NEW TRANSITION METAL OXALATO COMPLEXES WITH DABCOH22+ AS ADVERSE CATION: SYNTHESIS AND INFRARED STUDY
On allowing DABCOH2(HC2O4)2 to react with transition metal dihalides in ethanol, a new series of complexes of general formula M(oxalate)2 DABCOH22+. nDABCOH22+.2X- (n=1/2;1) have been obtained. When (n=1) a dimeric structure is suggested, the two monomeric species being hold together by biprotonate...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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Alma Mater Publishing House "Vasile Alecsandri" University of Bacau
2017-09-01
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| Series: | Journal of Engineering Studies and Research |
| Subjects: | |
| Online Access: | https://jesr.ub.ro/1/article/view/77 |
| Summary: | On allowing DABCOH2(HC2O4)2 to react with transition metal dihalides in ethanol, a new series of complexes of general formula M(oxalate)2 DABCOH22+. nDABCOH22+.2X- (n=1/2;1) have been obtained. When (n=1) a dimeric structure is suggested, the two monomeric species being hold together by biprotonated DABCO through N-H…O hydrogen bonds. In the case of the complex M(oxalate)2DABCOH22+ .1/2 DABCOH22+.2X- -M = Ni, Cu- the structure is an infinite chain. The environment around the metallic centers is octahedral or square pyramidal. The oxalate behaves as a monochelating and hydrogen bonds involved ligand or is only concerned by hydrogen bonds.
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| ISSN: | 2068-7559 2344-4932 |