Bis(dicyanamido-κN)tetrakis(pyridine-κN)nickel(II)
In the crystal structure of the title compound, [Ni(C2N3)2(C5H5N)4], the NiII cations are coordinated by four pyridine ligands and two dicyanamide anions into discrete complexes. The shortest Ni...Ni separation is 8.1068 (10) Å. The structure is pseudo-centro...
Main Authors: | , , , |
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Format: | Article |
Language: | English |
Published: |
International Union of Crystallography
2012-06-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812019691 |
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author | Susanne Wöhlert Mario Wriedt Inke Jess Christian Näther |
author_facet | Susanne Wöhlert Mario Wriedt Inke Jess Christian Näther |
author_sort | Susanne Wöhlert |
collection | DOAJ |
description | In the crystal structure of the title compound, [Ni(C2N3)2(C5H5N)4], the NiII cations are coordinated by four pyridine ligands and two dicyanamide anions into discrete complexes. The shortest Ni...Ni separation is 8.1068 (10) Å. The structure is pseudo-centrosymmetric and can also be refined in the space group C2/c in which both anionic ligands are strongly disordered and the refinement leads to significantly poorer reliability factors. |
first_indexed | 2024-04-11T18:26:31Z |
format | Article |
id | doaj.art-7e0ccd937040457ea69640c68d59ab4f |
institution | Directory Open Access Journal |
issn | 1600-5368 |
language | English |
last_indexed | 2024-04-11T18:26:31Z |
publishDate | 2012-06-01 |
publisher | International Union of Crystallography |
record_format | Article |
series | Acta Crystallographica Section E |
spelling | doaj.art-7e0ccd937040457ea69640c68d59ab4f2022-12-22T04:09:36ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-06-01686m745m74510.1107/S1600536812019691Bis(dicyanamido-κN)tetrakis(pyridine-κN)nickel(II)Susanne WöhlertMario WriedtInke JessChristian NätherIn the crystal structure of the title compound, [Ni(C2N3)2(C5H5N)4], the NiII cations are coordinated by four pyridine ligands and two dicyanamide anions into discrete complexes. The shortest Ni...Ni separation is 8.1068 (10) Å. The structure is pseudo-centrosymmetric and can also be refined in the space group C2/c in which both anionic ligands are strongly disordered and the refinement leads to significantly poorer reliability factors.http://scripts.iucr.org/cgi-bin/paper?S1600536812019691 |
spellingShingle | Susanne Wöhlert Mario Wriedt Inke Jess Christian Näther Bis(dicyanamido-κN)tetrakis(pyridine-κN)nickel(II) Acta Crystallographica Section E |
title | Bis(dicyanamido-κN)tetrakis(pyridine-κN)nickel(II) |
title_full | Bis(dicyanamido-κN)tetrakis(pyridine-κN)nickel(II) |
title_fullStr | Bis(dicyanamido-κN)tetrakis(pyridine-κN)nickel(II) |
title_full_unstemmed | Bis(dicyanamido-κN)tetrakis(pyridine-κN)nickel(II) |
title_short | Bis(dicyanamido-κN)tetrakis(pyridine-κN)nickel(II) |
title_sort | bis dicyanamido amp 954 n tetrakis pyridine amp 954 n nickel ii |
url | http://scripts.iucr.org/cgi-bin/paper?S1600536812019691 |
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