catena-Poly[[bis(dimethyl sulfoxide-κO)cerium(III)]tris(μ2-3,5-dinitrobenzoato-κ2O:O′)]
The polymeric title compound, [Ce(C7H3N2O6)3(C2H6OS)2]n, exists as a linear chain along [111] as the three dinitrobenzoate anions each engages in bridging adjacent dimethyl sulfoxide (DMSO) coordinated CeIII atoms. The metal atoms are surrounded by eight O atoms in a square-antiprismatic environment...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2011-06-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811015947 |
| _version_ | 1819289070131478528 |
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| author | Fu-Lin Zhou Zhi-Hua Du Seik Weng Ng |
| author_facet | Fu-Lin Zhou Zhi-Hua Du Seik Weng Ng |
| author_sort | Fu-Lin Zhou |
| collection | DOAJ |
| description | The polymeric title compound, [Ce(C7H3N2O6)3(C2H6OS)2]n, exists as a linear chain along [111] as the three dinitrobenzoate anions each engages in bridging adjacent dimethyl sulfoxide (DMSO) coordinated CeIII atoms. The metal atoms are surrounded by eight O atoms in a square-antiprismatic environment. There are two independent formula units in the asymmetric unit. The S atoms of two of the four DMSO molecules are disordered in a 0.926 (3):0.074 (3) ratio. |
| first_indexed | 2024-12-24T03:01:00Z |
| format | Article |
| id | doaj.art-7e34085e2bb04fbb9e1ed3904e0232a4 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T03:01:00Z |
| publishDate | 2011-06-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-7e34085e2bb04fbb9e1ed3904e0232a42022-12-21T17:18:13ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-06-01676m673m67310.1107/S1600536811015947catena-Poly[[bis(dimethyl sulfoxide-κO)cerium(III)]tris(μ2-3,5-dinitrobenzoato-κ2O:O′)]Fu-Lin ZhouZhi-Hua DuSeik Weng NgThe polymeric title compound, [Ce(C7H3N2O6)3(C2H6OS)2]n, exists as a linear chain along [111] as the three dinitrobenzoate anions each engages in bridging adjacent dimethyl sulfoxide (DMSO) coordinated CeIII atoms. The metal atoms are surrounded by eight O atoms in a square-antiprismatic environment. There are two independent formula units in the asymmetric unit. The S atoms of two of the four DMSO molecules are disordered in a 0.926 (3):0.074 (3) ratio.http://scripts.iucr.org/cgi-bin/paper?S1600536811015947 |
| spellingShingle | Fu-Lin Zhou Zhi-Hua Du Seik Weng Ng catena-Poly[[bis(dimethyl sulfoxide-κO)cerium(III)]tris(μ2-3,5-dinitrobenzoato-κ2O:O′)] Acta Crystallographica Section E |
| title | catena-Poly[[bis(dimethyl sulfoxide-κO)cerium(III)]tris(μ2-3,5-dinitrobenzoato-κ2O:O′)] |
| title_full | catena-Poly[[bis(dimethyl sulfoxide-κO)cerium(III)]tris(μ2-3,5-dinitrobenzoato-κ2O:O′)] |
| title_fullStr | catena-Poly[[bis(dimethyl sulfoxide-κO)cerium(III)]tris(μ2-3,5-dinitrobenzoato-κ2O:O′)] |
| title_full_unstemmed | catena-Poly[[bis(dimethyl sulfoxide-κO)cerium(III)]tris(μ2-3,5-dinitrobenzoato-κ2O:O′)] |
| title_short | catena-Poly[[bis(dimethyl sulfoxide-κO)cerium(III)]tris(μ2-3,5-dinitrobenzoato-κ2O:O′)] |
| title_sort | catena poly bis dimethyl sulfoxide amp 954 o cerium iii tris amp 956 2 3 5 dinitrobenzoato amp 954 2o o amp 8242 |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536811015947 |
| work_keys_str_mv | AT fulinzhou catenapolybisdimethylsulfoxideamp954oceriumiiitrisamp956235dinitrobenzoatoamp9542ooamp8242 AT zhihuadu catenapolybisdimethylsulfoxideamp954oceriumiiitrisamp956235dinitrobenzoatoamp9542ooamp8242 AT seikwengng catenapolybisdimethylsulfoxideamp954oceriumiiitrisamp956235dinitrobenzoatoamp9542ooamp8242 |