Recent Advances in C<sub>5</sub> and C<sub>6</sub> Sugar Alcohol Synthesis by Hydrogenation of Monosaccharides and Cellulose Hydrolytic Hydrogenation over Non-Noble Metal Catalysts
A new reality of the 21st century is the transition to a new type of economy and energy concepts characterized by the replacement of existing petrochemical routes to a bio-based circular economy. The needs for new strategies in obtaining basic products from bio-based resources with minimum CO<sub...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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MDPI AG
2022-02-01
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| Series: | Molecules |
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| Online Access: | https://www.mdpi.com/1420-3049/27/4/1353 |
| _version_ | 1827653512046051328 |
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| author | Elena Redina Olga Tkachenko Tapio Salmi |
| author_facet | Elena Redina Olga Tkachenko Tapio Salmi |
| author_sort | Elena Redina |
| collection | DOAJ |
| description | A new reality of the 21st century is the transition to a new type of economy and energy concepts characterized by the replacement of existing petrochemical routes to a bio-based circular economy. The needs for new strategies in obtaining basic products from bio-based resources with minimum CO<sub>2</sub> traces has become mandatory. In this review, recent trends in the conversion of biomass-derived molecules, such as simple monomeric sugars and cellulose, to industrially important C<sub>5</sub> and C<sub>6</sub> sugar alcohols on heterogeneous catalysts based on non-noble metals are discussed focusing on the influence of catalyst structures and reaction conditions used on the substrate conversion and product selectivity. The challenges and prominent ideas are suggested for the further development of catalytic hydrogenation of naturally abundant carbohydrates to value-added chemicals on non-noble metal catalysts. |
| first_indexed | 2024-03-09T21:20:54Z |
| format | Article |
| id | doaj.art-7dd135fffe7e450696d148df5233ec33 |
| institution | Directory Open Access Journal |
| issn | 1420-3049 |
| language | English |
| last_indexed | 2024-03-09T21:20:54Z |
| publishDate | 2022-02-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj.art-7dd135fffe7e450696d148df5233ec332023-11-23T21:22:40ZengMDPI AGMolecules1420-30492022-02-01274135310.3390/molecules27041353Recent Advances in C<sub>5</sub> and C<sub>6</sub> Sugar Alcohol Synthesis by Hydrogenation of Monosaccharides and Cellulose Hydrolytic Hydrogenation over Non-Noble Metal CatalystsElena Redina0Olga Tkachenko1Tapio Salmi2N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Prospect, 119991 Moscow, RussiaN.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Prospect, 119991 Moscow, RussiaJohan Gadolin Process Chemistry Centre, Abo Akademi University, FI-20500 Turku, FinlandA new reality of the 21st century is the transition to a new type of economy and energy concepts characterized by the replacement of existing petrochemical routes to a bio-based circular economy. The needs for new strategies in obtaining basic products from bio-based resources with minimum CO<sub>2</sub> traces has become mandatory. In this review, recent trends in the conversion of biomass-derived molecules, such as simple monomeric sugars and cellulose, to industrially important C<sub>5</sub> and C<sub>6</sub> sugar alcohols on heterogeneous catalysts based on non-noble metals are discussed focusing on the influence of catalyst structures and reaction conditions used on the substrate conversion and product selectivity. The challenges and prominent ideas are suggested for the further development of catalytic hydrogenation of naturally abundant carbohydrates to value-added chemicals on non-noble metal catalysts.https://www.mdpi.com/1420-3049/27/4/1353sugar alcoholcelluloseglucosesorbitolxylitolmannitol |
| spellingShingle | Elena Redina Olga Tkachenko Tapio Salmi Recent Advances in C<sub>5</sub> and C<sub>6</sub> Sugar Alcohol Synthesis by Hydrogenation of Monosaccharides and Cellulose Hydrolytic Hydrogenation over Non-Noble Metal Catalysts Molecules sugar alcohol cellulose glucose sorbitol xylitol mannitol |
| title | Recent Advances in C<sub>5</sub> and C<sub>6</sub> Sugar Alcohol Synthesis by Hydrogenation of Monosaccharides and Cellulose Hydrolytic Hydrogenation over Non-Noble Metal Catalysts |
| title_full | Recent Advances in C<sub>5</sub> and C<sub>6</sub> Sugar Alcohol Synthesis by Hydrogenation of Monosaccharides and Cellulose Hydrolytic Hydrogenation over Non-Noble Metal Catalysts |
| title_fullStr | Recent Advances in C<sub>5</sub> and C<sub>6</sub> Sugar Alcohol Synthesis by Hydrogenation of Monosaccharides and Cellulose Hydrolytic Hydrogenation over Non-Noble Metal Catalysts |
| title_full_unstemmed | Recent Advances in C<sub>5</sub> and C<sub>6</sub> Sugar Alcohol Synthesis by Hydrogenation of Monosaccharides and Cellulose Hydrolytic Hydrogenation over Non-Noble Metal Catalysts |
| title_short | Recent Advances in C<sub>5</sub> and C<sub>6</sub> Sugar Alcohol Synthesis by Hydrogenation of Monosaccharides and Cellulose Hydrolytic Hydrogenation over Non-Noble Metal Catalysts |
| title_sort | recent advances in c sub 5 sub and c sub 6 sub sugar alcohol synthesis by hydrogenation of monosaccharides and cellulose hydrolytic hydrogenation over non noble metal catalysts |
| topic | sugar alcohol cellulose glucose sorbitol xylitol mannitol |
| url | https://www.mdpi.com/1420-3049/27/4/1353 |
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