A novel proton transfer compound (a new molybdate salt) and its X-ray structure
A novel proton transfer compound (OHRNH<sub>3</sub>)<sub>2</sub><sup>2+</sup>(MoO<sub>4</sub>)<sup>2-</sup> (R = 2-methyl-1-propyl), derived from 2-amino-2-methyl-1-propanol and MoO<sub>2</sub>(acac)<sub>2</sub>, syn...
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| Format: | Article |
| Language: | English |
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Chemical Society of Ethiopia
2013-04-01
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| Series: | Bulletin of the Chemical Society of Ethiopia |
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| Online Access: | http://www.ajol.info/index.php/bcse/article/view/84077 |
| _version_ | 1811343283408863232 |
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| author | M. Ghazizadeh I. Sheikhshoaie |
| author_facet | M. Ghazizadeh I. Sheikhshoaie |
| author_sort | M. Ghazizadeh |
| collection | DOAJ |
| description | A novel proton transfer compound (OHRNH<sub>3</sub>)<sub>2</sub><sup>2+</sup>(MoO<sub>4</sub>)<sup>2-</sup> (R = 2-methyl-1-propyl), derived from 2-amino-2-methyl-1-propanol and MoO<sub>2</sub>(acac)<sub>2</sub>, synthesized and characterized by <sup>1</sup>H NMR, X-ray diffraction analysis, UV-Vis and FT-IR spectroscopy. The single crystal X-ray diffraction analysis revealed that intra- and intermolecular proton transfer from (MoO<sub>4</sub>H<sub>2</sub>) to (OHRNH<sub>2</sub>) results in the formation of a new molybdate salt that its fragments are connected through H-bonding and ion-pairing as shown in the X-ray crystal structure. This salt crystallizes in the space group <i>P</i>21/<i>n</i> P_1 of the monoclinic system, with four molecules per unit cell. The unit cell parameters are a = 13.6091(11) Å, b = 6.1049(5) Å, c = 17.0840(13) Å and β = 97.745(4)°.DOI: http://dx.doi.org/10.4314/bcse.v27i1.7 |
| first_indexed | 2024-04-13T19:25:42Z |
| format | Article |
| id | doaj.art-7e2cfb5e72804da79cb01193f766c634 |
| institution | Directory Open Access Journal |
| issn | 1011-3924 1726-801X |
| language | English |
| last_indexed | 2024-04-13T19:25:42Z |
| publishDate | 2013-04-01 |
| publisher | Chemical Society of Ethiopia |
| record_format | Article |
| series | Bulletin of the Chemical Society of Ethiopia |
| spelling | doaj.art-7e2cfb5e72804da79cb01193f766c6342022-12-22T02:33:22ZengChemical Society of EthiopiaBulletin of the Chemical Society of Ethiopia1011-39241726-801X2013-04-012716976A novel proton transfer compound (a new molybdate salt) and its X-ray structureM. GhazizadehI. SheikhshoaieA novel proton transfer compound (OHRNH<sub>3</sub>)<sub>2</sub><sup>2+</sup>(MoO<sub>4</sub>)<sup>2-</sup> (R = 2-methyl-1-propyl), derived from 2-amino-2-methyl-1-propanol and MoO<sub>2</sub>(acac)<sub>2</sub>, synthesized and characterized by <sup>1</sup>H NMR, X-ray diffraction analysis, UV-Vis and FT-IR spectroscopy. The single crystal X-ray diffraction analysis revealed that intra- and intermolecular proton transfer from (MoO<sub>4</sub>H<sub>2</sub>) to (OHRNH<sub>2</sub>) results in the formation of a new molybdate salt that its fragments are connected through H-bonding and ion-pairing as shown in the X-ray crystal structure. This salt crystallizes in the space group <i>P</i>21/<i>n</i> P_1 of the monoclinic system, with four molecules per unit cell. The unit cell parameters are a = 13.6091(11) Å, b = 6.1049(5) Å, c = 17.0840(13) Å and β = 97.745(4)°.DOI: http://dx.doi.org/10.4314/bcse.v27i1.7http://www.ajol.info/index.php/bcse/article/view/84077Proton transferMolybdate saltX-ray structureMoO<sub>2</sub>(acac)<sub>2</sub>2-Amino-2-methyl-1-propanol |
| spellingShingle | M. Ghazizadeh I. Sheikhshoaie A novel proton transfer compound (a new molybdate salt) and its X-ray structure Bulletin of the Chemical Society of Ethiopia Proton transfer Molybdate salt X-ray structure MoO<sub>2</sub>(acac)<sub>2</sub> 2-Amino-2-methyl-1-propanol |
| title | A novel proton transfer compound (a new molybdate salt) and its X-ray structure |
| title_full | A novel proton transfer compound (a new molybdate salt) and its X-ray structure |
| title_fullStr | A novel proton transfer compound (a new molybdate salt) and its X-ray structure |
| title_full_unstemmed | A novel proton transfer compound (a new molybdate salt) and its X-ray structure |
| title_short | A novel proton transfer compound (a new molybdate salt) and its X-ray structure |
| title_sort | novel proton transfer compound a new molybdate salt and its x ray structure |
| topic | Proton transfer Molybdate salt X-ray structure MoO<sub>2</sub>(acac)<sub>2</sub> 2-Amino-2-methyl-1-propanol |
| url | http://www.ajol.info/index.php/bcse/article/view/84077 |
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