Highly Crystalline MIL-100 (Fe) Nanoparticles Prepared from Ferrous Salts and Applications in Photodegradation of Organic Dyes

In order to prepare highly crystalline and stable metal-organic frameworks (MOFs) nanoparticles in a straightforward and low cost method, trimesic acid was depronated by three equivalent NaOH in water, and mixed with ferrous salts (<i>e.g.</i> FeCl<sub>2</sub> and Fe(OAc)) so...

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Bibliographic Details
Main Authors: LIU Xiang-yue, ZHANG Yu, WANG Chen, MAO Hui-ling, DU Xuan, CHENG Hu, ZHUANG Jin-liang
Format: Article
Language:zho
Published: Journal of Materials Engineering 2018-10-01
Series:Cailiao gongcheng
Subjects:
Online Access: http://jme.biam.ac.cn/CN/Y2018/V46/I10/127
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Summary:In order to prepare highly crystalline and stable metal-organic frameworks (MOFs) nanoparticles in a straightforward and low cost method, trimesic acid was depronated by three equivalent NaOH in water, and mixed with ferrous salts (<i>e.g.</i> FeCl<sub>2</sub> and Fe(OAc)) solution under vigorous stirring for 24h at room temperature. The morphology and photocatalytic activity of the obtained MIL-100(Fe) nanoparticles were fully characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), UV-Vis diffuse reflectance spectroscopy (UV-Vis DRS) and UV-Vis spectroscopy. The results demonstrate that the MIL-100(Fe) nanoparticles exhibit excellent photocatalytic performance toward high concentrated Rhodamine B (RhB) and methyl orange (MO) organic dyes in the presence of H<sub>2</sub>O<sub>2</sub> as a co-catalyst under UV light irradiation.
ISSN:1001-4381
1001-4381