Bis[N,N-bis(diphenylphosphanyl)cyclohexylamine-κ2P,P′]platinum(II) bis(hexafluoridophosphate) dichloromethane disolvate
In the title compound, [Pt(C30H31NP2)2](PF6)2·2CH2Cl2, the four-coordinated PtII atom, situated on an inversion centre, exhibits a highly distorted square-planar geometry illustrated by the P—Pt—P bite angle of 70.76 (3)°. The cyclo...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2010-08-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810028795 |
| Summary: | In the title compound, [Pt(C30H31NP2)2](PF6)2·2CH2Cl2, the four-coordinated PtII atom, situated on an inversion centre, exhibits a highly distorted square-planar geometry illustrated by the P—Pt—P bite angle of 70.76 (3)°. The cyclohexyl ring and one of the phenyl rings display 0.630 (7):0.37 (7) and 0.60 (2):0.40 (2) positional disorder, respectively. The dichloromethane solvent molecule displays 0.526 (4):0.474 (4) positional disorder. C—H...F hydrogen bonds stabilize the crystal packing. |
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| ISSN: | 1600-5368 |