Hydrothermal Carbonization of Chemical and Biological Pulp Mill Sludges

A modern pulp mill generates a variety of different by-products and waste streams, some of these can be recycled, refined, sold, or used on-site for energy production. However, some, such as chemical and biological sludges produced in wastewater treatment cannot be reused or disposed of easily, main...

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Main Authors: Clara Lisseth Mendoza Martinez, Ekaterina Sermyagina, Esa Vakkilainen
Format: Article
Language:English
Published: MDPI AG 2021-09-01
Series:Energies
Subjects:
Online Access:https://www.mdpi.com/1996-1073/14/18/5693
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author Clara Lisseth Mendoza Martinez
Ekaterina Sermyagina
Esa Vakkilainen
author_facet Clara Lisseth Mendoza Martinez
Ekaterina Sermyagina
Esa Vakkilainen
author_sort Clara Lisseth Mendoza Martinez
collection DOAJ
description A modern pulp mill generates a variety of different by-products and waste streams, some of these can be recycled, refined, sold, or used on-site for energy production. However, some, such as chemical and biological sludges produced in wastewater treatment cannot be reused or disposed of easily, mainly due to their high moisture content and poor drying characteristics. Tightening legislation regarding waste disposal as well as the growing need to increase the process efficiencies of pulp mills act as driving forces to find environmentally friendly and energy-efficient techniques for pulp mill sludge treatment. This study summarizes the current methods for pulp mill sludge handling and evaluates the potential of hydrothermal carbonization (HTC), a conversion process through which wet organic substrates can be transformed into a carbonaceous material (hydrochar). Depending on the process parameters, the material’s structure is modified, enabling hydrochar use in energy, soil conditioning and adsorption applications. The sludges were hydrothermally carbonized at 180, 200, 220 and 240 °C for 3 h. The hydrochar and liquid products’ main properties were analyzed. Their potential applications were also evaluated. The effective treatment of sludges from the pulp industry with HTC could transform energy-demanding waste into a value-added source of materials.
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spelling doaj.art-7e7458e89b974c3b9606d21663fbd7df2023-11-22T12:51:32ZengMDPI AGEnergies1996-10732021-09-011418569310.3390/en14185693Hydrothermal Carbonization of Chemical and Biological Pulp Mill SludgesClara Lisseth Mendoza Martinez0Ekaterina Sermyagina1Esa Vakkilainen2School of Energy Systems, LUT University, Yliopistonkatu 34, 53850 Lappeenranta, FinlandSchool of Energy Systems, LUT University, Yliopistonkatu 34, 53850 Lappeenranta, FinlandSchool of Energy Systems, LUT University, Yliopistonkatu 34, 53850 Lappeenranta, FinlandA modern pulp mill generates a variety of different by-products and waste streams, some of these can be recycled, refined, sold, or used on-site for energy production. However, some, such as chemical and biological sludges produced in wastewater treatment cannot be reused or disposed of easily, mainly due to their high moisture content and poor drying characteristics. Tightening legislation regarding waste disposal as well as the growing need to increase the process efficiencies of pulp mills act as driving forces to find environmentally friendly and energy-efficient techniques for pulp mill sludge treatment. This study summarizes the current methods for pulp mill sludge handling and evaluates the potential of hydrothermal carbonization (HTC), a conversion process through which wet organic substrates can be transformed into a carbonaceous material (hydrochar). Depending on the process parameters, the material’s structure is modified, enabling hydrochar use in energy, soil conditioning and adsorption applications. The sludges were hydrothermally carbonized at 180, 200, 220 and 240 °C for 3 h. The hydrochar and liquid products’ main properties were analyzed. Their potential applications were also evaluated. The effective treatment of sludges from the pulp industry with HTC could transform energy-demanding waste into a value-added source of materials.https://www.mdpi.com/1996-1073/14/18/5693thermochemical processsludge treatmentwaste biomass
spellingShingle Clara Lisseth Mendoza Martinez
Ekaterina Sermyagina
Esa Vakkilainen
Hydrothermal Carbonization of Chemical and Biological Pulp Mill Sludges
Energies
thermochemical process
sludge treatment
waste biomass
title Hydrothermal Carbonization of Chemical and Biological Pulp Mill Sludges
title_full Hydrothermal Carbonization of Chemical and Biological Pulp Mill Sludges
title_fullStr Hydrothermal Carbonization of Chemical and Biological Pulp Mill Sludges
title_full_unstemmed Hydrothermal Carbonization of Chemical and Biological Pulp Mill Sludges
title_short Hydrothermal Carbonization of Chemical and Biological Pulp Mill Sludges
title_sort hydrothermal carbonization of chemical and biological pulp mill sludges
topic thermochemical process
sludge treatment
waste biomass
url https://www.mdpi.com/1996-1073/14/18/5693
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AT ekaterinasermyagina hydrothermalcarbonizationofchemicalandbiologicalpulpmillsludges
AT esavakkilainen hydrothermalcarbonizationofchemicalandbiologicalpulpmillsludges