A numerical model of a zinc-para-benzoquinone membrane-free organic flow battery

Organic flow batteries have received a great deal of interest in the past five years as potential candidates for large-scale energy storage, due to their low costs, abundant active materials and multi-electron transfers. Membrane-less systems are particular attractive given the cost of high-performa...

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Main Authors: Feilin Yu, Akeel Shah, Puiki Leung
Format: Article
Language:English
Published: Elsevier 2022-11-01
Series:Energy Reports
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2352484722010964
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author Feilin Yu
Akeel Shah
Puiki Leung
author_facet Feilin Yu
Akeel Shah
Puiki Leung
author_sort Feilin Yu
collection DOAJ
description Organic flow batteries have received a great deal of interest in the past five years as potential candidates for large-scale energy storage, due to their low costs, abundant active materials and multi-electron transfers. Membrane-less systems are particular attractive given the cost of high-performance membranes such as Nafion©. To overcome known limitations, and to design and optimize new systems, modeling and simulation can play a vital role. In this paper, a two-dimensional transient model of a membrane-less zinc-quinone flow battery incorporating the conservation of mass, charge and momentum in the battery and reservoir is developed and validated. The performance is studied under the influence of different electrolyte flow regimes and variations in key parameters, in order to provide new insights and recommendations for further development of the system, as well as similar systems.
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spelling doaj.art-7d00163724a94326a7b48945d79bd9632023-01-20T04:25:30ZengElsevierEnergy Reports2352-48472022-11-01811581165A numerical model of a zinc-para-benzoquinone membrane-free organic flow batteryFeilin Yu0Akeel Shah1Puiki Leung2Key Laboratory of Low-grade Energy Utilization Technologies and Systems, MOE, Chongqing University, Chongqing, 400030, ChinaCorresponding author.; Key Laboratory of Low-grade Energy Utilization Technologies and Systems, MOE, Chongqing University, Chongqing, 400030, ChinaKey Laboratory of Low-grade Energy Utilization Technologies and Systems, MOE, Chongqing University, Chongqing, 400030, ChinaOrganic flow batteries have received a great deal of interest in the past five years as potential candidates for large-scale energy storage, due to their low costs, abundant active materials and multi-electron transfers. Membrane-less systems are particular attractive given the cost of high-performance membranes such as Nafion©. To overcome known limitations, and to design and optimize new systems, modeling and simulation can play a vital role. In this paper, a two-dimensional transient model of a membrane-less zinc-quinone flow battery incorporating the conservation of mass, charge and momentum in the battery and reservoir is developed and validated. The performance is studied under the influence of different electrolyte flow regimes and variations in key parameters, in order to provide new insights and recommendations for further development of the system, as well as similar systems.http://www.sciencedirect.com/science/article/pii/S2352484722010964Membrane free organic flow batteryZinc-quinone batteryNumerical modelEnergy storage
spellingShingle Feilin Yu
Akeel Shah
Puiki Leung
A numerical model of a zinc-para-benzoquinone membrane-free organic flow battery
Energy Reports
Membrane free organic flow battery
Zinc-quinone battery
Numerical model
Energy storage
title A numerical model of a zinc-para-benzoquinone membrane-free organic flow battery
title_full A numerical model of a zinc-para-benzoquinone membrane-free organic flow battery
title_fullStr A numerical model of a zinc-para-benzoquinone membrane-free organic flow battery
title_full_unstemmed A numerical model of a zinc-para-benzoquinone membrane-free organic flow battery
title_short A numerical model of a zinc-para-benzoquinone membrane-free organic flow battery
title_sort numerical model of a zinc para benzoquinone membrane free organic flow battery
topic Membrane free organic flow battery
Zinc-quinone battery
Numerical model
Energy storage
url http://www.sciencedirect.com/science/article/pii/S2352484722010964
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