Development of a Detection Algorithm for Use with Reflectance-Based, Real-Time Chemical Sensing

Here, we describe our efforts focused on development of an algorithm for identification of detection events in a real-time sensing application relying on reporting of color values using commercially available color sensing chips. The effort focuses on the identification of event occurrence, rather t...

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Main Authors: Anthony P. Malanoski, Brandy J. Johnson, Jeffrey S. Erickson, David A. Stenger
Format: Article
Language:English
Published: MDPI AG 2016-11-01
Series:Sensors
Subjects:
Online Access:http://www.mdpi.com/1424-8220/16/11/1927
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author Anthony P. Malanoski
Brandy J. Johnson
Jeffrey S. Erickson
David A. Stenger
author_facet Anthony P. Malanoski
Brandy J. Johnson
Jeffrey S. Erickson
David A. Stenger
author_sort Anthony P. Malanoski
collection DOAJ
description Here, we describe our efforts focused on development of an algorithm for identification of detection events in a real-time sensing application relying on reporting of color values using commercially available color sensing chips. The effort focuses on the identification of event occurrence, rather than target identification, and utilizes approaches suitable to onboard device incorporation to facilitate portable and autonomous use. The described algorithm first excludes electronic noise generated by the sensor system and determines response thresholds. This automatic adjustment provides the potential for use with device variations as well as accommodating differing indicator behaviors. Multiple signal channels (RGB) as well as multiple indicator array elements are combined for reporting of an event with a minimum of false responses. While the method reported was developed for use with paper-supported porphyrin and metalloporphyrin indicators, it should be equally applicable to other colorimetric indicators. Depending on device configurations, receiver operating characteristic (ROC) sensitivities of 1 could be obtained with specificities of 0.87 (threshold 160 ppb, ethanol).
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spelling doaj.art-7cb76dae3d9a4aafa8ba05886f3de6c92022-12-22T04:24:12ZengMDPI AGSensors1424-82202016-11-011611192710.3390/s16111927s16111927Development of a Detection Algorithm for Use with Reflectance-Based, Real-Time Chemical SensingAnthony P. Malanoski0Brandy J. Johnson1Jeffrey S. Erickson2David A. Stenger3Center for Bio/Molecular Science & Engineering, Naval Research Laboratory, Washington, DC 20375, USACenter for Bio/Molecular Science & Engineering, Naval Research Laboratory, Washington, DC 20375, USACenter for Bio/Molecular Science & Engineering, Naval Research Laboratory, Washington, DC 20375, USACenter for Bio/Molecular Science & Engineering, Naval Research Laboratory, Washington, DC 20375, USAHere, we describe our efforts focused on development of an algorithm for identification of detection events in a real-time sensing application relying on reporting of color values using commercially available color sensing chips. The effort focuses on the identification of event occurrence, rather than target identification, and utilizes approaches suitable to onboard device incorporation to facilitate portable and autonomous use. The described algorithm first excludes electronic noise generated by the sensor system and determines response thresholds. This automatic adjustment provides the potential for use with device variations as well as accommodating differing indicator behaviors. Multiple signal channels (RGB) as well as multiple indicator array elements are combined for reporting of an event with a minimum of false responses. While the method reported was developed for use with paper-supported porphyrin and metalloporphyrin indicators, it should be equally applicable to other colorimetric indicators. Depending on device configurations, receiver operating characteristic (ROC) sensitivities of 1 could be obtained with specificities of 0.87 (threshold 160 ppb, ethanol).http://www.mdpi.com/1424-8220/16/11/1927colorimetricsensorchemical detectoralgorithmautonomous
spellingShingle Anthony P. Malanoski
Brandy J. Johnson
Jeffrey S. Erickson
David A. Stenger
Development of a Detection Algorithm for Use with Reflectance-Based, Real-Time Chemical Sensing
Sensors
colorimetric
sensor
chemical detector
algorithm
autonomous
title Development of a Detection Algorithm for Use with Reflectance-Based, Real-Time Chemical Sensing
title_full Development of a Detection Algorithm for Use with Reflectance-Based, Real-Time Chemical Sensing
title_fullStr Development of a Detection Algorithm for Use with Reflectance-Based, Real-Time Chemical Sensing
title_full_unstemmed Development of a Detection Algorithm for Use with Reflectance-Based, Real-Time Chemical Sensing
title_short Development of a Detection Algorithm for Use with Reflectance-Based, Real-Time Chemical Sensing
title_sort development of a detection algorithm for use with reflectance based real time chemical sensing
topic colorimetric
sensor
chemical detector
algorithm
autonomous
url http://www.mdpi.com/1424-8220/16/11/1927
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AT brandyjjohnson developmentofadetectionalgorithmforusewithreflectancebasedrealtimechemicalsensing
AT jeffreyserickson developmentofadetectionalgorithmforusewithreflectancebasedrealtimechemicalsensing
AT davidastenger developmentofadetectionalgorithmforusewithreflectancebasedrealtimechemicalsensing