Study on the Regeneration of Waste FCC Catalyst by Boron Modification
Regeneration has been considered as an ideal way for the post-treatment of waste FCC catalyst (ECat). In this work, the degeneration mechanism of ECat was firstly researched and attributed to the increasing of strong acid sites accessibility of ECat in contrast with fresh FCC catalyst by adsorption...
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| Format: | Article |
| Language: | English |
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MDPI AG
2024-02-01
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| Series: | Molecules |
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| Online Access: | https://www.mdpi.com/1420-3049/29/5/962 |
| _version_ | 1797264161154007040 |
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| author | Chengyuan Yuan Qiang Chen Zhongfu Li Jingyan Zhang Conghua Liu |
| author_facet | Chengyuan Yuan Qiang Chen Zhongfu Li Jingyan Zhang Conghua Liu |
| author_sort | Chengyuan Yuan |
| collection | DOAJ |
| description | Regeneration has been considered as an ideal way for the post-treatment of waste FCC catalyst (ECat). In this work, the degeneration mechanism of ECat was firstly researched and attributed to the increasing of strong acid sites accessibility of ECat in contrast with fresh FCC catalyst by adsorption FTIR. Based on the proposed degeneration mechanism, ECat was successfully regenerated through suitable weakening for strong acid sites by boron modification. Characterization and evaluation results suggested that, the strong acid sites of regenerated ECat (R-ECat) were apparently decreased by boron modification which had significantly improve the heavy oil catalytic cracking performance of R-ECat. Because of the excellent performance, R-ECat in this work could successfully substitute for partial fresh FCC catalyst in FCC unit, which would provide a practicable way for the reutilization of ECat. |
| first_indexed | 2024-04-25T00:24:30Z |
| format | Article |
| id | doaj.art-7d930eedb0d7465cb725ae9f9a70e623 |
| institution | Directory Open Access Journal |
| issn | 1420-3049 |
| language | English |
| last_indexed | 2024-04-25T00:24:30Z |
| publishDate | 2024-02-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj.art-7d930eedb0d7465cb725ae9f9a70e6232024-03-12T16:50:34ZengMDPI AGMolecules1420-30492024-02-0129596210.3390/molecules29050962Study on the Regeneration of Waste FCC Catalyst by Boron ModificationChengyuan Yuan0Qiang Chen1Zhongfu Li2Jingyan Zhang3Conghua Liu4School of Materials Science and Engineering, Shandong University of Technology, Zibo 255000, ChinaShanxi Tengmao Technology Co., Ltd., Hejin 043300, ChinaSchool of Materials Science and Engineering, Shandong University of Technology, Zibo 255000, ChinaSchool of Materials Science and Engineering, Shandong University of Technology, Zibo 255000, ChinaSchool of Materials Science and Engineering, Shandong University of Technology, Zibo 255000, ChinaRegeneration has been considered as an ideal way for the post-treatment of waste FCC catalyst (ECat). In this work, the degeneration mechanism of ECat was firstly researched and attributed to the increasing of strong acid sites accessibility of ECat in contrast with fresh FCC catalyst by adsorption FTIR. Based on the proposed degeneration mechanism, ECat was successfully regenerated through suitable weakening for strong acid sites by boron modification. Characterization and evaluation results suggested that, the strong acid sites of regenerated ECat (R-ECat) were apparently decreased by boron modification which had significantly improve the heavy oil catalytic cracking performance of R-ECat. Because of the excellent performance, R-ECat in this work could successfully substitute for partial fresh FCC catalyst in FCC unit, which would provide a practicable way for the reutilization of ECat.https://www.mdpi.com/1420-3049/29/5/962waste FCC catalystregenerationboron modificationacid sites accessibilitycatalytic cracking |
| spellingShingle | Chengyuan Yuan Qiang Chen Zhongfu Li Jingyan Zhang Conghua Liu Study on the Regeneration of Waste FCC Catalyst by Boron Modification Molecules waste FCC catalyst regeneration boron modification acid sites accessibility catalytic cracking |
| title | Study on the Regeneration of Waste FCC Catalyst by Boron Modification |
| title_full | Study on the Regeneration of Waste FCC Catalyst by Boron Modification |
| title_fullStr | Study on the Regeneration of Waste FCC Catalyst by Boron Modification |
| title_full_unstemmed | Study on the Regeneration of Waste FCC Catalyst by Boron Modification |
| title_short | Study on the Regeneration of Waste FCC Catalyst by Boron Modification |
| title_sort | study on the regeneration of waste fcc catalyst by boron modification |
| topic | waste FCC catalyst regeneration boron modification acid sites accessibility catalytic cracking |
| url | https://www.mdpi.com/1420-3049/29/5/962 |
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