Bis(dicyanamido-κN)tetrakis(pyridine-κN)nickel(II)

In the crystal structure of the title compound, [Ni(C2N3)2(C5H5N)4], the NiII cations are coordinated by four pyridine ligands and two dicyanamide anions into discrete complexes. The shortest Ni...Ni separation is 8.1068 (10) Å. The structure is pseudo-centro...

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Main Authors: Susanne Wöhlert, Mario Wriedt, Inke Jess, Christian Näther
Format: Article
Language:English
Published: International Union of Crystallography 2012-06-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812019691
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author Susanne Wöhlert
Mario Wriedt
Inke Jess
Christian Näther
author_facet Susanne Wöhlert
Mario Wriedt
Inke Jess
Christian Näther
author_sort Susanne Wöhlert
collection DOAJ
description In the crystal structure of the title compound, [Ni(C2N3)2(C5H5N)4], the NiII cations are coordinated by four pyridine ligands and two dicyanamide anions into discrete complexes. The shortest Ni...Ni separation is 8.1068 (10) Å. The structure is pseudo-centrosymmetric and can also be refined in the space group C2/c in which both anionic ligands are strongly disordered and the refinement leads to significantly poorer reliability factors.
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spelling doaj.art-7e0ccd937040457ea69640c68d59ab4f2022-12-22T04:09:36ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-06-01686m745m74510.1107/S1600536812019691Bis(dicyanamido-κN)tetrakis(pyridine-κN)nickel(II)Susanne WöhlertMario WriedtInke JessChristian NätherIn the crystal structure of the title compound, [Ni(C2N3)2(C5H5N)4], the NiII cations are coordinated by four pyridine ligands and two dicyanamide anions into discrete complexes. The shortest Ni...Ni separation is 8.1068 (10) Å. The structure is pseudo-centrosymmetric and can also be refined in the space group C2/c in which both anionic ligands are strongly disordered and the refinement leads to significantly poorer reliability factors.http://scripts.iucr.org/cgi-bin/paper?S1600536812019691
spellingShingle Susanne Wöhlert
Mario Wriedt
Inke Jess
Christian Näther
Bis(dicyanamido-κN)tetrakis(pyridine-κN)nickel(II)
Acta Crystallographica Section E
title Bis(dicyanamido-κN)tetrakis(pyridine-κN)nickel(II)
title_full Bis(dicyanamido-κN)tetrakis(pyridine-κN)nickel(II)
title_fullStr Bis(dicyanamido-κN)tetrakis(pyridine-κN)nickel(II)
title_full_unstemmed Bis(dicyanamido-κN)tetrakis(pyridine-κN)nickel(II)
title_short Bis(dicyanamido-κN)tetrakis(pyridine-κN)nickel(II)
title_sort bis dicyanamido amp 954 n tetrakis pyridine amp 954 n nickel ii
url http://scripts.iucr.org/cgi-bin/paper?S1600536812019691
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AT inkejess bisdicyanamidoamp954ntetrakispyridineamp954nnickelii
AT christiannamp228ther bisdicyanamidoamp954ntetrakispyridineamp954nnickelii