Oxidative Dearomatization of Phenols and Anilines via λ3- and λ5-Iodane-Mediated Phenylation and Oxygenation
Treatment of 2-methylphenols with chloro(diphenyl)-λ3-iodane led to theirregioselective dearomatizing 2-phenylation into cyclohexa-2,4-dienone derivatives via aproposed ligand coupling reaction. In the same vein of investigation, treatment of2-methylanilines with the λ5-iodane 2-iodoxybenzoic...
Main Authors: | J. Gagnepain, A. Ozanne, L. Pouységu, S. Quideau |
---|---|
Format: | Article |
Language: | English |
Published: |
MDPI AG
2005-01-01
|
Series: | Molecules |
Subjects: | |
Online Access: | http://www.mdpi.com/1420-3049/10/1/201/ |
Similar Items
-
Addition to Electron Deficient Olefins of α-Oxy Carbon- Centered Radicals, Generated from Cyclic Ethers and Acetals by the Reaction with Alkylperoxy- λ3-iodane
by: M. Ochiai, et al.
Published: (2005-01-01) -
Efficient Oxidative Dearomatisations of Substituted Phenols Using Hypervalent Iodine (III) Reagents and Antiprotozoal Evaluation of the Resulting Cyclohexadienones against <i>T. b. rhodesiense</i> and <i>P. falciparum</i> Strain NF54
by: Nina Scheiber, et al.
Published: (2022-10-01) -
Nucleophilic dearomatization of 4-aza-6-nitrobenzofuroxan by CH acids in the synthesis of pharmacology-oriented compounds
by: Alexey M. Starosotnikov, et al.
Published: (2017-12-01) -
Phosphazene-catalyzed desymmetrization of cyclohexadienones by dithiane addition
by: Matthew A. Horwitz, et al.
Published: (2017-04-01) -
Arenophile-Mediated Photochemical Dearomatization of Nonactivated Arenes
by: Mikiko Okumura, et al.
Published: (2020-08-01)