Bis[μ-2-(4-hydroxyphenyl)acetato]-κ3O,O′:O;κ3O:O,O′-bis{aqua(4,4′-bipyridine-κN)bis[2-(4-hydroxyphenyl)acetato-κ2O,O′]thulium(III)} monohydrate
In the title dinuclear complex, [Tm2(C8H7O3)6(C10H8N2)2(H2O)2]·H2O, the TmIII atoms are coordinated by eight O atoms from four 2-(4-hydroxyphenyl)acetate (HPAA) ligands and a water molecule, and one N atom from a 4,4′-bipyridine ligand in a distorted tricapped trigonal&...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2010-11-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810043898 |
| _version_ | 1819279892926169088 |
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| author | Jia-Lu Liu Jian-Feng Liu Guo-Liang Zhao |
| author_facet | Jia-Lu Liu Jian-Feng Liu Guo-Liang Zhao |
| author_sort | Jia-Lu Liu |
| collection | DOAJ |
| description | In the title dinuclear complex, [Tm2(C8H7O3)6(C10H8N2)2(H2O)2]·H2O, the TmIII atoms are coordinated by eight O atoms from four 2-(4-hydroxyphenyl)acetate (HPAA) ligands and a water molecule, and one N atom from a 4,4′-bipyridine ligand in a distorted tricapped trigonal–prismatic geometry. While four of the HPAA ligands coordinate to just one Tm atom, the remaining two HPAA ligands bridge the two Tm atoms. In the crystal, O—H...O and O—H...N hydrogen bonds link the molecules into a three-dimensional network. |
| first_indexed | 2024-12-24T00:35:08Z |
| format | Article |
| id | doaj.art-7e19efaa89434a61bd6444b7d52664fc |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T00:35:08Z |
| publishDate | 2010-11-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-7e19efaa89434a61bd6444b7d52664fc2022-12-21T17:24:06ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-11-016611m1497m149710.1107/S1600536810043898Bis[μ-2-(4-hydroxyphenyl)acetato]-κ3O,O′:O;κ3O:O,O′-bis{aqua(4,4′-bipyridine-κN)bis[2-(4-hydroxyphenyl)acetato-κ2O,O′]thulium(III)} monohydrateJia-Lu LiuJian-Feng LiuGuo-Liang ZhaoIn the title dinuclear complex, [Tm2(C8H7O3)6(C10H8N2)2(H2O)2]·H2O, the TmIII atoms are coordinated by eight O atoms from four 2-(4-hydroxyphenyl)acetate (HPAA) ligands and a water molecule, and one N atom from a 4,4′-bipyridine ligand in a distorted tricapped trigonal–prismatic geometry. While four of the HPAA ligands coordinate to just one Tm atom, the remaining two HPAA ligands bridge the two Tm atoms. In the crystal, O—H...O and O—H...N hydrogen bonds link the molecules into a three-dimensional network.http://scripts.iucr.org/cgi-bin/paper?S1600536810043898 |
| spellingShingle | Jia-Lu Liu Jian-Feng Liu Guo-Liang Zhao Bis[μ-2-(4-hydroxyphenyl)acetato]-κ3O,O′:O;κ3O:O,O′-bis{aqua(4,4′-bipyridine-κN)bis[2-(4-hydroxyphenyl)acetato-κ2O,O′]thulium(III)} monohydrate Acta Crystallographica Section E |
| title | Bis[μ-2-(4-hydroxyphenyl)acetato]-κ3O,O′:O;κ3O:O,O′-bis{aqua(4,4′-bipyridine-κN)bis[2-(4-hydroxyphenyl)acetato-κ2O,O′]thulium(III)} monohydrate |
| title_full | Bis[μ-2-(4-hydroxyphenyl)acetato]-κ3O,O′:O;κ3O:O,O′-bis{aqua(4,4′-bipyridine-κN)bis[2-(4-hydroxyphenyl)acetato-κ2O,O′]thulium(III)} monohydrate |
| title_fullStr | Bis[μ-2-(4-hydroxyphenyl)acetato]-κ3O,O′:O;κ3O:O,O′-bis{aqua(4,4′-bipyridine-κN)bis[2-(4-hydroxyphenyl)acetato-κ2O,O′]thulium(III)} monohydrate |
| title_full_unstemmed | Bis[μ-2-(4-hydroxyphenyl)acetato]-κ3O,O′:O;κ3O:O,O′-bis{aqua(4,4′-bipyridine-κN)bis[2-(4-hydroxyphenyl)acetato-κ2O,O′]thulium(III)} monohydrate |
| title_short | Bis[μ-2-(4-hydroxyphenyl)acetato]-κ3O,O′:O;κ3O:O,O′-bis{aqua(4,4′-bipyridine-κN)bis[2-(4-hydroxyphenyl)acetato-κ2O,O′]thulium(III)} monohydrate |
| title_sort | bis amp 956 2 4 hydroxyphenyl acetato amp 954 3o o amp 8242 o amp 954 3o o o amp 8242 bis aqua 4 4 amp 8242 bipyridine amp 954 n bis 2 4 hydroxyphenyl acetato amp 954 2o o amp 8242 thulium iii monohydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810043898 |
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