Removal of Trihalomethanes from Aqueous Solution through Adsorption and Photodegradation

Trihalomethanes (THMs) are carcinogenic by-products of disinfection that are present in drinking water. In the present research, adsorption and photodegradation, either individually or in tandem, were employed for the removal of the principal THMs found in water supply systems. The effects of pH, co...

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Main Author: S.M. Yakout
Format: Article
Language:English
Published: SAGE Publications 2010-08-01
Series:Adsorption Science & Technology
Online Access:https://doi.org/10.1260/0263-6174.28.7.601
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author S.M. Yakout
author_facet S.M. Yakout
author_sort S.M. Yakout
collection DOAJ
description Trihalomethanes (THMs) are carcinogenic by-products of disinfection that are present in drinking water. In the present research, adsorption and photodegradation, either individually or in tandem, were employed for the removal of the principal THMs found in water supply systems. The effects of pH, contact time, adsorbents and adsorbate concentration on the adsorption system were investigated. The Langmuir and Freundlich adsorption isotherm models were used to analyze the resulting adsorption data. Photodegradation of THMs was carried out in the presence and absence of activated carbon. The integration of adsorption and photodegradation systems as a hybrid treatment process resulted in a synergetic enhancement of the THM removal efficiency. The kinetics of THM removal were found to follow the pseudo-second-order model rather than the Langmuir–Hinshelwood pseudo-first-order model.
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spelling doaj.art-7d12dedc6f86417a892ce81bcc2b06d62024-03-02T16:26:39ZengSAGE PublicationsAdsorption Science & Technology0263-61742048-40382010-08-012810.1260/0263-6174.28.7.601Removal of Trihalomethanes from Aqueous Solution through Adsorption and PhotodegradationS.M. YakoutTrihalomethanes (THMs) are carcinogenic by-products of disinfection that are present in drinking water. In the present research, adsorption and photodegradation, either individually or in tandem, were employed for the removal of the principal THMs found in water supply systems. The effects of pH, contact time, adsorbents and adsorbate concentration on the adsorption system were investigated. The Langmuir and Freundlich adsorption isotherm models were used to analyze the resulting adsorption data. Photodegradation of THMs was carried out in the presence and absence of activated carbon. The integration of adsorption and photodegradation systems as a hybrid treatment process resulted in a synergetic enhancement of the THM removal efficiency. The kinetics of THM removal were found to follow the pseudo-second-order model rather than the Langmuir–Hinshelwood pseudo-first-order model.https://doi.org/10.1260/0263-6174.28.7.601
spellingShingle S.M. Yakout
Removal of Trihalomethanes from Aqueous Solution through Adsorption and Photodegradation
Adsorption Science & Technology
title Removal of Trihalomethanes from Aqueous Solution through Adsorption and Photodegradation
title_full Removal of Trihalomethanes from Aqueous Solution through Adsorption and Photodegradation
title_fullStr Removal of Trihalomethanes from Aqueous Solution through Adsorption and Photodegradation
title_full_unstemmed Removal of Trihalomethanes from Aqueous Solution through Adsorption and Photodegradation
title_short Removal of Trihalomethanes from Aqueous Solution through Adsorption and Photodegradation
title_sort removal of trihalomethanes from aqueous solution through adsorption and photodegradation
url https://doi.org/10.1260/0263-6174.28.7.601
work_keys_str_mv AT smyakout removaloftrihalomethanesfromaqueoussolutionthroughadsorptionandphotodegradation