Oxidized jute as a valuable adsorbent for Congo Red from an aqueous solution
The raw jute fabric was oxidized with 0.2% or 0.4% NaIO 4 for 60 or 120 min to obtain valuable adsorbents for the textile dye Congo Red (CR). Batch adsorption experiments were carried out as a function of solution pH, contact time, initial CR concentration, and temperature. At an initial CR concentr...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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SAGE Publishing
2022-05-01
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| Series: | Journal of Engineered Fibers and Fabrics |
| Online Access: | https://doi.org/10.1177/15589250221101380 |
| _version_ | 1817980365491404800 |
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| author | Aleksandra Ivanovska Ivana Branković Jelena Lađarević Leposava Pavun Mirjana Kostic |
| author_facet | Aleksandra Ivanovska Ivana Branković Jelena Lađarević Leposava Pavun Mirjana Kostic |
| author_sort | Aleksandra Ivanovska |
| collection | DOAJ |
| description | The raw jute fabric was oxidized with 0.2% or 0.4% NaIO 4 for 60 or 120 min to obtain valuable adsorbents for the textile dye Congo Red (CR). Batch adsorption experiments were carried out as a function of solution pH, contact time, initial CR concentration, and temperature. At an initial CR concentration of 25 mg/L, the raw jute possessed the lowest adsorption due to the lowest availability and content of carboxyl and aldehyde groups capable of binding dye. The fabrics oxidized for 60 min with 0.2% NaIO 4 and 120 min with 0.4% NaIO 4 reached equilibrium adsorption after 240 and 330 min, respectively. The adsorption of CR onto studied fabrics followed the pseudo-second-order model indicating that the chemisorption process is primarily represented. Within the studied range of CR concentrations (25–100 mg/L), its adsorption onto fabric oxidized for 120 min with 0.4% NaIO 4 obeys the Langmuir isotherm model (i.e. adsorption occurs at specific, energetically equivalent adsorbent sites with monolayer coverage of CR over a homogeneous surface), wherein the calculated maximal adsorption capacity is 12.863 mg/g. A thermodynamic study revealed the spontaneous and endothermic character of CR adsorption onto jute fabric. Based on the recorded ATR-FTIR spectra before and after CR adsorption, it is suggested that repulsion, hydrogen bonds, and π-π stacking interactions are involved in the binding of CR onto jute fabrics. |
| first_indexed | 2024-04-13T22:53:04Z |
| format | Article |
| id | doaj.art-7d6b776bba484237b8193de2fbab4d71 |
| institution | Directory Open Access Journal |
| issn | 1558-9250 |
| language | English |
| last_indexed | 2024-04-13T22:53:04Z |
| publishDate | 2022-05-01 |
| publisher | SAGE Publishing |
| record_format | Article |
| series | Journal of Engineered Fibers and Fabrics |
| spelling | doaj.art-7d6b776bba484237b8193de2fbab4d712022-12-22T02:26:07ZengSAGE PublishingJournal of Engineered Fibers and Fabrics1558-92502022-05-011710.1177/15589250221101380Oxidized jute as a valuable adsorbent for Congo Red from an aqueous solutionAleksandra Ivanovska0Ivana Branković1Jelena Lađarević2Leposava Pavun3Mirjana Kostic4Innovation Center of the Faculty of Technology and Metallurgy, University of Belgrade, Belgrade, SerbiaFaculty of Technology and Metallurgy, University of Belgrade, Belgrade, SerbiaFaculty of Technology and Metallurgy, University of Belgrade, Belgrade, SerbiaFaculty of Pharmacy, University of Belgrade, Belgrade, SerbiaFaculty of Technology and Metallurgy, University of Belgrade, Belgrade, SerbiaThe raw jute fabric was oxidized with 0.2% or 0.4% NaIO 4 for 60 or 120 min to obtain valuable adsorbents for the textile dye Congo Red (CR). Batch adsorption experiments were carried out as a function of solution pH, contact time, initial CR concentration, and temperature. At an initial CR concentration of 25 mg/L, the raw jute possessed the lowest adsorption due to the lowest availability and content of carboxyl and aldehyde groups capable of binding dye. The fabrics oxidized for 60 min with 0.2% NaIO 4 and 120 min with 0.4% NaIO 4 reached equilibrium adsorption after 240 and 330 min, respectively. The adsorption of CR onto studied fabrics followed the pseudo-second-order model indicating that the chemisorption process is primarily represented. Within the studied range of CR concentrations (25–100 mg/L), its adsorption onto fabric oxidized for 120 min with 0.4% NaIO 4 obeys the Langmuir isotherm model (i.e. adsorption occurs at specific, energetically equivalent adsorbent sites with monolayer coverage of CR over a homogeneous surface), wherein the calculated maximal adsorption capacity is 12.863 mg/g. A thermodynamic study revealed the spontaneous and endothermic character of CR adsorption onto jute fabric. Based on the recorded ATR-FTIR spectra before and after CR adsorption, it is suggested that repulsion, hydrogen bonds, and π-π stacking interactions are involved in the binding of CR onto jute fabrics.https://doi.org/10.1177/15589250221101380 |
| spellingShingle | Aleksandra Ivanovska Ivana Branković Jelena Lađarević Leposava Pavun Mirjana Kostic Oxidized jute as a valuable adsorbent for Congo Red from an aqueous solution Journal of Engineered Fibers and Fabrics |
| title | Oxidized jute as a valuable adsorbent for Congo Red from an aqueous solution |
| title_full | Oxidized jute as a valuable adsorbent for Congo Red from an aqueous solution |
| title_fullStr | Oxidized jute as a valuable adsorbent for Congo Red from an aqueous solution |
| title_full_unstemmed | Oxidized jute as a valuable adsorbent for Congo Red from an aqueous solution |
| title_short | Oxidized jute as a valuable adsorbent for Congo Red from an aqueous solution |
| title_sort | oxidized jute as a valuable adsorbent for congo red from an aqueous solution |
| url | https://doi.org/10.1177/15589250221101380 |
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