Protocol for olefin metathesis reactions of hydrophobic substrates performed in aqueous emulsion with mechanical stirring or with microwaves support
Summary: In the presented protocol, we describe the olefin metathesis of hydrophobic substrates in water emulsions using ruthenium catalysts in the presence of air. We detail the testing of mechanical foaming for emulsification and the use of microwave heating to optimize metathesis reaction efficie...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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Elsevier
2022-12-01
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| Series: | STAR Protocols |
| Subjects: | |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S2666166722005512 |
| _version_ | 1811292670186749952 |
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| author | Agata Tyszka-Gumkowska Anna Kajetanowicz Karol Grela |
| author_facet | Agata Tyszka-Gumkowska Anna Kajetanowicz Karol Grela |
| author_sort | Agata Tyszka-Gumkowska |
| collection | DOAJ |
| description | Summary: In the presented protocol, we describe the olefin metathesis of hydrophobic substrates in water emulsions using ruthenium catalysts in the presence of air. We detail the testing of mechanical foaming for emulsification and the use of microwave heating to optimize metathesis reaction efficiency. By utilizing relatively low catalyst loading and ensuring simple product isolation, the steps outlined in this protocol extend known methods for the aqueous metathesis techniques.For complete details on the use and execution of this protocol, please refer to Tyszka-Gumkowska et al. (2022). : Publisher’s note: Undertaking any experimental protocol requires adherence to local institutional guidelines for laboratory safety and ethics. |
| first_indexed | 2024-04-13T04:48:51Z |
| format | Article |
| id | doaj.art-7eae23c215104beb8605e1d76fabb23e |
| institution | Directory Open Access Journal |
| issn | 2666-1667 |
| language | English |
| last_indexed | 2024-04-13T04:48:51Z |
| publishDate | 2022-12-01 |
| publisher | Elsevier |
| record_format | Article |
| series | STAR Protocols |
| spelling | doaj.art-7eae23c215104beb8605e1d76fabb23e2022-12-22T03:01:45ZengElsevierSTAR Protocols2666-16672022-12-0134101671Protocol for olefin metathesis reactions of hydrophobic substrates performed in aqueous emulsion with mechanical stirring or with microwaves supportAgata Tyszka-Gumkowska0Anna Kajetanowicz1Karol Grela2Biological and Chemical Research Centre, Faculty of Chemistry, University of Warsaw, Żwirki i Wigury 101, 02-089 Warsaw, PolandBiological and Chemical Research Centre, Faculty of Chemistry, University of Warsaw, Żwirki i Wigury 101, 02-089 Warsaw, Poland; Corresponding authorBiological and Chemical Research Centre, Faculty of Chemistry, University of Warsaw, Żwirki i Wigury 101, 02-089 Warsaw, Poland; Corresponding authorSummary: In the presented protocol, we describe the olefin metathesis of hydrophobic substrates in water emulsions using ruthenium catalysts in the presence of air. We detail the testing of mechanical foaming for emulsification and the use of microwave heating to optimize metathesis reaction efficiency. By utilizing relatively low catalyst loading and ensuring simple product isolation, the steps outlined in this protocol extend known methods for the aqueous metathesis techniques.For complete details on the use and execution of this protocol, please refer to Tyszka-Gumkowska et al. (2022). : Publisher’s note: Undertaking any experimental protocol requires adherence to local institutional guidelines for laboratory safety and ethics.http://www.sciencedirect.com/science/article/pii/S2666166722005512ChemistryEnvironmental sciences |
| spellingShingle | Agata Tyszka-Gumkowska Anna Kajetanowicz Karol Grela Protocol for olefin metathesis reactions of hydrophobic substrates performed in aqueous emulsion with mechanical stirring or with microwaves support STAR Protocols Chemistry Environmental sciences |
| title | Protocol for olefin metathesis reactions of hydrophobic substrates performed in aqueous emulsion with mechanical stirring or with microwaves support |
| title_full | Protocol for olefin metathesis reactions of hydrophobic substrates performed in aqueous emulsion with mechanical stirring or with microwaves support |
| title_fullStr | Protocol for olefin metathesis reactions of hydrophobic substrates performed in aqueous emulsion with mechanical stirring or with microwaves support |
| title_full_unstemmed | Protocol for olefin metathesis reactions of hydrophobic substrates performed in aqueous emulsion with mechanical stirring or with microwaves support |
| title_short | Protocol for olefin metathesis reactions of hydrophobic substrates performed in aqueous emulsion with mechanical stirring or with microwaves support |
| title_sort | protocol for olefin metathesis reactions of hydrophobic substrates performed in aqueous emulsion with mechanical stirring or with microwaves support |
| topic | Chemistry Environmental sciences |
| url | http://www.sciencedirect.com/science/article/pii/S2666166722005512 |
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