Action of Mechanical Forces on Polymerization and Polymers
In this review, we summarize recent developments in the field of the mechanochemistry of polymers. The aim of the review is to consider the consequences of mechanical forces and actions on polymers and polymer synthesis. First, we review classical works on chemical reactions and polymerization proce...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2022-02-01
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| Series: | Polymers |
| Subjects: | |
| Online Access: | https://www.mdpi.com/2073-4360/14/3/604 |
| _version_ | 1797485220691181568 |
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| author | Anatoly T. Ponomarenko Alexey R. Tameev Vitaliy G. Shevchenko |
| author_facet | Anatoly T. Ponomarenko Alexey R. Tameev Vitaliy G. Shevchenko |
| author_sort | Anatoly T. Ponomarenko |
| collection | DOAJ |
| description | In this review, we summarize recent developments in the field of the mechanochemistry of polymers. The aim of the review is to consider the consequences of mechanical forces and actions on polymers and polymer synthesis. First, we review classical works on chemical reactions and polymerization processes under strong shear deformations. Then, we analyze two emerging directions of research in mechanochemistry—the role of mechanophores and, for the first time, new physical phenomena, accompanying external impulse mechanical actions on polymers. Mechanophores have been recently proposed as sensors of fatigue and cracks in polymers and composites. The effects of the high-pressure pulsed loading of polymers and composites include the Dzyaloshinskii–Moriya effect, emission of superradiation and the formation of metal nanoparticles. These effects provide deeper insight into the mechanism of chemical reactions under shear deformations and pave the way for further research in the interests of modern technologies. |
| first_indexed | 2024-03-09T23:15:39Z |
| format | Article |
| id | doaj.art-7d2a971348f94eb29b909a505074a65b |
| institution | Directory Open Access Journal |
| issn | 2073-4360 |
| language | English |
| last_indexed | 2024-03-09T23:15:39Z |
| publishDate | 2022-02-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Polymers |
| spelling | doaj.art-7d2a971348f94eb29b909a505074a65b2023-11-23T17:36:39ZengMDPI AGPolymers2073-43602022-02-0114360410.3390/polym14030604Action of Mechanical Forces on Polymerization and PolymersAnatoly T. Ponomarenko0Alexey R. Tameev1Vitaliy G. Shevchenko2Enikolopov Institute of Synthetic Polymeric Materials, Russian Academy of Sciences, 70 Profsoyuznaya, 117393 Moscow, RussiaFrumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, 31, bld. 4 Leninsky Prospect, 119071 Moscow, RussiaEnikolopov Institute of Synthetic Polymeric Materials, Russian Academy of Sciences, 70 Profsoyuznaya, 117393 Moscow, RussiaIn this review, we summarize recent developments in the field of the mechanochemistry of polymers. The aim of the review is to consider the consequences of mechanical forces and actions on polymers and polymer synthesis. First, we review classical works on chemical reactions and polymerization processes under strong shear deformations. Then, we analyze two emerging directions of research in mechanochemistry—the role of mechanophores and, for the first time, new physical phenomena, accompanying external impulse mechanical actions on polymers. Mechanophores have been recently proposed as sensors of fatigue and cracks in polymers and composites. The effects of the high-pressure pulsed loading of polymers and composites include the Dzyaloshinskii–Moriya effect, emission of superradiation and the formation of metal nanoparticles. These effects provide deeper insight into the mechanism of chemical reactions under shear deformations and pave the way for further research in the interests of modern technologies.https://www.mdpi.com/2073-4360/14/3/604mechanochemistrypolymerizationradicalsanvilsmechanodestructionmechanophores |
| spellingShingle | Anatoly T. Ponomarenko Alexey R. Tameev Vitaliy G. Shevchenko Action of Mechanical Forces on Polymerization and Polymers Polymers mechanochemistry polymerization radicals anvils mechanodestruction mechanophores |
| title | Action of Mechanical Forces on Polymerization and Polymers |
| title_full | Action of Mechanical Forces on Polymerization and Polymers |
| title_fullStr | Action of Mechanical Forces on Polymerization and Polymers |
| title_full_unstemmed | Action of Mechanical Forces on Polymerization and Polymers |
| title_short | Action of Mechanical Forces on Polymerization and Polymers |
| title_sort | action of mechanical forces on polymerization and polymers |
| topic | mechanochemistry polymerization radicals anvils mechanodestruction mechanophores |
| url | https://www.mdpi.com/2073-4360/14/3/604 |
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