Analyzing and Modeling of Water Transport Phenomena in Open-Cathode Polymer Electrolyte Membrane Fuel Cell

Water management is one issue that must be surpassed to ensure high membrane proton conductivity and adequate reactant transport in the membrane-electrode assembly (MEA) simultaneously. A well-designed water management system is based on a comprehensive understanding of water transport in the inner...

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Main Authors: Wei-Wei Yuan, Kai Ou, Seunghun Jung, Young-Bae Kim
Format: Article
Language:English
Published: MDPI AG 2021-06-01
Series:Applied Sciences
Subjects:
Online Access:https://www.mdpi.com/2076-3417/11/13/5964
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author Wei-Wei Yuan
Kai Ou
Seunghun Jung
Young-Bae Kim
author_facet Wei-Wei Yuan
Kai Ou
Seunghun Jung
Young-Bae Kim
author_sort Wei-Wei Yuan
collection DOAJ
description Water management is one issue that must be surpassed to ensure high membrane proton conductivity and adequate reactant transport in the membrane-electrode assembly (MEA) simultaneously. A well-designed water management system is based on a comprehensive understanding of water transport in the inner part of the polymer electrolyte membrane (PEM) fuel cell. In this work, the water transport phenomena in the MEA PEM fuel cell are analyzed by using a mathematical model. The transport of diluted species interface is used to model the transport of water in the ionomer phase in the catalytic layer and the membrane domains. The molecular flux of water is defined using Nernst–Planck equations, including migration and Fickian diffusion using parameters obtained experimentally for diffusivity and mobility based on water drag for a fully humidified membrane. The proposed model 1D model includes anode gas channel, cathode gas channel, anode gas diffusion layer (GDL), cathode GDL, anode catalyst layer, cathode catalyst layer, and proton exchange membrane. Water activity, ionomer conductivity, and output voltage are predicted by changing the humidity on the anode side of the fuel cell.
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spelling doaj.art-7e71a01f0a224dfba7b5bd73aa7bdd1a2023-12-03T13:09:46ZengMDPI AGApplied Sciences2076-34172021-06-011113596410.3390/app11135964Analyzing and Modeling of Water Transport Phenomena in Open-Cathode Polymer Electrolyte Membrane Fuel CellWei-Wei Yuan0Kai Ou1Seunghun Jung2Young-Bae Kim3Department of Mechanical Engineering, Chonnam National University, Gwangju 61186, KoreaSchool of Mechanical Engineering, Fuzhou University, Fuzhou 350108, ChinaDepartment of Mechanical Engineering, Chonnam National University, Gwangju 61186, KoreaDepartment of Mechanical Engineering, Chonnam National University, Gwangju 61186, KoreaWater management is one issue that must be surpassed to ensure high membrane proton conductivity and adequate reactant transport in the membrane-electrode assembly (MEA) simultaneously. A well-designed water management system is based on a comprehensive understanding of water transport in the inner part of the polymer electrolyte membrane (PEM) fuel cell. In this work, the water transport phenomena in the MEA PEM fuel cell are analyzed by using a mathematical model. The transport of diluted species interface is used to model the transport of water in the ionomer phase in the catalytic layer and the membrane domains. The molecular flux of water is defined using Nernst–Planck equations, including migration and Fickian diffusion using parameters obtained experimentally for diffusivity and mobility based on water drag for a fully humidified membrane. The proposed model 1D model includes anode gas channel, cathode gas channel, anode gas diffusion layer (GDL), cathode GDL, anode catalyst layer, cathode catalyst layer, and proton exchange membrane. Water activity, ionomer conductivity, and output voltage are predicted by changing the humidity on the anode side of the fuel cell.https://www.mdpi.com/2076-3417/11/13/5964open cathode PEM fuel cell1D modelwater managementwater transportPDEtwo-phase model
spellingShingle Wei-Wei Yuan
Kai Ou
Seunghun Jung
Young-Bae Kim
Analyzing and Modeling of Water Transport Phenomena in Open-Cathode Polymer Electrolyte Membrane Fuel Cell
Applied Sciences
open cathode PEM fuel cell
1D model
water management
water transport
PDE
two-phase model
title Analyzing and Modeling of Water Transport Phenomena in Open-Cathode Polymer Electrolyte Membrane Fuel Cell
title_full Analyzing and Modeling of Water Transport Phenomena in Open-Cathode Polymer Electrolyte Membrane Fuel Cell
title_fullStr Analyzing and Modeling of Water Transport Phenomena in Open-Cathode Polymer Electrolyte Membrane Fuel Cell
title_full_unstemmed Analyzing and Modeling of Water Transport Phenomena in Open-Cathode Polymer Electrolyte Membrane Fuel Cell
title_short Analyzing and Modeling of Water Transport Phenomena in Open-Cathode Polymer Electrolyte Membrane Fuel Cell
title_sort analyzing and modeling of water transport phenomena in open cathode polymer electrolyte membrane fuel cell
topic open cathode PEM fuel cell
1D model
water management
water transport
PDE
two-phase model
url https://www.mdpi.com/2076-3417/11/13/5964
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