RbZnFe(PO4)2: synthesis and crystal structure

A new iron phosphate, rubidium zinc iron(III) phosphate, RbZnFe(PO4)2, has been synthesized as single crystals by the flux method. This compound is isostructural to the previously reported KCoAl(PO4)2 [Chen et al. (1997). Acta Cryst. C53,1754–1756]. Its structure consists of a three-dimensional fram...

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Bibliographic Details
Main Authors: Abdessalem Badri, Mongi Ben Amara
Format: Article
Language:English
Published: International Union of Crystallography 2016-08-01
Series:Acta Crystallographica Section E: Crystallographic Communications
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Online Access:http://scripts.iucr.org/cgi-bin/paper?S205698901601046X
Description
Summary:A new iron phosphate, rubidium zinc iron(III) phosphate, RbZnFe(PO4)2, has been synthesized as single crystals by the flux method. This compound is isostructural to the previously reported KCoAl(PO4)2 [Chen et al. (1997). Acta Cryst. C53,1754–1756]. Its structure consists of a three-dimensional framework built up from corner-sharing PO4 and (Zn,Fe)O4 tetrahedra. This mode of linkage forms channels parallel to the [100], [010] and [001] directions in which the Rb+ ions are located.
ISSN:2056-9890