic Chemistry, Faculty of Chemical Engineering and Technology, Cracow University of Technology, Warszawska 24, 31-155 Kraków, PolandDepartment of Inorganic Chemistry, Faculty of Chemical Engineering and Technology, Cracow University of Technology, Warszawska 24, 31-155 Kraków, PolandDepartment of Biotechnology and Physical Chemistry, Faculty of Chemical Engineering and Technology, Cracow University of Technology, Warszawska 24, 31-155 Kraków, PolandDepartment of Biotechnology and Physical Chemistry, Faculty of Chemical Engineering and Technology, Cracow University of Technology, Warszawska 24, 31-155 Kraków, PolandDepartment of Biotechnology and Physical Chemistry, Faculty of Chemical Engineering and Technology, Cracow University of Technology, Warszawska 24, 31-155 Kraków, PolandDepartment of Analytical Chemistry, Faculty of Chemical Engineering and Technology, Cracow University of Technology, Warszawska 24, 31-155 Kraków, PolandSuperalloys provide high corrosion resistance and are widely used as high-performance materials in aerospace, automotive, chemical, and other industries. Herein, the investigation into the characteristics and properties of alloy waste; Inconel 625, Inconel 718, and Titanium Grade 5, from the automotive industry, was introduced as a result of a recovery in various processes. For this reason, the following procedures were carried as follows; the washing process to remove oil from the swarf was evaluated using several commercial agents and for the process of thermal disposal of processing fluids, a temperature of 900 °C was used in a muffle furnace without air access. The presented studies show that the commercially available series of washing agents did not modify the composition of the surface. However, the high temperatures during the calcination of oil residues are affecting the elemental composition of the alloys. According to the results of the analyses, it is not possible to remove 100% of the oil residues from alloy waste using washing agents based on light organic fractions; however, the effectiveness of this method reaches 99%. In this report, accurate SEM-EDS analyses show changes that occur on the surface after machining and removal of processing fluids. The NMR and GC/MS investigations indicate contaminants as a mixture of aliphatic and cycloaliphatic hydrocarbons with carbon numbers from C8–C30.https://www.mdpi.com/1996-1944/13/24/5600alloy wasteInconel 625Inconel 718Titanium Grade 5thermal processwashing process
spellingShingle Sylwester Żelazny
Witold Żukowski
Dariusz Bogdał
Szczepan Bednarz
Wiktor Kasprzyk
Tomasz Świergosz
Recovery and Characterization Studies of Post-Production Alloy Waste from the Automotive Industry
Materials
alloy waste
Inconel 625
Inconel 718
Titanium Grade 5
thermal process
washing process
title Recovery and Characterization Studies of Post-Production Alloy Waste from the Automotive Industry
title_full Recovery and Characterization Studies of Post-Production Alloy Waste from the Automotive Industry
title_fullStr Recovery and Characterization Studies of Post-Production Alloy Waste from the Automotive Industry
title_full_unstemmed Recovery and Characterization Studies of Post-Production Alloy Waste from the Automotive Industry
title_short Recovery and Characterization Studies of Post-Production Alloy Waste from the Automotive Industry
title_sort recovery and characterization studies of post production alloy waste from the automotive industry
topic alloy waste
Inconel 625
Inconel 718
Titanium Grade 5
thermal process
washing process
url https://www.mdpi.com/1996-1944/13/24/5600
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AT witoldzukowski recoveryandcharacterizationstudiesofpostproductionalloywastefromtheautomotiveindustry
AT dariuszbogdał recoveryandcharacterizationstudiesofpostproductionalloywastefromtheautomotiveindustry
AT szczepanbednarz recoveryandcharacterizationstudiesofpostproductionalloywastefromtheautomotiveindustry
AT wiktorkasprzyk recoveryandcharacterizationstudiesofpostproductionalloywastefromtheautomotiveindustry
AT tomaszswiergosz recoveryandcharacterizationstudiesofpostproductionalloywastefromtheautomotiveindustry