Consecutive Ink Writing of Conducting Polymer and Graphene Composite Electrodes for Foldable Electronics-Related Applications

For foldable electronic devices of the future, most components should have very good flexibility and reliability to maintain electrical properties even under repeated deformation. In this study, two types of inks for conducting polymer and graphene were simultaneously printed on flexible plastic sub...

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Main Authors: Heechan Lee, Youngdo Kim, Jiwoo Kim, Su Young Moon, Jea Uk Lee
Format: Article
Language:English
Published: MDPI AG 2022-12-01
Series:Polymers
Subjects:
Online Access:https://www.mdpi.com/2073-4360/14/23/5294
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author Heechan Lee
Youngdo Kim
Jiwoo Kim
Su Young Moon
Jea Uk Lee
author_facet Heechan Lee
Youngdo Kim
Jiwoo Kim
Su Young Moon
Jea Uk Lee
author_sort Heechan Lee
collection DOAJ
description For foldable electronic devices of the future, most components should have very good flexibility and reliability to maintain electrical properties even under repeated deformation. In this study, two types of inks for conducting polymer and graphene were simultaneously printed on flexible plastic substrates via the newly developed consecutive ink writing (CIW) process for the formation of composite electrodes of foldable electronic devices. To consecutively print conducting polymer ink and graphene ink, a conventional three-dimensional (3D) printer was modified by installing two needles in the printer head, and the two inks were printed through the nozzle in the same route with a time interval. By adjusting several printing conditions (ink concentration, printing parameters, printing time intervals between the two inks, etc.), various structures of composite electrodes, such as layered or fused 2D or 3D structures were developed on the glass substrate. Furthermore, by changing the printing order of the two inks and 3D printer bed temperature, the composite electrodes with a higher printing resolution were successfully printed on the flexible polyimide substrate. The printed composite electrodes via CIW process exhibit the lowest surface electrical resistance of 0.9 kΩ and high flexibility, and stable resistance values were maintained after 1000 cycles of the folding test. Consequently, the CIW process developed in this study applies to the production of the electrical parts and components for various flexible devices, such as foldable and wearable electronics.
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spelling doaj.art-7d646ce0f0264ad4bde4e6a2d91ee7182023-11-24T12:01:44ZengMDPI AGPolymers2073-43602022-12-011423529410.3390/polym14235294Consecutive Ink Writing of Conducting Polymer and Graphene Composite Electrodes for Foldable Electronics-Related ApplicationsHeechan Lee0Youngdo Kim1Jiwoo Kim2Su Young Moon3Jea Uk Lee4Department of Advanced Materials Engineering for Information and Electronics, Integrated Education Institute for Frontier Science & Technology (BK21 Four), Kyung Hee University, 1732 Deogyeong-daero, Giheung-gu, Yongin-si 17104, Republic of KoreaSamsung Display Co., Ltd., #1 Samsung-ro, Giheung-gu, Yongin-si 17113, Republic of KoreaDepartment of Advanced Materials Engineering for Information and Electronics, Integrated Education Institute for Frontier Science & Technology (BK21 Four), Kyung Hee University, 1732 Deogyeong-daero, Giheung-gu, Yongin-si 17104, Republic of KoreaChemical & Process Technology Division C1 Gas & Carbon Convergent Research Center, Korea Research Institute of Chemical Technology (KRICT), 141 Gajeongro, Yuseong, Daejon 34114, Republic of KoreaDepartment of Advanced Materials Engineering for Information and Electronics, Integrated Education Institute for Frontier Science & Technology (BK21 Four), Kyung Hee University, 1732 Deogyeong-daero, Giheung-gu, Yongin-si 17104, Republic of KoreaFor foldable electronic devices of the future, most components should have very good flexibility and reliability to maintain electrical properties even under repeated deformation. In this study, two types of inks for conducting polymer and graphene were simultaneously printed on flexible plastic substrates via the newly developed consecutive ink writing (CIW) process for the formation of composite electrodes of foldable electronic devices. To consecutively print conducting polymer ink and graphene ink, a conventional three-dimensional (3D) printer was modified by installing two needles in the printer head, and the two inks were printed through the nozzle in the same route with a time interval. By adjusting several printing conditions (ink concentration, printing parameters, printing time intervals between the two inks, etc.), various structures of composite electrodes, such as layered or fused 2D or 3D structures were developed on the glass substrate. Furthermore, by changing the printing order of the two inks and 3D printer bed temperature, the composite electrodes with a higher printing resolution were successfully printed on the flexible polyimide substrate. The printed composite electrodes via CIW process exhibit the lowest surface electrical resistance of 0.9 kΩ and high flexibility, and stable resistance values were maintained after 1000 cycles of the folding test. Consequently, the CIW process developed in this study applies to the production of the electrical parts and components for various flexible devices, such as foldable and wearable electronics.https://www.mdpi.com/2073-4360/14/23/5294conducting polymergraphenecompositeelectrode3D printing
spellingShingle Heechan Lee
Youngdo Kim
Jiwoo Kim
Su Young Moon
Jea Uk Lee
Consecutive Ink Writing of Conducting Polymer and Graphene Composite Electrodes for Foldable Electronics-Related Applications
Polymers
conducting polymer
graphene
composite
electrode
3D printing
title Consecutive Ink Writing of Conducting Polymer and Graphene Composite Electrodes for Foldable Electronics-Related Applications
title_full Consecutive Ink Writing of Conducting Polymer and Graphene Composite Electrodes for Foldable Electronics-Related Applications
title_fullStr Consecutive Ink Writing of Conducting Polymer and Graphene Composite Electrodes for Foldable Electronics-Related Applications
title_full_unstemmed Consecutive Ink Writing of Conducting Polymer and Graphene Composite Electrodes for Foldable Electronics-Related Applications
title_short Consecutive Ink Writing of Conducting Polymer and Graphene Composite Electrodes for Foldable Electronics-Related Applications
title_sort consecutive ink writing of conducting polymer and graphene composite electrodes for foldable electronics related applications
topic conducting polymer
graphene
composite
electrode
3D printing
url https://www.mdpi.com/2073-4360/14/23/5294
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