Mineralogy and Geochemistry of Deep-Sea Sediments from the Ultraslow-Spreading Southwest Indian Ridge: Implications for Hydrothermal Input and Igneous Host Rock

Detailed mineralogical and geochemical characteristics of typical surface sediments and hydrothermal deposits collected from the ultraslow-spreading Southwest Indian Ridge (SWIR) were studied by high-resolution XRD, SEM-EDS, XRF, and ICP-MS. The SWIR marine samples can be generally classified into t...

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Main Authors: Xian Chen, Xiaoming Sun, Zhongwei Wu, Yan Wang, Xiao Lin, Hongjun Chen
Format: Article
Language:English
Published: MDPI AG 2021-01-01
Series:Minerals
Subjects:
Online Access:https://www.mdpi.com/2075-163X/11/2/138
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author Xian Chen
Xiaoming Sun
Zhongwei Wu
Yan Wang
Xiao Lin
Hongjun Chen
author_facet Xian Chen
Xiaoming Sun
Zhongwei Wu
Yan Wang
Xiao Lin
Hongjun Chen
author_sort Xian Chen
collection DOAJ
description Detailed mineralogical and geochemical characteristics of typical surface sediments and hydrothermal deposits collected from the ultraslow-spreading Southwest Indian Ridge (SWIR) were studied by high-resolution XRD, SEM-EDS, XRF, and ICP-MS. The SWIR marine samples can be generally classified into two main categories: surface sediment (biogenic, volcanic) and hydrothermal-derived deposit; moreover, the surface sediment can be further classified into metalliferous and non-metalliferous based on the metalliferous sediment index (MSI). The chemical composition of biogenic sediment (mainly biogenic calcite) was characterized by elevated contents of Ca, Ba, Rb, Sr, Th, and light rare earth elements (LREE), while volcanic sediment (mainly volcanogenic debris) was relatively enriched in Mn, Mg, Al, Si, Ni, Cr, and high field strength elements (HFSEs). By contrast, the hydrothermal-derived deposit (mainly pyrite-marcasite, chalcopyrite-isocubanite, and low-temperature cherts) contained significantly higher contents of Fe, Cu, Zn, Pb, Mn, Co, Mo, Ag, and U. In addition, the metalliferous surface sediment contained a higher content of Cu, Mn, Fe, Co, Mo, Ba, and As. Compared with their different host (source) rock, the basalt-hosted marine sediments contained higher contents of Ti–Al–Zr–Sc–Hf and/or Mo–Ba–Ag; In contrast, the peridotite-hosted marine sediments were typically characterized by elevated concentrations of Mg–Cu–Ni–Cr and/or Co–Sn–Au. The differences in element enrichment and mineral composition between these sediment types were closely related to their sedimentary environments (e.g., near/far away from the vent sites) and inherited from their host (source) rock. Together with combinations of certain characteristic elements (such as Al–Fe–Mn and Si–Al–Mg), relict hydrothermal products, and diagnostic mineral tracers (e.g., nontronite, SiO<sub>2(bio)</sub>, olivine, serpentine, talc, sepiolite, pyroxene, zeolite, etc.), it would be more effective to differentiate the host rock of deep-sea sediments and to detect a possible hydrothermal input.
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spelling doaj.art-7d9d8bf84eab4bd994750d47ac3740e52023-12-03T15:17:08ZengMDPI AGMinerals2075-163X2021-01-0111213810.3390/min11020138Mineralogy and Geochemistry of Deep-Sea Sediments from the Ultraslow-Spreading Southwest Indian Ridge: Implications for Hydrothermal Input and Igneous Host RockXian Chen0Xiaoming Sun1Zhongwei Wu2Yan Wang3Xiao Lin4Hongjun Chen5School of Marine Sciences, Sun Yat-Sen University, Guangzhou 510006, ChinaSchool of Marine Sciences, Sun Yat-Sen University, Guangzhou 510006, ChinaSchool of Marine Sciences, Sun Yat-Sen University, Guangzhou 510006, ChinaSouth China Sea Institute of Planning and Environmental Research, Ministry of Natural Resources, Guangzhou 510300, ChinaSchool of Marine Sciences, Sun Yat-Sen University, Guangzhou 510006, ChinaSchool of Marine Sciences, Sun Yat-Sen University, Guangzhou 510006, ChinaDetailed mineralogical and geochemical characteristics of typical surface sediments and hydrothermal deposits collected from the ultraslow-spreading Southwest Indian Ridge (SWIR) were studied by high-resolution XRD, SEM-EDS, XRF, and ICP-MS. The SWIR marine samples can be generally classified into two main categories: surface sediment (biogenic, volcanic) and hydrothermal-derived deposit; moreover, the surface sediment can be further classified into metalliferous and non-metalliferous based on the metalliferous sediment index (MSI). The chemical composition of biogenic sediment (mainly biogenic calcite) was characterized by elevated contents of Ca, Ba, Rb, Sr, Th, and light rare earth elements (LREE), while volcanic sediment (mainly volcanogenic debris) was relatively enriched in Mn, Mg, Al, Si, Ni, Cr, and high field strength elements (HFSEs). By contrast, the hydrothermal-derived deposit (mainly pyrite-marcasite, chalcopyrite-isocubanite, and low-temperature cherts) contained significantly higher contents of Fe, Cu, Zn, Pb, Mn, Co, Mo, Ag, and U. In addition, the metalliferous surface sediment contained a higher content of Cu, Mn, Fe, Co, Mo, Ba, and As. Compared with their different host (source) rock, the basalt-hosted marine sediments contained higher contents of Ti–Al–Zr–Sc–Hf and/or Mo–Ba–Ag; In contrast, the peridotite-hosted marine sediments were typically characterized by elevated concentrations of Mg–Cu–Ni–Cr and/or Co–Sn–Au. The differences in element enrichment and mineral composition between these sediment types were closely related to their sedimentary environments (e.g., near/far away from the vent sites) and inherited from their host (source) rock. Together with combinations of certain characteristic elements (such as Al–Fe–Mn and Si–Al–Mg), relict hydrothermal products, and diagnostic mineral tracers (e.g., nontronite, SiO<sub>2(bio)</sub>, olivine, serpentine, talc, sepiolite, pyroxene, zeolite, etc.), it would be more effective to differentiate the host rock of deep-sea sediments and to detect a possible hydrothermal input.https://www.mdpi.com/2075-163X/11/2/138Southwest Indian Ridgesurface sediment and hydrothermal-derived depositmineralogy and geochemistrymetalliferous and non-metalliferousperidotite- and basalt-hosted
spellingShingle Xian Chen
Xiaoming Sun
Zhongwei Wu
Yan Wang
Xiao Lin
Hongjun Chen
Mineralogy and Geochemistry of Deep-Sea Sediments from the Ultraslow-Spreading Southwest Indian Ridge: Implications for Hydrothermal Input and Igneous Host Rock
Minerals
Southwest Indian Ridge
surface sediment and hydrothermal-derived deposit
mineralogy and geochemistry
metalliferous and non-metalliferous
peridotite- and basalt-hosted
title Mineralogy and Geochemistry of Deep-Sea Sediments from the Ultraslow-Spreading Southwest Indian Ridge: Implications for Hydrothermal Input and Igneous Host Rock
title_full Mineralogy and Geochemistry of Deep-Sea Sediments from the Ultraslow-Spreading Southwest Indian Ridge: Implications for Hydrothermal Input and Igneous Host Rock
title_fullStr Mineralogy and Geochemistry of Deep-Sea Sediments from the Ultraslow-Spreading Southwest Indian Ridge: Implications for Hydrothermal Input and Igneous Host Rock
title_full_unstemmed Mineralogy and Geochemistry of Deep-Sea Sediments from the Ultraslow-Spreading Southwest Indian Ridge: Implications for Hydrothermal Input and Igneous Host Rock
title_short Mineralogy and Geochemistry of Deep-Sea Sediments from the Ultraslow-Spreading Southwest Indian Ridge: Implications for Hydrothermal Input and Igneous Host Rock
title_sort mineralogy and geochemistry of deep sea sediments from the ultraslow spreading southwest indian ridge implications for hydrothermal input and igneous host rock
topic Southwest Indian Ridge
surface sediment and hydrothermal-derived deposit
mineralogy and geochemistry
metalliferous and non-metalliferous
peridotite- and basalt-hosted
url https://www.mdpi.com/2075-163X/11/2/138
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