Surface Observation and Magnetism of Oil-Extracted Botryococcus braunii Residues before and after Carbonization

Microalgae is a promising next-generational energy. In this research, we focus on oil-extracted Botryococcus braunii residues collected by adding polysilicato-iron (PSI) as a flocculant followed by carbonization under argon atmosphere. We conducted carbonization at various temperatures as a first at...

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Main Authors: Aohan Wang, Mikihide Demura, Makoto M. Watanabe, Kotaro Ohara, Takanari Kashiwagi, Kazuo Kadowaki, Eiji Kita, Jiuchao Dong, Hiromasa Goto
Format: Article
Language:English
Published: MDPI AG 2018-02-01
Series:C
Subjects:
Online Access:http://www.mdpi.com/2311-5629/4/1/10
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author Aohan Wang
Mikihide Demura
Makoto M. Watanabe
Kotaro Ohara
Takanari Kashiwagi
Kazuo Kadowaki
Eiji Kita
Jiuchao Dong
Hiromasa Goto
author_facet Aohan Wang
Mikihide Demura
Makoto M. Watanabe
Kotaro Ohara
Takanari Kashiwagi
Kazuo Kadowaki
Eiji Kita
Jiuchao Dong
Hiromasa Goto
author_sort Aohan Wang
collection DOAJ
description Microalgae is a promising next-generational energy. In this research, we focus on oil-extracted Botryococcus braunii residues collected by adding polysilicato-iron (PSI) as a flocculant followed by carbonization under argon atmosphere. We conducted carbonization at various temperatures as a first attempt to reveal the fundamental properties of the carbonization process of the microbes. The carbons thus obtained by heat treatment at 900 °C present a unique magnetic behavior due to reduced magnetite (Fe3O4) inclusion, which is produced from polysilicato iron (Fe2O3) during the heating process. Experimental results suggest that this carbonic material can be applied as a heavy metal-capturing carbon and magnetic porous substrate catalyst. The effective use of the waste may open a new avenue for an energy-microbiology-materials system.
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spelling doaj.art-7db1eace135f4e8c954d89a17ab841252022-12-22T00:32:20ZengMDPI AGC2311-56292018-02-01411010.3390/c4010010c4010010Surface Observation and Magnetism of Oil-Extracted Botryococcus braunii Residues before and after CarbonizationAohan Wang0Mikihide Demura1Makoto M. Watanabe2Kotaro Ohara3Takanari Kashiwagi4Kazuo Kadowaki5Eiji Kita6Jiuchao Dong7Hiromasa Goto8Division of Materials Science, Faculty of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Ibaraki 305-8573, JapanAlgae Biomass and Energy System R & D Center (ABES), University of Tsukuba, Tsukuba, Ibaraki 305-8572, JapanAlgae Biomass and Energy System R & D Center (ABES), University of Tsukuba, Tsukuba, Ibaraki 305-8572, JapanDivision of Materials Science, Faculty of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Ibaraki 305-8573, JapanDivision of Materials Science, Faculty of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Ibaraki 305-8573, JapanDivision of Materials Science, Faculty of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Ibaraki 305-8573, JapanDivision of Applied Physics, Faculty of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Ibaraki 305-8573, JapanDivision of Materials Science, Faculty of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Ibaraki 305-8573, JapanDivision of Materials Science, Faculty of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Ibaraki 305-8573, JapanMicroalgae is a promising next-generational energy. In this research, we focus on oil-extracted Botryococcus braunii residues collected by adding polysilicato-iron (PSI) as a flocculant followed by carbonization under argon atmosphere. We conducted carbonization at various temperatures as a first attempt to reveal the fundamental properties of the carbonization process of the microbes. The carbons thus obtained by heat treatment at 900 °C present a unique magnetic behavior due to reduced magnetite (Fe3O4) inclusion, which is produced from polysilicato iron (Fe2O3) during the heating process. Experimental results suggest that this carbonic material can be applied as a heavy metal-capturing carbon and magnetic porous substrate catalyst. The effective use of the waste may open a new avenue for an energy-microbiology-materials system.http://www.mdpi.com/2311-5629/4/1/10Botryococcus braunii residuescarbonizationmagnetismporous structuresuperconducting quantum interference device (SQUID)57Fe Mössbauerpolysilicato-ironFe3O4flocculant
spellingShingle Aohan Wang
Mikihide Demura
Makoto M. Watanabe
Kotaro Ohara
Takanari Kashiwagi
Kazuo Kadowaki
Eiji Kita
Jiuchao Dong
Hiromasa Goto
Surface Observation and Magnetism of Oil-Extracted Botryococcus braunii Residues before and after Carbonization
C
Botryococcus braunii residues
carbonization
magnetism
porous structure
superconducting quantum interference device (SQUID)
57Fe Mössbauer
polysilicato-iron
Fe3O4
flocculant
title Surface Observation and Magnetism of Oil-Extracted Botryococcus braunii Residues before and after Carbonization
title_full Surface Observation and Magnetism of Oil-Extracted Botryococcus braunii Residues before and after Carbonization
title_fullStr Surface Observation and Magnetism of Oil-Extracted Botryococcus braunii Residues before and after Carbonization
title_full_unstemmed Surface Observation and Magnetism of Oil-Extracted Botryococcus braunii Residues before and after Carbonization
title_short Surface Observation and Magnetism of Oil-Extracted Botryococcus braunii Residues before and after Carbonization
title_sort surface observation and magnetism of oil extracted botryococcus braunii residues before and after carbonization
topic Botryococcus braunii residues
carbonization
magnetism
porous structure
superconducting quantum interference device (SQUID)
57Fe Mössbauer
polysilicato-iron
Fe3O4
flocculant
url http://www.mdpi.com/2311-5629/4/1/10
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