LANTHANIDE OXYIODIDES

The present review is devoted to consideration and generalization of a number of synthetic methods for lanthanide oxoiodides preparation as well as to consideration of their structural particularities and thermal stability. Phase diagrams with the participation of REE oxoiodides, alkaline metal iodi...

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Main Authors: N. S. Rukk, R. M. Zakalyukin, A. Yu. Skryabina
Format: Article
Language:Russian
Published: MIREA - Russian Technological University 2016-02-01
Series:Тонкие химические технологии
Subjects:
Online Access:https://www.finechem-mirea.ru/jour/article/view/2
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author N. S. Rukk
R. M. Zakalyukin
A. Yu. Skryabina
author_facet N. S. Rukk
R. M. Zakalyukin
A. Yu. Skryabina
author_sort N. S. Rukk
collection DOAJ
description The present review is devoted to consideration and generalization of a number of synthetic methods for lanthanide oxoiodides preparation as well as to consideration of their structural particularities and thermal stability. Phase diagrams with the participation of REE oxoiodides, alkaline metal iodides or silver iodide are given and discussed. All the systems are characterized by the solid solution formation on the basis of the pure compounds, while the systems with the participation of alkaline metal iodides are characterized by the formation of incongruent melting compounds. Structural data concerning oxoiodides of lanthanides with different oxidation states and with the participation of some other elements (carbon, nitrogen, barium, osmium, etc) are present and overviewed. Possible areas of application (catalysis, X-ray detectors, medical diagnostics) including distinct luminescent properties of Ce-, Pr-, Nd-, Sm-doped REE oxoiodides are underlined.
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spelling doaj.art-7de6110c4a5e4203bb4d2306bebe733c2025-03-02T10:57:33ZrusMIREA - Russian Technological UniversityТонкие химические технологии2410-65932686-75752016-02-0111152210.32362/2410-6593-2016-11-1-5-222LANTHANIDE OXYIODIDESN. S. Rukk0R. M. Zakalyukin1A. Yu. Skryabina2Moscow Technological University (Institute of Fine Chemical Technologies)Moscow Technological University (Institute of Fine Chemical Technologies)Moscow Technological University (Institute of Fine Chemical Technologies)The present review is devoted to consideration and generalization of a number of synthetic methods for lanthanide oxoiodides preparation as well as to consideration of their structural particularities and thermal stability. Phase diagrams with the participation of REE oxoiodides, alkaline metal iodides or silver iodide are given and discussed. All the systems are characterized by the solid solution formation on the basis of the pure compounds, while the systems with the participation of alkaline metal iodides are characterized by the formation of incongruent melting compounds. Structural data concerning oxoiodides of lanthanides with different oxidation states and with the participation of some other elements (carbon, nitrogen, barium, osmium, etc) are present and overviewed. Possible areas of application (catalysis, X-ray detectors, medical diagnostics) including distinct luminescent properties of Ce-, Pr-, Nd-, Sm-doped REE oxoiodides are underlined.https://www.finechem-mirea.ru/jour/article/view/2rare earth elements (ree)iodideoxoiodidesphase equilibriacrystal structure
spellingShingle N. S. Rukk
R. M. Zakalyukin
A. Yu. Skryabina
LANTHANIDE OXYIODIDES
Тонкие химические технологии
rare earth elements (ree)
iodide
oxoiodides
phase equilibria
crystal structure
title LANTHANIDE OXYIODIDES
title_full LANTHANIDE OXYIODIDES
title_fullStr LANTHANIDE OXYIODIDES
title_full_unstemmed LANTHANIDE OXYIODIDES
title_short LANTHANIDE OXYIODIDES
title_sort lanthanide oxyiodides
topic rare earth elements (ree)
iodide
oxoiodides
phase equilibria
crystal structure
url https://www.finechem-mirea.ru/jour/article/view/2
work_keys_str_mv AT nsrukk lanthanideoxyiodides
AT rmzakalyukin lanthanideoxyiodides
AT ayuskryabina lanthanideoxyiodides