Regioselective C(sp<sup>2</sup>)-C(sp<sup>3</sup>) Coupling Mediated by Classical and Rollover Cyclometalation
By taking advantage of a sequence of oxidative addition/reductive elimination reactions, Pt(II) cyclometalated derivatives are able to promote a rare C(sp<sup>2</sup>)-C(sp<sup>3</sup>) bond coupling, resulting in the production of novel methyl-substituted pyridines and bipyr...
Main Authors: | Lorenzo Manca, Giacomo Senzacqua, Sergio Stoccoro, Antonio Zucca |
---|---|
Format: | Article |
Language: | English |
Published: |
MDPI AG
2024-02-01
|
Series: | Molecules |
Subjects: | |
Online Access: | https://www.mdpi.com/1420-3049/29/3/707 |
Similar Items
-
Classical vs. Non-Classical Cyclometalated Pt(II) Complexes
by: Luca Maidich, et al.
Published: (2022-10-01) -
Rollover Cyclometalation as a Valuable Tool for Regioselective C–H Bond Activation and Functionalization
by: Antonio Zucca, et al.
Published: (2021-01-01) -
Pt(II) Derivatives with Rollover-Coordinated 6-substituted 2,2′-bipyridines: Ligands with Multiple Personalities
by: Antonio Zucca, et al.
Published: (2020-09-01) -
A Novel Class of Cyclometalated Platinum(II) Complexes for Solution-Processable OLEDs
by: Dominique Roberto, et al.
Published: (2022-08-01) -
Trinuclear and Cyclometallated Organometallic Dinuclear Pt-Pyrazolato Complexes: A Combined Experimental and Theoretical Study
by: Zhichun Shi, et al.
Published: (2023-01-01)