Assessment of Operational Degradation of Pipeline Steels

This paper summarizes a series of the authors’ research in the field of assessing the operational degradation of oil and gas transit pipeline steels. Both mechanical and electrochemical properties of steels are deteriorated after operation, as is their resistance to environmentally-assisted cracking...

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Main Authors: Hryhoriy Nykyforchyn, Olha Zvirko, Ihor Dzioba, Halyna Krechkovska, Myroslava Hredil, Oleksandr Tsyrulnyk, Oleksandra Student, Sebastian Lipiec, Robert Pala
Format: Article
Language:English
Published: MDPI AG 2021-06-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/14/12/3247
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author Hryhoriy Nykyforchyn
Olha Zvirko
Ihor Dzioba
Halyna Krechkovska
Myroslava Hredil
Oleksandr Tsyrulnyk
Oleksandra Student
Sebastian Lipiec
Robert Pala
author_facet Hryhoriy Nykyforchyn
Olha Zvirko
Ihor Dzioba
Halyna Krechkovska
Myroslava Hredil
Oleksandr Tsyrulnyk
Oleksandra Student
Sebastian Lipiec
Robert Pala
author_sort Hryhoriy Nykyforchyn
collection DOAJ
description This paper summarizes a series of the authors’ research in the field of assessing the operational degradation of oil and gas transit pipeline steels. Both mechanical and electrochemical properties of steels are deteriorated after operation, as is their resistance to environmentally-assisted cracking. The characteristics of resistance to brittle fracture and stress corrosion cracking decrease most intensively, which is associated with a development of in-bulk dissipated microdamages of the material. The most sensitive indicators of changes in the material’s state caused by degradation are impact toughness and fracture toughness by the J-integral method. The degradation degree of pipeline steels can also be evaluated nondestructively based on in-service changes in their polarization resistance and potential of the fracture surface. Attention is drawn to hydrogenation of a pipe wall from inside as a result of the electrochemical interaction of pipe metal with condensed moisture, which facilitates operational degradation of steel due to the combined action of operating stresses and hydrogen. The development of microdamages along steel texture was evidenced metallographically as a trend to the selective etching of boundaries between adjacent bands of ferrite and pearlite and fractographically by revealing brittle fracture elements on the fracture surfaces, namely delamination and cleavage, indicating the sites of cohesion weakening between ferrite and pearlite bands. The state of the X52 steel in its initial state and after use for 30 years was assessed based on the numerical simulation method.
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spelling doaj.art-7e28ea0ba749473087ffe481ce6bf0da2023-11-21T23:50:51ZengMDPI AGMaterials1996-19442021-06-011412324710.3390/ma14123247Assessment of Operational Degradation of Pipeline SteelsHryhoriy Nykyforchyn0Olha Zvirko1Ihor Dzioba2Halyna Krechkovska3Myroslava Hredil4Oleksandr Tsyrulnyk5Oleksandra Student6Sebastian Lipiec7Robert Pala8Department of Diagnostics of Materials Corrosion-Hydrogen Degradation, Karpenko Physico-Mechanical Institute of the NAS of Ukraine, 5 Naukova St., 79060 Lviv, UkraineDepartment of Diagnostics of Materials Corrosion-Hydrogen Degradation, Karpenko Physico-Mechanical Institute of the NAS of Ukraine, 5 Naukova St., 79060 Lviv, UkraineDepartment of Machine Design, Faculty of Mechatronics and Mechanical Engineering, Kielce University of Technology, Av. 1000-an. of Polish State, 7, 25-314 Kielce, PolandDepartment of Diagnostics of Materials Corrosion-Hydrogen Degradation, Karpenko Physico-Mechanical Institute of the NAS of Ukraine, 5 Naukova St., 79060 Lviv, UkraineDepartment of Diagnostics of Materials Corrosion-Hydrogen Degradation, Karpenko Physico-Mechanical Institute of the NAS of Ukraine, 5 Naukova St., 79060 Lviv, UkraineDepartment of Diagnostics of Materials Corrosion-Hydrogen Degradation, Karpenko Physico-Mechanical Institute of the NAS of Ukraine, 5 Naukova St., 79060 Lviv, UkraineDepartment of Diagnostics of Materials Corrosion-Hydrogen Degradation, Karpenko Physico-Mechanical Institute of the NAS of Ukraine, 5 Naukova St., 79060 Lviv, UkraineDepartment of Machine Design, Faculty of Mechatronics and Mechanical Engineering, Kielce University of Technology, Av. 1000-an. of Polish State, 7, 25-314 Kielce, PolandDepartment of Machine Design, Faculty of Mechatronics and Mechanical Engineering, Kielce University of Technology, Av. 1000-an. of Polish State, 7, 25-314 Kielce, PolandThis paper summarizes a series of the authors’ research in the field of assessing the operational degradation of oil and gas transit pipeline steels. Both mechanical and electrochemical properties of steels are deteriorated after operation, as is their resistance to environmentally-assisted cracking. The characteristics of resistance to brittle fracture and stress corrosion cracking decrease most intensively, which is associated with a development of in-bulk dissipated microdamages of the material. The most sensitive indicators of changes in the material’s state caused by degradation are impact toughness and fracture toughness by the J-integral method. The degradation degree of pipeline steels can also be evaluated nondestructively based on in-service changes in their polarization resistance and potential of the fracture surface. Attention is drawn to hydrogenation of a pipe wall from inside as a result of the electrochemical interaction of pipe metal with condensed moisture, which facilitates operational degradation of steel due to the combined action of operating stresses and hydrogen. The development of microdamages along steel texture was evidenced metallographically as a trend to the selective etching of boundaries between adjacent bands of ferrite and pearlite and fractographically by revealing brittle fracture elements on the fracture surfaces, namely delamination and cleavage, indicating the sites of cohesion weakening between ferrite and pearlite bands. The state of the X52 steel in its initial state and after use for 30 years was assessed based on the numerical simulation method.https://www.mdpi.com/1996-1944/14/12/3247transit pipeline steeloperational degradationhydrogenmechanical propertieselectrochemical propertiesmicrostructure
spellingShingle Hryhoriy Nykyforchyn
Olha Zvirko
Ihor Dzioba
Halyna Krechkovska
Myroslava Hredil
Oleksandr Tsyrulnyk
Oleksandra Student
Sebastian Lipiec
Robert Pala
Assessment of Operational Degradation of Pipeline Steels
Materials
transit pipeline steel
operational degradation
hydrogen
mechanical properties
electrochemical properties
microstructure
title Assessment of Operational Degradation of Pipeline Steels
title_full Assessment of Operational Degradation of Pipeline Steels
title_fullStr Assessment of Operational Degradation of Pipeline Steels
title_full_unstemmed Assessment of Operational Degradation of Pipeline Steels
title_short Assessment of Operational Degradation of Pipeline Steels
title_sort assessment of operational degradation of pipeline steels
topic transit pipeline steel
operational degradation
hydrogen
mechanical properties
electrochemical properties
microstructure
url https://www.mdpi.com/1996-1944/14/12/3247
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