Bis[N,N-bis(diphenylphosphanyl)cyclohexylamine-κ2P,P′]platinum(II) bis(hexafluoridophosphate) dichloromethane disolvate

In the title compound, [Pt(C30H31NP2)2](PF6)2·2CH2Cl2, the four-coordinated PtII atom, situated on an inversion centre, exhibits a highly distorted square-planar geometry illustrated by the P—Pt—P bite angle of 70.76 (3)°. The cyclo...

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Main Authors: Ilana Engelbrecht, Hendrik G. Visser, Andreas Roodt
Format: Article
Language:English
Published: International Union of Crystallography 2010-08-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810028795
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author Ilana Engelbrecht
Hendrik G. Visser
Andreas Roodt
author_facet Ilana Engelbrecht
Hendrik G. Visser
Andreas Roodt
author_sort Ilana Engelbrecht
collection DOAJ
description In the title compound, [Pt(C30H31NP2)2](PF6)2·2CH2Cl2, the four-coordinated PtII atom, situated on an inversion centre, exhibits a highly distorted square-planar geometry illustrated by the P—Pt—P bite angle of 70.76 (3)°. The cyclohexyl ring and one of the phenyl rings display 0.630 (7):0.37 (7) and 0.60 (2):0.40 (2) positional disorder, respectively. The dichloromethane solvent molecule displays 0.526 (4):0.474 (4) positional disorder. C—H...F hydrogen bonds stabilize the crystal packing.
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spelling doaj.art-7d08d9bdeb7048ea925ae571764afdde2022-12-21T21:10:01ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-08-01668m994m99510.1107/S1600536810028795Bis[N,N-bis(diphenylphosphanyl)cyclohexylamine-κ2P,P′]platinum(II) bis(hexafluoridophosphate) dichloromethane disolvateIlana EngelbrechtHendrik G. VisserAndreas RoodtIn the title compound, [Pt(C30H31NP2)2](PF6)2·2CH2Cl2, the four-coordinated PtII atom, situated on an inversion centre, exhibits a highly distorted square-planar geometry illustrated by the P—Pt—P bite angle of 70.76 (3)°. The cyclohexyl ring and one of the phenyl rings display 0.630 (7):0.37 (7) and 0.60 (2):0.40 (2) positional disorder, respectively. The dichloromethane solvent molecule displays 0.526 (4):0.474 (4) positional disorder. C—H...F hydrogen bonds stabilize the crystal packing.http://scripts.iucr.org/cgi-bin/paper?S1600536810028795
spellingShingle Ilana Engelbrecht
Hendrik G. Visser
Andreas Roodt
Bis[N,N-bis(diphenylphosphanyl)cyclohexylamine-κ2P,P′]platinum(II) bis(hexafluoridophosphate) dichloromethane disolvate
Acta Crystallographica Section E
title Bis[N,N-bis(diphenylphosphanyl)cyclohexylamine-κ2P,P′]platinum(II) bis(hexafluoridophosphate) dichloromethane disolvate
title_full Bis[N,N-bis(diphenylphosphanyl)cyclohexylamine-κ2P,P′]platinum(II) bis(hexafluoridophosphate) dichloromethane disolvate
title_fullStr Bis[N,N-bis(diphenylphosphanyl)cyclohexylamine-κ2P,P′]platinum(II) bis(hexafluoridophosphate) dichloromethane disolvate
title_full_unstemmed Bis[N,N-bis(diphenylphosphanyl)cyclohexylamine-κ2P,P′]platinum(II) bis(hexafluoridophosphate) dichloromethane disolvate
title_short Bis[N,N-bis(diphenylphosphanyl)cyclohexylamine-κ2P,P′]platinum(II) bis(hexafluoridophosphate) dichloromethane disolvate
title_sort bis n n bis diphenylphosphanyl cyclohexylamine amp 954 2p p amp 8242 platinum ii bis hexafluoridophosphate dichloromethane disolvate
url http://scripts.iucr.org/cgi-bin/paper?S1600536810028795
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AT hendrikgvisser bisnnbisdiphenylphosphanylcyclohexylamineamp9542ppamp8242platinumiibishexafluoridophosphatedichloromethanedisolvate
AT andreasroodt bisnnbisdiphenylphosphanylcyclohexylamineamp9542ppamp8242platinumiibishexafluoridophosphatedichloromethanedisolvate