Study on the Regeneration of Waste FCC Catalyst by Boron Modification

Regeneration has been considered as an ideal way for the post-treatment of waste FCC catalyst (ECat). In this work, the degeneration mechanism of ECat was firstly researched and attributed to the increasing of strong acid sites accessibility of ECat in contrast with fresh FCC catalyst by adsorption...

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Bibliographic Details
Main Authors: Chengyuan Yuan, Qiang Chen, Zhongfu Li, Jingyan Zhang, Conghua Liu
Format: Article
Language:English
Published: MDPI AG 2024-02-01
Series:Molecules
Subjects:
Online Access:https://www.mdpi.com/1420-3049/29/5/962
Description
Summary:Regeneration has been considered as an ideal way for the post-treatment of waste FCC catalyst (ECat). In this work, the degeneration mechanism of ECat was firstly researched and attributed to the increasing of strong acid sites accessibility of ECat in contrast with fresh FCC catalyst by adsorption FTIR. Based on the proposed degeneration mechanism, ECat was successfully regenerated through suitable weakening for strong acid sites by boron modification. Characterization and evaluation results suggested that, the strong acid sites of regenerated ECat (R-ECat) were apparently decreased by boron modification which had significantly improve the heavy oil catalytic cracking performance of R-ECat. Because of the excellent performance, R-ECat in this work could successfully substitute for partial fresh FCC catalyst in FCC unit, which would provide a practicable way for the reutilization of ECat.
ISSN:1420-3049