Bis(3-hydroxyphenylacetato-κ2O,O′)bis(1H-imidazole-κN3)nickel(II)
In the title mononuclear complex, [Ni(C8H7O3)2(C3H4N2)2], the NiII atom, lying on a twofold rotation axis, is coordinated by four carboxylate O atoms from two bidentate 3-hydroxyphenylacetato ligands and two N atoms from two imidazole molecules in a distorted octahedral geometry. A three-dimensional...
| Format: | Article |
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| Language: | English |
| Published: |
International Union of Crystallography
2009-03-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809005960 |
| _version_ | 1828854764553633792 |
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| collection | DOAJ |
| description | In the title mononuclear complex, [Ni(C8H7O3)2(C3H4N2)2], the NiII atom, lying on a twofold rotation axis, is coordinated by four carboxylate O atoms from two bidentate 3-hydroxyphenylacetato ligands and two N atoms from two imidazole molecules in a distorted octahedral geometry. A three-dimensional network is formed via intermolecular O—H...O and N—H...O hydrogen bonds and π–π stacking interactions between the imidazole and benzene rings of neighboring molecules [centroid–centroid distance = 3.856 (2) Å]. |
| first_indexed | 2024-12-13T00:41:16Z |
| format | Article |
| id | doaj.art-7e3088a67b9e4ab5a62ca8301b561d21 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-13T00:41:16Z |
| publishDate | 2009-03-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-7e3088a67b9e4ab5a62ca8301b561d212022-12-22T00:05:07ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-03-01653m330m33010.1107/S1600536809005960Bis(3-hydroxyphenylacetato-κ2O,O′)bis(1H-imidazole-κN3)nickel(II)In the title mononuclear complex, [Ni(C8H7O3)2(C3H4N2)2], the NiII atom, lying on a twofold rotation axis, is coordinated by four carboxylate O atoms from two bidentate 3-hydroxyphenylacetato ligands and two N atoms from two imidazole molecules in a distorted octahedral geometry. A three-dimensional network is formed via intermolecular O—H...O and N—H...O hydrogen bonds and π–π stacking interactions between the imidazole and benzene rings of neighboring molecules [centroid–centroid distance = 3.856 (2) Å].http://scripts.iucr.org/cgi-bin/paper?S1600536809005960 |
| spellingShingle | Bis(3-hydroxyphenylacetato-κ2O,O′)bis(1H-imidazole-κN3)nickel(II) Acta Crystallographica Section E |
| title | Bis(3-hydroxyphenylacetato-κ2O,O′)bis(1H-imidazole-κN3)nickel(II) |
| title_full | Bis(3-hydroxyphenylacetato-κ2O,O′)bis(1H-imidazole-κN3)nickel(II) |
| title_fullStr | Bis(3-hydroxyphenylacetato-κ2O,O′)bis(1H-imidazole-κN3)nickel(II) |
| title_full_unstemmed | Bis(3-hydroxyphenylacetato-κ2O,O′)bis(1H-imidazole-κN3)nickel(II) |
| title_short | Bis(3-hydroxyphenylacetato-κ2O,O′)bis(1H-imidazole-κN3)nickel(II) |
| title_sort | bis 3 hydroxyphenylacetato amp 954 2o o amp 8242 bis 1h imidazole amp 954 n3 nickel ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536809005960 |