LANTHANIDE OXYIODIDES
The present review is devoted to consideration and generalization of a number of synthetic methods for lanthanide oxoiodides preparation as well as to consideration of their structural particularities and thermal stability. Phase diagrams with the participation of REE oxoiodides, alkaline metal iodi...
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Format: | Article |
Language: | Russian |
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MIREA - Russian Technological University
2016-02-01
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Series: | Тонкие химические технологии |
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Online Access: | https://www.finechem-mirea.ru/jour/article/view/2 |
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author | N. S. Rukk R. M. Zakalyukin A. Yu. Skryabina |
author_facet | N. S. Rukk R. M. Zakalyukin A. Yu. Skryabina |
author_sort | N. S. Rukk |
collection | DOAJ |
description | The present review is devoted to consideration and generalization of a number of synthetic methods for lanthanide oxoiodides preparation as well as to consideration of their structural particularities and thermal stability. Phase diagrams with the participation of REE oxoiodides, alkaline metal iodides or silver iodide are given and discussed. All the systems are characterized by the solid solution formation on the basis of the pure compounds, while the systems with the participation of alkaline metal iodides are characterized by the formation of incongruent melting compounds. Structural data concerning oxoiodides of lanthanides with different oxidation states and with the participation of some other elements (carbon, nitrogen, barium, osmium, etc) are present and overviewed. Possible areas of application (catalysis, X-ray detectors, medical diagnostics) including distinct luminescent properties of Ce-, Pr-, Nd-, Sm-doped REE oxoiodides are underlined. |
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id | doaj.art-7de6110c4a5e4203bb4d2306bebe733c |
institution | Directory Open Access Journal |
issn | 2410-6593 2686-7575 |
language | Russian |
last_indexed | 2025-03-14T10:40:16Z |
publishDate | 2016-02-01 |
publisher | MIREA - Russian Technological University |
record_format | Article |
series | Тонкие химические технологии |
spelling | doaj.art-7de6110c4a5e4203bb4d2306bebe733c2025-03-02T10:57:33ZrusMIREA - Russian Technological UniversityТонкие химические технологии2410-65932686-75752016-02-0111152210.32362/2410-6593-2016-11-1-5-222LANTHANIDE OXYIODIDESN. S. Rukk0R. M. Zakalyukin1A. Yu. Skryabina2Moscow Technological University (Institute of Fine Chemical Technologies)Moscow Technological University (Institute of Fine Chemical Technologies)Moscow Technological University (Institute of Fine Chemical Technologies)The present review is devoted to consideration and generalization of a number of synthetic methods for lanthanide oxoiodides preparation as well as to consideration of their structural particularities and thermal stability. Phase diagrams with the participation of REE oxoiodides, alkaline metal iodides or silver iodide are given and discussed. All the systems are characterized by the solid solution formation on the basis of the pure compounds, while the systems with the participation of alkaline metal iodides are characterized by the formation of incongruent melting compounds. Structural data concerning oxoiodides of lanthanides with different oxidation states and with the participation of some other elements (carbon, nitrogen, barium, osmium, etc) are present and overviewed. Possible areas of application (catalysis, X-ray detectors, medical diagnostics) including distinct luminescent properties of Ce-, Pr-, Nd-, Sm-doped REE oxoiodides are underlined.https://www.finechem-mirea.ru/jour/article/view/2rare earth elements (ree)iodideoxoiodidesphase equilibriacrystal structure |
spellingShingle | N. S. Rukk R. M. Zakalyukin A. Yu. Skryabina LANTHANIDE OXYIODIDES Тонкие химические технологии rare earth elements (ree) iodide oxoiodides phase equilibria crystal structure |
title | LANTHANIDE OXYIODIDES |
title_full | LANTHANIDE OXYIODIDES |
title_fullStr | LANTHANIDE OXYIODIDES |
title_full_unstemmed | LANTHANIDE OXYIODIDES |
title_short | LANTHANIDE OXYIODIDES |
title_sort | lanthanide oxyiodides |
topic | rare earth elements (ree) iodide oxoiodides phase equilibria crystal structure |
url | https://www.finechem-mirea.ru/jour/article/view/2 |
work_keys_str_mv | AT nsrukk lanthanideoxyiodides AT rmzakalyukin lanthanideoxyiodides AT ayuskryabina lanthanideoxyiodides |