Correlation between the particle size, structural and photoluminescence spectra of nano NiCr2O4 and La doped NiCr2O4 materials

Nano NiCr2O4 undoped and La doped NiCr2O4 nanorods array were successfully prepared by solution based conventional method[sbcm]. The synthesized samples were characterized by the diffuse reflectance spectroscopy (DRS) and photoluminescence (PL) spectroscopy for finding optical properties. Further, t...

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Main Authors: C. Ragupathi, S. Narayanan, P. Tamizhdurai, T.A. Sukantha, G. Ramalingam, M.P. Pachamuthu, V.L. Mangesh, Nadavala Siva Kumar, Ahmed S. Al-Fatesh, Samsudeen Olajide Kasim
Format: Article
Language:English
Published: Elsevier 2023-11-01
Series:Heliyon
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2405844023091892
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author C. Ragupathi
S. Narayanan
P. Tamizhdurai
T.A. Sukantha
G. Ramalingam
M.P. Pachamuthu
V.L. Mangesh
Nadavala Siva Kumar
Ahmed S. Al-Fatesh
Samsudeen Olajide Kasim
author_facet C. Ragupathi
S. Narayanan
P. Tamizhdurai
T.A. Sukantha
G. Ramalingam
M.P. Pachamuthu
V.L. Mangesh
Nadavala Siva Kumar
Ahmed S. Al-Fatesh
Samsudeen Olajide Kasim
author_sort C. Ragupathi
collection DOAJ
description Nano NiCr2O4 undoped and La doped NiCr2O4 nanorods array were successfully prepared by solution based conventional method[sbcm]. The synthesized samples were characterized by the diffuse reflectance spectroscopy (DRS) and photoluminescence (PL) spectroscopy for finding optical properties. Further, the samples structure confirmed by Fourier transforms infrared (FTIR), and X-ray diffraction (XRD)techniques. High-resolution transmission electron microscopy (HRTEM) analysis revealed the attachment of NiCr2O4 nanorods on surface of nanoparticles. From the results, it was found that the reaction time, band gap energy, and particle size strongly influenced by changing the concentration of La in NiCr2O4. This work is notable for its examination of the impact of the precursor on the optical and structural characteristics of samples of La-doped and undoped NiCr2O4. This was the first time the investigation had been done. The average particle size of the La-doped and undoped NiCr2O4 samples is between 16 and 24 nm.
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spelling doaj.art-7d34a0a0d2434c4d97f94f2851401f222023-12-02T07:04:50ZengElsevierHeliyon2405-84402023-11-01911e21981Correlation between the particle size, structural and photoluminescence spectra of nano NiCr2O4 and La doped NiCr2O4 materialsC. Ragupathi0S. Narayanan1P. Tamizhdurai2T.A. Sukantha3G. Ramalingam4M.P. Pachamuthu5V.L. Mangesh6Nadavala Siva Kumar7Ahmed S. Al-Fatesh8Samsudeen Olajide Kasim9Department of Chemistry, Sriram College of Arts and Science, Perumalpattu, Tiruvallur, 602024, Tamil Nadu, IndiaResearch and Development, Manali Petrochemicals Ltd., Ponneri High Road, Manali, Chennai, Tamil Nadu, 600068, IndiaDepartment of Chemistry, Dwaraka Doss Goverdhan Doss Vaishnav College (Autonomous) (Affiliated to the University of Madras, Chennai), 833, Gokul Bagh, E.V.R. Periyar Road, Arumbakkam, Chennai, 600106, Tamil Nadu, India; Corresponding author.Department of Chemistry, K.S. Rangasamy College of Technology, Tiruchengode, 637215, IndiaQuantum Materials Research Lab(QMRL), Department of Nanoscience and Technology, Alagappa University, Karaikudi, 630003, Tamil Nadu, IndiaDepartment of Chemistry, Bannari Amman Institute of Technology, Sathyamangalam, 638401, Erode, Tamil Nadu, IndiaDepartment of Marine Engineering, Indian Maritime University, 600119, IndiaChemical Engineering Department, College of Engineering, King Saud University, P.O. Box 800, Riyadh, 11421, Saudi ArabiaChemical Engineering Department, College of Engineering, King Saud University, P.O. Box 800, Riyadh, 11421, Saudi ArabiaSchool of Photovoltaic and Renewable Energy Engineering (SPREE), Faculty of Engineering University of New South Wales (UNSW), Kensington, NSW, 2052, AustraliaNano NiCr2O4 undoped and La doped NiCr2O4 nanorods array were successfully prepared by solution based conventional method[sbcm]. The synthesized samples were characterized by the diffuse reflectance spectroscopy (DRS) and photoluminescence (PL) spectroscopy for finding optical properties. Further, the samples structure confirmed by Fourier transforms infrared (FTIR), and X-ray diffraction (XRD)techniques. High-resolution transmission electron microscopy (HRTEM) analysis revealed the attachment of NiCr2O4 nanorods on surface of nanoparticles. From the results, it was found that the reaction time, band gap energy, and particle size strongly influenced by changing the concentration of La in NiCr2O4. This work is notable for its examination of the impact of the precursor on the optical and structural characteristics of samples of La-doped and undoped NiCr2O4. This was the first time the investigation had been done. The average particle size of the La-doped and undoped NiCr2O4 samples is between 16 and 24 nm.http://www.sciencedirect.com/science/article/pii/S2405844023091892PowdersMicrostructureOptical propertiesRare earthsSemiconductors
spellingShingle C. Ragupathi
S. Narayanan
P. Tamizhdurai
T.A. Sukantha
G. Ramalingam
M.P. Pachamuthu
V.L. Mangesh
Nadavala Siva Kumar
Ahmed S. Al-Fatesh
Samsudeen Olajide Kasim
Correlation between the particle size, structural and photoluminescence spectra of nano NiCr2O4 and La doped NiCr2O4 materials
Heliyon
Powders
Microstructure
Optical properties
Rare earths
Semiconductors
title Correlation between the particle size, structural and photoluminescence spectra of nano NiCr2O4 and La doped NiCr2O4 materials
title_full Correlation between the particle size, structural and photoluminescence spectra of nano NiCr2O4 and La doped NiCr2O4 materials
title_fullStr Correlation between the particle size, structural and photoluminescence spectra of nano NiCr2O4 and La doped NiCr2O4 materials
title_full_unstemmed Correlation between the particle size, structural and photoluminescence spectra of nano NiCr2O4 and La doped NiCr2O4 materials
title_short Correlation between the particle size, structural and photoluminescence spectra of nano NiCr2O4 and La doped NiCr2O4 materials
title_sort correlation between the particle size structural and photoluminescence spectra of nano nicr2o4 and la doped nicr2o4 materials
topic Powders
Microstructure
Optical properties
Rare earths
Semiconductors
url http://www.sciencedirect.com/science/article/pii/S2405844023091892
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