Synthesis, Crystal Structure and Water Vapor Adsorption Properties of a Porous Supramolecular Architecture
A new complex, [Cu4(HL)4(H2O)14] (1, H3L·HCl = 5-((4-carboxypiperidin-1-yl)methyl)isophthalic acid hydrochloride), has been prepared and characterized by single-crystal X-ray diffraction, elemental analysis, IR spectroscopy and powder X-ray diffraction (PXRD). The result of the X-ray diffraction ana...
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MDPI AG
2017-10-01
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| Series: | Crystals |
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| Online Access: | https://www.mdpi.com/2073-4352/7/10/297 |
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| author | Rui Qiao Zi-You Zhang Mei-An Zhu |
| author_facet | Rui Qiao Zi-You Zhang Mei-An Zhu |
| author_sort | Rui Qiao |
| collection | DOAJ |
| description | A new complex, [Cu4(HL)4(H2O)14] (1, H3L·HCl = 5-((4-carboxypiperidin-1-yl)methyl)isophthalic acid hydrochloride), has been prepared and characterized by single-crystal X-ray diffraction, elemental analysis, IR spectroscopy and powder X-ray diffraction (PXRD). The result of the X-ray diffraction analysis reveals that the complex crystallizes in monoclinic, space group C2/c and three unique Cu(II) atoms that are connected by partially deprotonated HL2− anion to form a cyclic structure. The rich hydrogen bonding and π-π non-covalent packing interactions extend cyclic units into a three-dimensional (3D) supramolecular polymer. Moreover, the thermogravimetric (TG) analysis and water vapor adsorption property of 1 were also discussed. |
| first_indexed | 2024-04-13T00:42:11Z |
| format | Article |
| id | doaj.art-7e280c50e6254d13a8a755612ef1a8a2 |
| institution | Directory Open Access Journal |
| issn | 2073-4352 |
| language | English |
| last_indexed | 2024-04-13T00:42:11Z |
| publishDate | 2017-10-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Crystals |
| spelling | doaj.art-7e280c50e6254d13a8a755612ef1a8a22022-12-22T03:10:06ZengMDPI AGCrystals2073-43522017-10-0171029710.3390/cryst7100297cryst7100297Synthesis, Crystal Structure and Water Vapor Adsorption Properties of a Porous Supramolecular ArchitectureRui Qiao0Zi-You Zhang1Mei-An Zhu2College of Chemistry & Chemical Engineering, Fuyang Normal University, Fuyang 236041, ChinaCollege of Chemistry & Chemical Engineering, Fuyang Normal University, Fuyang 236041, ChinaCollege of Chemistry & Chemical Engineering, Fuyang Normal University, Fuyang 236041, ChinaA new complex, [Cu4(HL)4(H2O)14] (1, H3L·HCl = 5-((4-carboxypiperidin-1-yl)methyl)isophthalic acid hydrochloride), has been prepared and characterized by single-crystal X-ray diffraction, elemental analysis, IR spectroscopy and powder X-ray diffraction (PXRD). The result of the X-ray diffraction analysis reveals that the complex crystallizes in monoclinic, space group C2/c and three unique Cu(II) atoms that are connected by partially deprotonated HL2− anion to form a cyclic structure. The rich hydrogen bonding and π-π non-covalent packing interactions extend cyclic units into a three-dimensional (3D) supramolecular polymer. Moreover, the thermogravimetric (TG) analysis and water vapor adsorption property of 1 were also discussed.https://www.mdpi.com/2073-4352/7/10/297Cu(II) complexsupramolecular architecturewater vapor adsorption |
| spellingShingle | Rui Qiao Zi-You Zhang Mei-An Zhu Synthesis, Crystal Structure and Water Vapor Adsorption Properties of a Porous Supramolecular Architecture Crystals Cu(II) complex supramolecular architecture water vapor adsorption |
| title | Synthesis, Crystal Structure and Water Vapor Adsorption Properties of a Porous Supramolecular Architecture |
| title_full | Synthesis, Crystal Structure and Water Vapor Adsorption Properties of a Porous Supramolecular Architecture |
| title_fullStr | Synthesis, Crystal Structure and Water Vapor Adsorption Properties of a Porous Supramolecular Architecture |
| title_full_unstemmed | Synthesis, Crystal Structure and Water Vapor Adsorption Properties of a Porous Supramolecular Architecture |
| title_short | Synthesis, Crystal Structure and Water Vapor Adsorption Properties of a Porous Supramolecular Architecture |
| title_sort | synthesis crystal structure and water vapor adsorption properties of a porous supramolecular architecture |
| topic | Cu(II) complex supramolecular architecture water vapor adsorption |
| url | https://www.mdpi.com/2073-4352/7/10/297 |
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