Investigation on Surface Polarization of Al2O3-capped GaN/AlGaN/GaN Heterostructure by Angle-Resolved X-ray Photoelectron Spectroscopy

Abstract The surface polarization of Ga-face gallium nitride (GaN) (2 nm)/AlGaN (22 nm)/GaN channel (150 nm)/buffer/Si with Al2O3 capping layer is investigated by angle-resolved X-ray photoelectron spectroscopy (ARXPS). It is found that the energy band varies from upward bending to downward bending...

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Main Authors: Tian Li Duan, Ji Sheng Pan, Ning Wang, Kai Cheng, Hong Yu Yu
Format: Article
Language:English
Published: SpringerOpen 2017-08-01
Series:Nanoscale Research Letters
Subjects:
Online Access:http://link.springer.com/article/10.1186/s11671-017-2271-x
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author Tian Li Duan
Ji Sheng Pan
Ning Wang
Kai Cheng
Hong Yu Yu
author_facet Tian Li Duan
Ji Sheng Pan
Ning Wang
Kai Cheng
Hong Yu Yu
author_sort Tian Li Duan
collection DOAJ
description Abstract The surface polarization of Ga-face gallium nitride (GaN) (2 nm)/AlGaN (22 nm)/GaN channel (150 nm)/buffer/Si with Al2O3 capping layer is investigated by angle-resolved X-ray photoelectron spectroscopy (ARXPS). It is found that the energy band varies from upward bending to downward bending in the interface region, which is believed to be corresponding to the polarization variation. An interfacial layer is formed between top GaN and Al2O3 due to the occurrence of Ga–N bond break and Ga–O bond forming during Al2O3 deposition via the atomic layer deposition (ALD). This interfacial layer is believed to eliminate the GaN polarization, thus reducing the polarization-induced negative charges. Furthermore, this interfacial layer plays a key role for the introduction of the positive charges which lead the energy band downward. Finally, a N2 annealing at 400 °C is observed to enhance the interfacial layer growth thus increasing the density of positive charges.
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spelling doaj.art-7e22b3768fb0485382b500235b73f5992023-09-03T02:39:30ZengSpringerOpenNanoscale Research Letters1931-75731556-276X2017-08-011211610.1186/s11671-017-2271-xInvestigation on Surface Polarization of Al2O3-capped GaN/AlGaN/GaN Heterostructure by Angle-Resolved X-ray Photoelectron SpectroscopyTian Li Duan0Ji Sheng Pan1Ning Wang2Kai Cheng3Hong Yu Yu4Southern University of Science and TechnologyInstitute of Materials Research and Engineering, A*STAR (Agency for Science, Technology and Research)Southern University of Science and TechnologyEnkris Semiconductor, IncSouthern University of Science and TechnologyAbstract The surface polarization of Ga-face gallium nitride (GaN) (2 nm)/AlGaN (22 nm)/GaN channel (150 nm)/buffer/Si with Al2O3 capping layer is investigated by angle-resolved X-ray photoelectron spectroscopy (ARXPS). It is found that the energy band varies from upward bending to downward bending in the interface region, which is believed to be corresponding to the polarization variation. An interfacial layer is formed between top GaN and Al2O3 due to the occurrence of Ga–N bond break and Ga–O bond forming during Al2O3 deposition via the atomic layer deposition (ALD). This interfacial layer is believed to eliminate the GaN polarization, thus reducing the polarization-induced negative charges. Furthermore, this interfacial layer plays a key role for the introduction of the positive charges which lead the energy band downward. Finally, a N2 annealing at 400 °C is observed to enhance the interfacial layer growth thus increasing the density of positive charges.http://link.springer.com/article/10.1186/s11671-017-2271-xSurface polarizationInterfacial layerARXPSGaN heterostructure
spellingShingle Tian Li Duan
Ji Sheng Pan
Ning Wang
Kai Cheng
Hong Yu Yu
Investigation on Surface Polarization of Al2O3-capped GaN/AlGaN/GaN Heterostructure by Angle-Resolved X-ray Photoelectron Spectroscopy
Nanoscale Research Letters
Surface polarization
Interfacial layer
ARXPS
GaN heterostructure
title Investigation on Surface Polarization of Al2O3-capped GaN/AlGaN/GaN Heterostructure by Angle-Resolved X-ray Photoelectron Spectroscopy
title_full Investigation on Surface Polarization of Al2O3-capped GaN/AlGaN/GaN Heterostructure by Angle-Resolved X-ray Photoelectron Spectroscopy
title_fullStr Investigation on Surface Polarization of Al2O3-capped GaN/AlGaN/GaN Heterostructure by Angle-Resolved X-ray Photoelectron Spectroscopy
title_full_unstemmed Investigation on Surface Polarization of Al2O3-capped GaN/AlGaN/GaN Heterostructure by Angle-Resolved X-ray Photoelectron Spectroscopy
title_short Investigation on Surface Polarization of Al2O3-capped GaN/AlGaN/GaN Heterostructure by Angle-Resolved X-ray Photoelectron Spectroscopy
title_sort investigation on surface polarization of al2o3 capped gan algan gan heterostructure by angle resolved x ray photoelectron spectroscopy
topic Surface polarization
Interfacial layer
ARXPS
GaN heterostructure
url http://link.springer.com/article/10.1186/s11671-017-2271-x
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AT jishengpan investigationonsurfacepolarizationofal2o3cappedganalganganheterostructurebyangleresolvedxrayphotoelectronspectroscopy
AT ningwang investigationonsurfacepolarizationofal2o3cappedganalganganheterostructurebyangleresolvedxrayphotoelectronspectroscopy
AT kaicheng investigationonsurfacepolarizationofal2o3cappedganalganganheterostructurebyangleresolvedxrayphotoelectronspectroscopy
AT hongyuyu investigationonsurfacepolarizationofal2o3cappedganalganganheterostructurebyangleresolvedxrayphotoelectronspectroscopy