Cyclic voltammetry study of Ce(IV)/Ce(III) redox couple and Ce(IV)-F complex in sulfuric acid medium
In this paper the electrochemical behaviors of Ce(IV)/Ce(III) redox couple and Ce(IV) - F complex in sulfuric acid medium were studied by cyclic voltammetry using a platinum electrode. Both of the Ce(IV)/Ce(III) couple in Ce(IV) solution and Ce(IV) - F complex is a quasi-reversible process, and give...
| Main Authors: | , , , , , |
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| Format: | Article |
| Language: | English |
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Croatian Metallurgical Society
2016-10-01
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| Series: | Metalurgija |
| Subjects: | |
| Online Access: | http://hrcak.srce.hr/file/231963 |
| _version_ | 1818212285670227968 |
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| author | J. G. He Y. Li X. X. Xue H. Q. Ru X. W. Huang H. Yang |
| author_facet | J. G. He Y. Li X. X. Xue H. Q. Ru X. W. Huang H. Yang |
| author_sort | J. G. He |
| collection | DOAJ |
| description | In this paper the electrochemical behaviors of Ce(IV)/Ce(III) redox couple and Ce(IV) - F complex in sulfuric acid medium were studied by cyclic voltammetry using a platinum electrode. Both of the Ce(IV)/Ce(III) couple in Ce(IV) solution and Ce(IV) - F complex is a quasi-reversible process, and gives a linear correlation between the peak potentials and square root of scan rates, showing that the kinetics of the overall process is diffusion controlled. The complexation of cerium(IV) and fluoride is favorable for the oxidation of Ce(III). The kinetic parameters such as diffusion coefficients, anodic transfer coefficients and rate constants were studied. |
| first_indexed | 2024-12-12T05:45:58Z |
| format | Article |
| id | doaj.art-7e706bbbaf6d411cbc015da24d243dce |
| institution | Directory Open Access Journal |
| issn | 0543-5846 1334-2576 |
| language | English |
| last_indexed | 2024-12-12T05:45:58Z |
| publishDate | 2016-10-01 |
| publisher | Croatian Metallurgical Society |
| record_format | Article |
| series | Metalurgija |
| spelling | doaj.art-7e706bbbaf6d411cbc015da24d243dce2022-12-22T00:35:48ZengCroatian Metallurgical SocietyMetalurgija0543-58461334-25762016-10-01554687690Cyclic voltammetry study of Ce(IV)/Ce(III) redox couple and Ce(IV)-F complex in sulfuric acid mediumJ. G. HeY. LiX. X. XueH. Q. RuX. W. HuangH. YangIn this paper the electrochemical behaviors of Ce(IV)/Ce(III) redox couple and Ce(IV) - F complex in sulfuric acid medium were studied by cyclic voltammetry using a platinum electrode. Both of the Ce(IV)/Ce(III) couple in Ce(IV) solution and Ce(IV) - F complex is a quasi-reversible process, and gives a linear correlation between the peak potentials and square root of scan rates, showing that the kinetics of the overall process is diffusion controlled. The complexation of cerium(IV) and fluoride is favorable for the oxidation of Ce(III). The kinetic parameters such as diffusion coefficients, anodic transfer coefficients and rate constants were studied.http://hrcak.srce.hr/file/231963cyclic voltammetryCe(IV)/Ce(III) coupleCeF<sub>2</sub><sup>2+</sup> complex ionoxidation |
| spellingShingle | J. G. He Y. Li X. X. Xue H. Q. Ru X. W. Huang H. Yang Cyclic voltammetry study of Ce(IV)/Ce(III) redox couple and Ce(IV)-F complex in sulfuric acid medium Metalurgija cyclic voltammetry Ce(IV)/Ce(III) couple CeF<sub>2</sub><sup>2+</sup> complex ion oxidation |
| title | Cyclic voltammetry study of Ce(IV)/Ce(III) redox couple and Ce(IV)-F complex in sulfuric acid medium |
| title_full | Cyclic voltammetry study of Ce(IV)/Ce(III) redox couple and Ce(IV)-F complex in sulfuric acid medium |
| title_fullStr | Cyclic voltammetry study of Ce(IV)/Ce(III) redox couple and Ce(IV)-F complex in sulfuric acid medium |
| title_full_unstemmed | Cyclic voltammetry study of Ce(IV)/Ce(III) redox couple and Ce(IV)-F complex in sulfuric acid medium |
| title_short | Cyclic voltammetry study of Ce(IV)/Ce(III) redox couple and Ce(IV)-F complex in sulfuric acid medium |
| title_sort | cyclic voltammetry study of ce iv ce iii redox couple and ce iv f complex in sulfuric acid medium |
| topic | cyclic voltammetry Ce(IV)/Ce(III) couple CeF<sub>2</sub><sup>2+</sup> complex ion oxidation |
| url | http://hrcak.srce.hr/file/231963 |
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