6,6'-(1E,1'E)-((1R,2R)-1,2-Diphenylethane-1,2-diyl)bis(azan-1-yl-1-ylidene)bis(methan-1-yl-1-ylidene)bis(2-tert-butyl-4-((trimethylsilyl)ethynyl)phenol)
Functionalizable salen derivative, 6,6'-(1E,1'E)-((1R,2R)-1,2-diphenylethane-1,2-diyl)bis(azan-1-yl-1-ylidene)bis(methan-1-yl-1-ylidene)bis(2-tert-butyl-4-((trimethylsilyl) ethyn-yl)phenol) (3), was synthesized by condensation between (1R,2R)-1,2-diphenylethane-1,2-diamine (2) and...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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MDPI AG
2013-03-01
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| Series: | Molbank |
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| Online Access: | http://www.mdpi.com/1422-8599/2013/1/M795 |
| _version_ | 1819136037600886784 |
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| author | David Díaz Díaz M. G. Finn Thimo Huber Lennart Niehues Carlos Cativiela |
| author_facet | David Díaz Díaz M. G. Finn Thimo Huber Lennart Niehues Carlos Cativiela |
| author_sort | David Díaz Díaz |
| collection | DOAJ |
| description | Functionalizable salen derivative, 6,6'-(1E,1'E)-((1R,2R)-1,2-diphenylethane-1,2-diyl)bis(azan-1-yl-1-ylidene)bis(methan-1-yl-1-ylidene)bis(2-tert-butyl-4-((trimethylsilyl) ethyn-yl)phenol) (3), was synthesized by condensation between (1R,2R)-1,2-diphenylethane-1,2-diamine (2) and 3-tert-butyl-2-hydroxy-5-((trimethylsilyl)ethynyl) benzaldehyde (1) under refluxing conditions. The title compound was characterized by 1H-NMR, 13C-NMR, FT-IR, high-resolution mass spectrometry, optical rotation and melting point determination. |
| first_indexed | 2024-12-22T10:28:37Z |
| format | Article |
| id | doaj.art-7e5ff9436f854a448868e02ee87c7d56 |
| institution | Directory Open Access Journal |
| issn | 1422-8599 |
| language | English |
| last_indexed | 2024-12-22T10:28:37Z |
| publishDate | 2013-03-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molbank |
| spelling | doaj.art-7e5ff9436f854a448868e02ee87c7d562022-12-21T18:29:24ZengMDPI AGMolbank1422-85992013-03-0120131M79510.3390/M7956,6'-(1E,1'E)-((1R,2R)-1,2-Diphenylethane-1,2-diyl)bis(azan-1-yl-1-ylidene)bis(methan-1-yl-1-ylidene)bis(2-tert-butyl-4-((trimethylsilyl)ethynyl)phenol)David Díaz DíazM. G. FinnThimo HuberLennart NiehuesCarlos CativielaFunctionalizable salen derivative, 6,6'-(1E,1'E)-((1R,2R)-1,2-diphenylethane-1,2-diyl)bis(azan-1-yl-1-ylidene)bis(methan-1-yl-1-ylidene)bis(2-tert-butyl-4-((trimethylsilyl) ethyn-yl)phenol) (3), was synthesized by condensation between (1R,2R)-1,2-diphenylethane-1,2-diamine (2) and 3-tert-butyl-2-hydroxy-5-((trimethylsilyl)ethynyl) benzaldehyde (1) under refluxing conditions. The title compound was characterized by 1H-NMR, 13C-NMR, FT-IR, high-resolution mass spectrometry, optical rotation and melting point determination.http://www.mdpi.com/1422-8599/2013/1/M795salen ligandschiral 1,2-diaminesalkynesnucleophilic addition |
| spellingShingle | David Díaz Díaz M. G. Finn Thimo Huber Lennart Niehues Carlos Cativiela 6,6'-(1E,1'E)-((1R,2R)-1,2-Diphenylethane-1,2-diyl)bis(azan-1-yl-1-ylidene)bis(methan-1-yl-1-ylidene)bis(2-tert-butyl-4-((trimethylsilyl)ethynyl)phenol) Molbank salen ligands chiral 1,2-diamines alkynes nucleophilic addition |
| title | 6,6'-(1E,1'E)-((1R,2R)-1,2-Diphenylethane-1,2-diyl)bis(azan-1-yl-1-ylidene)bis(methan-1-yl-1-ylidene)bis(2-tert-butyl-4-((trimethylsilyl)ethynyl)phenol) |
| title_full | 6,6'-(1E,1'E)-((1R,2R)-1,2-Diphenylethane-1,2-diyl)bis(azan-1-yl-1-ylidene)bis(methan-1-yl-1-ylidene)bis(2-tert-butyl-4-((trimethylsilyl)ethynyl)phenol) |
| title_fullStr | 6,6'-(1E,1'E)-((1R,2R)-1,2-Diphenylethane-1,2-diyl)bis(azan-1-yl-1-ylidene)bis(methan-1-yl-1-ylidene)bis(2-tert-butyl-4-((trimethylsilyl)ethynyl)phenol) |
| title_full_unstemmed | 6,6'-(1E,1'E)-((1R,2R)-1,2-Diphenylethane-1,2-diyl)bis(azan-1-yl-1-ylidene)bis(methan-1-yl-1-ylidene)bis(2-tert-butyl-4-((trimethylsilyl)ethynyl)phenol) |
| title_short | 6,6'-(1E,1'E)-((1R,2R)-1,2-Diphenylethane-1,2-diyl)bis(azan-1-yl-1-ylidene)bis(methan-1-yl-1-ylidene)bis(2-tert-butyl-4-((trimethylsilyl)ethynyl)phenol) |
| title_sort | 6 6 039 1e 1 039 e 1r 2r 1 2 diphenylethane 1 2 diyl bis azan 1 yl 1 ylidene bis methan 1 yl 1 ylidene bis 2 tert butyl 4 trimethylsilyl ethynyl phenol |
| topic | salen ligands chiral 1,2-diamines alkynes nucleophilic addition |
| url | http://www.mdpi.com/1422-8599/2013/1/M795 |
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