Catalytic Dehydrogenation of Methylcyclohexane by Pt Nanoparticles Supported on Nitrogen doped Carbon
Pt nanoparticles supported on nitrogen doped carbon (Pt/CN) catalysts with different surface areas were obtained and characterized by transmission electron microscope (TEM) and brunner-emmet-teller (BET). The characterized results showed that Pt nanoparticles dispersed uniformly on the support surfa...
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EDP Sciences
2020-01-01
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Series: | E3S Web of Conferences |
Online Access: | https://www.e3s-conferences.org/articles/e3sconf/pdf/2020/54/e3sconf_icaeer2020_01030.pdf |
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author | Wang Jian Fan Shiguang Xu Xuan Yun Huiru Liu He Wang Zongxian |
author_facet | Wang Jian Fan Shiguang Xu Xuan Yun Huiru Liu He Wang Zongxian |
author_sort | Wang Jian |
collection | DOAJ |
description | Pt nanoparticles supported on nitrogen doped carbon (Pt/CN) catalysts with different surface areas were obtained and characterized by transmission electron microscope (TEM) and brunner-emmet-teller (BET). The characterized results showed that Pt nanoparticles dispersed uniformly on the support surface, and the surface area of the Pt/CN catalyst increased with the increase of annealing temperature. Subsequently, the catalytic performance of Pt/CN catalysts for methylcyclohexane dehydrogenation was studied. The activity of Pt/CN catalysts in methylcyclohexane dehydrogenation increased with the increase of the surface area, Pt/CN-1000 catalyst has the largest surface area and the highest catalytic activity, with the methylcyclohexane conversion of 99% and the TOF value of 424.78 h-1 at 180 ℃ for 150 minutes. |
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institution | Directory Open Access Journal |
issn | 2267-1242 |
language | English |
last_indexed | 2024-12-24T04:13:13Z |
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series | E3S Web of Conferences |
spelling | doaj.art-7d1ac28344af4639aa87d1aa8f6b24c82022-12-21T17:16:01ZengEDP SciencesE3S Web of Conferences2267-12422020-01-011940103010.1051/e3sconf/202019401030e3sconf_icaeer2020_01030Catalytic Dehydrogenation of Methylcyclohexane by Pt Nanoparticles Supported on Nitrogen doped CarbonWang JianFan ShiguangXu XuanYun HuiruLiu HeWang ZongxianPt nanoparticles supported on nitrogen doped carbon (Pt/CN) catalysts with different surface areas were obtained and characterized by transmission electron microscope (TEM) and brunner-emmet-teller (BET). The characterized results showed that Pt nanoparticles dispersed uniformly on the support surface, and the surface area of the Pt/CN catalyst increased with the increase of annealing temperature. Subsequently, the catalytic performance of Pt/CN catalysts for methylcyclohexane dehydrogenation was studied. The activity of Pt/CN catalysts in methylcyclohexane dehydrogenation increased with the increase of the surface area, Pt/CN-1000 catalyst has the largest surface area and the highest catalytic activity, with the methylcyclohexane conversion of 99% and the TOF value of 424.78 h-1 at 180 ℃ for 150 minutes.https://www.e3s-conferences.org/articles/e3sconf/pdf/2020/54/e3sconf_icaeer2020_01030.pdf |
spellingShingle | Wang Jian Fan Shiguang Xu Xuan Yun Huiru Liu He Wang Zongxian Catalytic Dehydrogenation of Methylcyclohexane by Pt Nanoparticles Supported on Nitrogen doped Carbon E3S Web of Conferences |
title | Catalytic Dehydrogenation of Methylcyclohexane by Pt Nanoparticles Supported on Nitrogen doped Carbon |
title_full | Catalytic Dehydrogenation of Methylcyclohexane by Pt Nanoparticles Supported on Nitrogen doped Carbon |
title_fullStr | Catalytic Dehydrogenation of Methylcyclohexane by Pt Nanoparticles Supported on Nitrogen doped Carbon |
title_full_unstemmed | Catalytic Dehydrogenation of Methylcyclohexane by Pt Nanoparticles Supported on Nitrogen doped Carbon |
title_short | Catalytic Dehydrogenation of Methylcyclohexane by Pt Nanoparticles Supported on Nitrogen doped Carbon |
title_sort | catalytic dehydrogenation of methylcyclohexane by pt nanoparticles supported on nitrogen doped carbon |
url | https://www.e3s-conferences.org/articles/e3sconf/pdf/2020/54/e3sconf_icaeer2020_01030.pdf |
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