Bis[N,N-bis(diphenylphosphanyl)cyclohexylamine-κ2P,P′]platinum(II) bis(hexafluoridophosphate) dichloromethane disolvate
In the title compound, [Pt(C30H31NP2)2](PF6)2·2CH2Cl2, the four-coordinated PtII atom, situated on an inversion centre, exhibits a highly distorted square-planar geometry illustrated by the P—Pt—P bite angle of 70.76 (3)°. The cyclo...
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Format: | Article |
Language: | English |
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International Union of Crystallography
2010-08-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810028795 |
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author | Ilana Engelbrecht Hendrik G. Visser Andreas Roodt |
author_facet | Ilana Engelbrecht Hendrik G. Visser Andreas Roodt |
author_sort | Ilana Engelbrecht |
collection | DOAJ |
description | In the title compound, [Pt(C30H31NP2)2](PF6)2·2CH2Cl2, the four-coordinated PtII atom, situated on an inversion centre, exhibits a highly distorted square-planar geometry illustrated by the P—Pt—P bite angle of 70.76 (3)°. The cyclohexyl ring and one of the phenyl rings display 0.630 (7):0.37 (7) and 0.60 (2):0.40 (2) positional disorder, respectively. The dichloromethane solvent molecule displays 0.526 (4):0.474 (4) positional disorder. C—H...F hydrogen bonds stabilize the crystal packing. |
first_indexed | 2024-12-18T11:08:47Z |
format | Article |
id | doaj.art-7d08d9bdeb7048ea925ae571764afdde |
institution | Directory Open Access Journal |
issn | 1600-5368 |
language | English |
last_indexed | 2024-12-18T11:08:47Z |
publishDate | 2010-08-01 |
publisher | International Union of Crystallography |
record_format | Article |
series | Acta Crystallographica Section E |
spelling | doaj.art-7d08d9bdeb7048ea925ae571764afdde2022-12-21T21:10:01ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-08-01668m994m99510.1107/S1600536810028795Bis[N,N-bis(diphenylphosphanyl)cyclohexylamine-κ2P,P′]platinum(II) bis(hexafluoridophosphate) dichloromethane disolvateIlana EngelbrechtHendrik G. VisserAndreas RoodtIn the title compound, [Pt(C30H31NP2)2](PF6)2·2CH2Cl2, the four-coordinated PtII atom, situated on an inversion centre, exhibits a highly distorted square-planar geometry illustrated by the P—Pt—P bite angle of 70.76 (3)°. The cyclohexyl ring and one of the phenyl rings display 0.630 (7):0.37 (7) and 0.60 (2):0.40 (2) positional disorder, respectively. The dichloromethane solvent molecule displays 0.526 (4):0.474 (4) positional disorder. C—H...F hydrogen bonds stabilize the crystal packing.http://scripts.iucr.org/cgi-bin/paper?S1600536810028795 |
spellingShingle | Ilana Engelbrecht Hendrik G. Visser Andreas Roodt Bis[N,N-bis(diphenylphosphanyl)cyclohexylamine-κ2P,P′]platinum(II) bis(hexafluoridophosphate) dichloromethane disolvate Acta Crystallographica Section E |
title | Bis[N,N-bis(diphenylphosphanyl)cyclohexylamine-κ2P,P′]platinum(II) bis(hexafluoridophosphate) dichloromethane disolvate |
title_full | Bis[N,N-bis(diphenylphosphanyl)cyclohexylamine-κ2P,P′]platinum(II) bis(hexafluoridophosphate) dichloromethane disolvate |
title_fullStr | Bis[N,N-bis(diphenylphosphanyl)cyclohexylamine-κ2P,P′]platinum(II) bis(hexafluoridophosphate) dichloromethane disolvate |
title_full_unstemmed | Bis[N,N-bis(diphenylphosphanyl)cyclohexylamine-κ2P,P′]platinum(II) bis(hexafluoridophosphate) dichloromethane disolvate |
title_short | Bis[N,N-bis(diphenylphosphanyl)cyclohexylamine-κ2P,P′]platinum(II) bis(hexafluoridophosphate) dichloromethane disolvate |
title_sort | bis n n bis diphenylphosphanyl cyclohexylamine amp 954 2p p amp 8242 platinum ii bis hexafluoridophosphate dichloromethane disolvate |
url | http://scripts.iucr.org/cgi-bin/paper?S1600536810028795 |
work_keys_str_mv | AT ilanaengelbrecht bisnnbisdiphenylphosphanylcyclohexylamineamp9542ppamp8242platinumiibishexafluoridophosphatedichloromethanedisolvate AT hendrikgvisser bisnnbisdiphenylphosphanylcyclohexylamineamp9542ppamp8242platinumiibishexafluoridophosphatedichloromethanedisolvate AT andreasroodt bisnnbisdiphenylphosphanylcyclohexylamineamp9542ppamp8242platinumiibishexafluoridophosphatedichloromethanedisolvate |