Low-temperature redetermination of tribenzylchloridotin(IV)
Compared to the previous studies [Ng (1997). Acta Cryst. C53, 56–58; Yin et al. (2005). Huaxue Shiji, 27, 295–296], the redetermined structure of the title compound, [Sn(C7H7)3Cl], exhibits a doubled c unit-cell parameter. There are two molecules in the asymmetric unit, with both...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2009-02-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S160053680900289X |
| Summary: | Compared to the previous studies [Ng (1997). Acta Cryst. C53, 56–58; Yin et al. (2005). Huaxue Shiji, 27, 295–296], the redetermined structure of the title compound, [Sn(C7H7)3Cl], exhibits a doubled c unit-cell parameter. There are two molecules in the asymmetric unit, with both Sn and both Cl atoms having 3 site symmetry. The Sn atoms have distorted SnClC3 tetrahedral geometries and the molecules interact by way of short Sn...Cl bridges [Sn...Cl = 3.418 (2) and 3.475 (2) Å], thereby forming chains propagating in c. |
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| ISSN: | 1600-5368 |