Catalytic Dehydrogenation of Methylcyclohexane by Pt Nanoparticles Supported on Nitrogen doped Carbon

Pt nanoparticles supported on nitrogen doped carbon (Pt/CN) catalysts with different surface areas were obtained and characterized by transmission electron microscope (TEM) and brunner-emmet-teller (BET). The characterized results showed that Pt nanoparticles dispersed uniformly on the support surfa...

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Main Authors: Wang Jian, Fan Shiguang, Xu Xuan, Yun Huiru, Liu He, Wang Zongxian
Format: Article
Language:English
Published: EDP Sciences 2020-01-01
Series:E3S Web of Conferences
Online Access:https://www.e3s-conferences.org/articles/e3sconf/pdf/2020/54/e3sconf_icaeer2020_01030.pdf
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author Wang Jian
Fan Shiguang
Xu Xuan
Yun Huiru
Liu He
Wang Zongxian
author_facet Wang Jian
Fan Shiguang
Xu Xuan
Yun Huiru
Liu He
Wang Zongxian
author_sort Wang Jian
collection DOAJ
description Pt nanoparticles supported on nitrogen doped carbon (Pt/CN) catalysts with different surface areas were obtained and characterized by transmission electron microscope (TEM) and brunner-emmet-teller (BET). The characterized results showed that Pt nanoparticles dispersed uniformly on the support surface, and the surface area of the Pt/CN catalyst increased with the increase of annealing temperature. Subsequently, the catalytic performance of Pt/CN catalysts for methylcyclohexane dehydrogenation was studied. The activity of Pt/CN catalysts in methylcyclohexane dehydrogenation increased with the increase of the surface area, Pt/CN-1000 catalyst has the largest surface area and the highest catalytic activity, with the methylcyclohexane conversion of 99% and the TOF value of 424.78 h-1 at 180 ℃ for 150 minutes.
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spelling doaj.art-7d1ac28344af4639aa87d1aa8f6b24c82022-12-21T17:16:01ZengEDP SciencesE3S Web of Conferences2267-12422020-01-011940103010.1051/e3sconf/202019401030e3sconf_icaeer2020_01030Catalytic Dehydrogenation of Methylcyclohexane by Pt Nanoparticles Supported on Nitrogen doped CarbonWang JianFan ShiguangXu XuanYun HuiruLiu HeWang ZongxianPt nanoparticles supported on nitrogen doped carbon (Pt/CN) catalysts with different surface areas were obtained and characterized by transmission electron microscope (TEM) and brunner-emmet-teller (BET). The characterized results showed that Pt nanoparticles dispersed uniformly on the support surface, and the surface area of the Pt/CN catalyst increased with the increase of annealing temperature. Subsequently, the catalytic performance of Pt/CN catalysts for methylcyclohexane dehydrogenation was studied. The activity of Pt/CN catalysts in methylcyclohexane dehydrogenation increased with the increase of the surface area, Pt/CN-1000 catalyst has the largest surface area and the highest catalytic activity, with the methylcyclohexane conversion of 99% and the TOF value of 424.78 h-1 at 180 ℃ for 150 minutes.https://www.e3s-conferences.org/articles/e3sconf/pdf/2020/54/e3sconf_icaeer2020_01030.pdf
spellingShingle Wang Jian
Fan Shiguang
Xu Xuan
Yun Huiru
Liu He
Wang Zongxian
Catalytic Dehydrogenation of Methylcyclohexane by Pt Nanoparticles Supported on Nitrogen doped Carbon
E3S Web of Conferences
title Catalytic Dehydrogenation of Methylcyclohexane by Pt Nanoparticles Supported on Nitrogen doped Carbon
title_full Catalytic Dehydrogenation of Methylcyclohexane by Pt Nanoparticles Supported on Nitrogen doped Carbon
title_fullStr Catalytic Dehydrogenation of Methylcyclohexane by Pt Nanoparticles Supported on Nitrogen doped Carbon
title_full_unstemmed Catalytic Dehydrogenation of Methylcyclohexane by Pt Nanoparticles Supported on Nitrogen doped Carbon
title_short Catalytic Dehydrogenation of Methylcyclohexane by Pt Nanoparticles Supported on Nitrogen doped Carbon
title_sort catalytic dehydrogenation of methylcyclohexane by pt nanoparticles supported on nitrogen doped carbon
url https://www.e3s-conferences.org/articles/e3sconf/pdf/2020/54/e3sconf_icaeer2020_01030.pdf
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