Tetraaquabis(piperazin-1-ium)cobalt(II) bis(sulfate) dihydrate
In the centrosymmetric title compound, [Co(C4H11N2)2(H2O)4](SO4)2·2H2O, the CoII atom is coordinated in a distorted octahedral geometry by four water O atoms and two piperazinium N atoms. These four water O atoms define an equatorial plane with a maximum deviation of 0.0384 (1)&am...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2013-12-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536813030365 |
| _version_ | 1828129009671602176 |
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| author | Mohamed Rzaigui Wajda Smirani Sta Thameur Sahbani |
| author_facet | Mohamed Rzaigui Wajda Smirani Sta Thameur Sahbani |
| author_sort | Mohamed Rzaigui |
| collection | DOAJ |
| description | In the centrosymmetric title compound, [Co(C4H11N2)2(H2O)4](SO4)2·2H2O, the CoII atom is coordinated in a distorted octahedral geometry by four water O atoms and two piperazinium N atoms. These four water O atoms define an equatorial plane with a maximum deviation of 0.0384 (1) Å while the two piperazinium N atoms complete the octahedron in the axial positions. Neighboring complex molecules and sulfate anions are connected through an extensive network of N—H...O and O—H...O hydrogen bonds, which link the different chemical species into layers in the ab plane. Additional Owater—H...O hydrogen bonds involving the non-coordinating water molecules and C—H...O interactions connect these layers into a three-dimensional supramolecular structure. |
| first_indexed | 2024-04-11T16:13:25Z |
| format | Article |
| id | doaj.art-7d36f98bde364b47ab1b8022be8cf2da |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-04-11T16:13:25Z |
| publishDate | 2013-12-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-7d36f98bde364b47ab1b8022be8cf2da2022-12-22T04:14:37ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-12-016912m649m65010.1107/S1600536813030365Tetraaquabis(piperazin-1-ium)cobalt(II) bis(sulfate) dihydrateMohamed RzaiguiWajda Smirani StaThameur SahbaniIn the centrosymmetric title compound, [Co(C4H11N2)2(H2O)4](SO4)2·2H2O, the CoII atom is coordinated in a distorted octahedral geometry by four water O atoms and two piperazinium N atoms. These four water O atoms define an equatorial plane with a maximum deviation of 0.0384 (1) Å while the two piperazinium N atoms complete the octahedron in the axial positions. Neighboring complex molecules and sulfate anions are connected through an extensive network of N—H...O and O—H...O hydrogen bonds, which link the different chemical species into layers in the ab plane. Additional Owater—H...O hydrogen bonds involving the non-coordinating water molecules and C—H...O interactions connect these layers into a three-dimensional supramolecular structure.http://scripts.iucr.org/cgi-bin/paper?S1600536813030365 |
| spellingShingle | Mohamed Rzaigui Wajda Smirani Sta Thameur Sahbani Tetraaquabis(piperazin-1-ium)cobalt(II) bis(sulfate) dihydrate Acta Crystallographica Section E |
| title | Tetraaquabis(piperazin-1-ium)cobalt(II) bis(sulfate) dihydrate |
| title_full | Tetraaquabis(piperazin-1-ium)cobalt(II) bis(sulfate) dihydrate |
| title_fullStr | Tetraaquabis(piperazin-1-ium)cobalt(II) bis(sulfate) dihydrate |
| title_full_unstemmed | Tetraaquabis(piperazin-1-ium)cobalt(II) bis(sulfate) dihydrate |
| title_short | Tetraaquabis(piperazin-1-ium)cobalt(II) bis(sulfate) dihydrate |
| title_sort | tetraaquabis piperazin 1 ium cobalt ii bis sulfate dihydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536813030365 |
| work_keys_str_mv | AT mohamedrzaigui tetraaquabispiperazin1iumcobaltiibissulfatedihydrate AT wajdasmiranista tetraaquabispiperazin1iumcobaltiibissulfatedihydrate AT thameursahbani tetraaquabispiperazin1iumcobaltiibissulfatedihydrate |