One-Pot Synthesis of Dioxime Oxalates
Dioxime oxalates, a type of carbonyl oximes, are well-known as clean sources of iminyl radicals that undergo key organic chemistry transformations. A series of dioxime oxalates is reported in this manuscript, obtained by the reaction of the corresponding oximes with oxalyl chloride and Et<sub>...
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| Format: | Article |
| Language: | English |
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MDPI AG
2022-10-01
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| Series: | Molbank |
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| Online Access: | https://www.mdpi.com/1422-8599/2022/4/M1473 |
| _version_ | 1827637611733188608 |
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| author | Laura Adarve-Cardona David Ezenarro-Salcedo Mario A. Macías Diego Gamba-Sánchez |
| author_facet | Laura Adarve-Cardona David Ezenarro-Salcedo Mario A. Macías Diego Gamba-Sánchez |
| author_sort | Laura Adarve-Cardona |
| collection | DOAJ |
| description | Dioxime oxalates, a type of carbonyl oximes, are well-known as clean sources of iminyl radicals that undergo key organic chemistry transformations. A series of dioxime oxalates is reported in this manuscript, obtained by the reaction of the corresponding oximes with oxalyl chloride and Et<sub>3</sub>N at room temperature. This one-pot method afforded three novel dioxime oxalates and the crystal structure of cyclopentanone dioxime oxalate analysis is also presented. |
| first_indexed | 2024-03-09T16:03:21Z |
| format | Article |
| id | doaj.art-7ea3919275314395a6128e63cfde7980 |
| institution | Directory Open Access Journal |
| issn | 1422-8599 |
| language | English |
| last_indexed | 2024-03-09T16:03:21Z |
| publishDate | 2022-10-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molbank |
| spelling | doaj.art-7ea3919275314395a6128e63cfde79802023-11-24T16:53:53ZengMDPI AGMolbank1422-85992022-10-0120224M147310.3390/M1473One-Pot Synthesis of Dioxime OxalatesLaura Adarve-Cardona0David Ezenarro-Salcedo1Mario A. Macías2Diego Gamba-Sánchez3Laboratory of Organic Synthesis Bio- and Organocatalysis, Chemistry Department, Universidad de Los Andes, Cra. 1 No 18A-12 Q:305, Bogotá 111711, ColombiaInorganic Chemistry, Catalysis and Bio-Inorganic Group, Chemistry Department, Universidad de Los Andes, Cra. 1 No. 18A-12, Bogotá 111711, ColombiaCrystallography and Chemistry of Materials, CrisQuimMat, Chemistry Department, Universidad de Los Andes, Cra. 1 No. 18A-12, Bogotá 111711, ColombiaLaboratory of Organic Synthesis Bio- and Organocatalysis, Chemistry Department, Universidad de Los Andes, Cra. 1 No 18A-12 Q:305, Bogotá 111711, ColombiaDioxime oxalates, a type of carbonyl oximes, are well-known as clean sources of iminyl radicals that undergo key organic chemistry transformations. A series of dioxime oxalates is reported in this manuscript, obtained by the reaction of the corresponding oximes with oxalyl chloride and Et<sub>3</sub>N at room temperature. This one-pot method afforded three novel dioxime oxalates and the crystal structure of cyclopentanone dioxime oxalate analysis is also presented.https://www.mdpi.com/1422-8599/2022/4/M1473dioxime oxalatesoximesketoximesiminyl radicalsX-ray diffraction |
| spellingShingle | Laura Adarve-Cardona David Ezenarro-Salcedo Mario A. Macías Diego Gamba-Sánchez One-Pot Synthesis of Dioxime Oxalates Molbank dioxime oxalates oximes ketoximes iminyl radicals X-ray diffraction |
| title | One-Pot Synthesis of Dioxime Oxalates |
| title_full | One-Pot Synthesis of Dioxime Oxalates |
| title_fullStr | One-Pot Synthesis of Dioxime Oxalates |
| title_full_unstemmed | One-Pot Synthesis of Dioxime Oxalates |
| title_short | One-Pot Synthesis of Dioxime Oxalates |
| title_sort | one pot synthesis of dioxime oxalates |
| topic | dioxime oxalates oximes ketoximes iminyl radicals X-ray diffraction |
| url | https://www.mdpi.com/1422-8599/2022/4/M1473 |
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