SOLVATOCHROMIC AND SUBSTITUENT EFFECT ON ELECTRONIC ABSORPTION OF ARENETRICARBONYLCHROMIUM(0) COMPLEXES
A number of arenetricarbonylchromium(0) complexes, [(η6-arene)Cr(CO)3], in which arene = benzene, chlorobenzene, phenyltrimethylsilane, and acenaphthene were synthesized. Electronic absorptions of these complexes were recorded in various solvents, ranging from polar to non polar ones; i.e. methanol,...
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| Format: | Article |
| Language: | English |
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Department of Chemistry, Universitas Gadjah Mada
2010-06-01
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| Series: | Indonesian Journal of Chemistry |
| Online Access: | https://jurnal.ugm.ac.id/ijc/article/view/21641 |
| _version_ | 1818696211697238016 |
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| author | Agus Abhi Purwoko |
| author_facet | Agus Abhi Purwoko |
| author_sort | Agus Abhi Purwoko |
| collection | DOAJ |
| description | A number of arenetricarbonylchromium(0) complexes, [(η6-arene)Cr(CO)3], in which arene = benzene, chlorobenzene, phenyltrimethylsilane, and acenaphthene were synthesized. Electronic absorptions of these complexes were recorded in various solvents, ranging from polar to non polar ones; i.e. methanol, methylene chloride, chloroform, benzene, and isooctane. These chromium tricarbonyl complexes show lowest electronic absorption in the energy range of 313 - 320 nm, with relatively high intensity (ε = 0,9 - 2,0 x 104 M-1cm-1). Detailed discussion of the solvent and substituent effect on electronic absorption of these complexes are presented in this article.
Keywords: solvatochromic and substituent effect, chromium tricarbonyl complexes, electronic absorption |
| first_indexed | 2024-12-17T13:57:46Z |
| format | Article |
| id | doaj.art-7eafb80d0e0140ecb3776f5e38b1202c |
| institution | Directory Open Access Journal |
| issn | 1411-9420 2460-1578 |
| language | English |
| last_indexed | 2024-12-17T13:57:46Z |
| publishDate | 2010-06-01 |
| publisher | Department of Chemistry, Universitas Gadjah Mada |
| record_format | Article |
| series | Indonesian Journal of Chemistry |
| spelling | doaj.art-7eafb80d0e0140ecb3776f5e38b1202c2022-12-21T21:45:52ZengDepartment of Chemistry, Universitas Gadjah MadaIndonesian Journal of Chemistry1411-94202460-15782010-06-0181131710.22146/ijc.2164114739SOLVATOCHROMIC AND SUBSTITUENT EFFECT ON ELECTRONIC ABSORPTION OF ARENETRICARBONYLCHROMIUM(0) COMPLEXESAgus Abhi Purwoko0Study Program of Chemistry Education, Faculty of Teacher Training and Education, University of Mataram, Jl. Majapahit 62 MataramA number of arenetricarbonylchromium(0) complexes, [(η6-arene)Cr(CO)3], in which arene = benzene, chlorobenzene, phenyltrimethylsilane, and acenaphthene were synthesized. Electronic absorptions of these complexes were recorded in various solvents, ranging from polar to non polar ones; i.e. methanol, methylene chloride, chloroform, benzene, and isooctane. These chromium tricarbonyl complexes show lowest electronic absorption in the energy range of 313 - 320 nm, with relatively high intensity (ε = 0,9 - 2,0 x 104 M-1cm-1). Detailed discussion of the solvent and substituent effect on electronic absorption of these complexes are presented in this article. Keywords: solvatochromic and substituent effect, chromium tricarbonyl complexes, electronic absorptionhttps://jurnal.ugm.ac.id/ijc/article/view/21641 |
| spellingShingle | Agus Abhi Purwoko SOLVATOCHROMIC AND SUBSTITUENT EFFECT ON ELECTRONIC ABSORPTION OF ARENETRICARBONYLCHROMIUM(0) COMPLEXES Indonesian Journal of Chemistry |
| title | SOLVATOCHROMIC AND SUBSTITUENT EFFECT ON ELECTRONIC ABSORPTION OF ARENETRICARBONYLCHROMIUM(0) COMPLEXES |
| title_full | SOLVATOCHROMIC AND SUBSTITUENT EFFECT ON ELECTRONIC ABSORPTION OF ARENETRICARBONYLCHROMIUM(0) COMPLEXES |
| title_fullStr | SOLVATOCHROMIC AND SUBSTITUENT EFFECT ON ELECTRONIC ABSORPTION OF ARENETRICARBONYLCHROMIUM(0) COMPLEXES |
| title_full_unstemmed | SOLVATOCHROMIC AND SUBSTITUENT EFFECT ON ELECTRONIC ABSORPTION OF ARENETRICARBONYLCHROMIUM(0) COMPLEXES |
| title_short | SOLVATOCHROMIC AND SUBSTITUENT EFFECT ON ELECTRONIC ABSORPTION OF ARENETRICARBONYLCHROMIUM(0) COMPLEXES |
| title_sort | solvatochromic and substituent effect on electronic absorption of arenetricarbonylchromium 0 complexes |
| url | https://jurnal.ugm.ac.id/ijc/article/view/21641 |
| work_keys_str_mv | AT agusabhipurwoko solvatochromicandsubstituenteffectonelectronicabsorptionofarenetricarbonylchromium0complexes |